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Competing Effects in the Hydration Mechanism of a Garnet-Type Li 7 La 3 Zr 2 O 12 Electrolyte

Journal Article · · Chemistry of Materials
 [1];  [2];  [3];  [3];  [4];  [5];  [6];  [7]
  1. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-1): Materials Synthesis and Processing, 52425 Jülich, Germany; OSTI
  2. Eyring Materials Center, Arizona State University, P.O. Box 878301, Tempe, Arizona 85287-8301, United States
  3. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-1): Materials Synthesis and Processing, 52425 Jülich, Germany
  4. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-1): Materials Synthesis and Processing, 52425 Jülich, Germany; Helmholtz Institute Münster: Ionics in Energy Storage (IEK-12), Forschungszentrum Jülich GmbH, Corrensstrasse 46, 48149 Münster, Germany; Faculty of Engineering, Center for Nanointegration Duisburg-Essen, Universität Duisburg-Essen, Lotharstrasse 1, 47057 Duisburg, Germany
  5. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-1): Materials Synthesis and Processing, 52425 Jülich, Germany; Helmholtz Institute Münster: Ionics in Energy Storage (IEK-12), Forschungszentrum Jülich GmbH, Corrensstrasse 46, 48149 Münster, Germany
  6. Navrotsky Eyring Center for Materials of the Universe, Arizona State University, Tempe, Arizona 85281, United States
  7. Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-1): Materials Synthesis and Processing, 52425 Jülich, Germany; Jülich Aachen Research Alliance, JARA-Energy, 52425 Jülich, Germany
Not provided.
Research Organization:
Univ. of California, Davis, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-03ER46053
OSTI ID:
1977784
Journal Information:
Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 4 Vol. 34; ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (40)

Controlling the lithium proton exchange of LLZO to enable reproducible processing and performance optimization journal January 2021
Mg-doping towards enhancing the composition-phase-structural stability of Li-La-zirconate based cubic garnet upon exposure to air journal March 2019
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal October 2007
Microelectrodes for local conductivity and degradation measurements on Al stabilized Li7La3Zr2O12 garnets journal November 2016
Reaction kinetics of portland cement mortars hydrated at different temperatures journal January 1992
Lithium Hydroxide Reaction for Low Temperature Chemical Heat Storage: Hydration and Dehydration Reaction journal September 2019
Reaction mechanisms of lithium garnet pellets in ambient air: The effect of humidity and CO 2 journal April 2017
Garnet Electrolyte Surface Degradation and Recovery journal October 2018
Li 7 La 3 Zr 2 O 12 Interface Modification for Li Dendrite Prevention journal April 2016
Electrochemical Stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 Solid Electrolytes journal January 2016
Present understanding of the stability of Li-stuffed garnets with moisture, carbon dioxide, and metallic lithium journal June 2018
Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li 7 La 3 Zr 2 O 12 journal September 2017
Effect of Li+/H+ exchange in water treated Ta-doped Li7La3Zr2O12 journal September 2016
Atmosphere Controlled Processing of Ga-Substituted Garnets for High Li-Ion Conductivity Ceramics journal June 2014
Cubic phases of garnet-type Li7La3Zr2O12: the role of hydration journal January 2013
A Simple and Fast Electrochemical CO 2 Sensor Based on Li 7 La 3 Zr 2 O 12 for Environmental Monitoring journal September 2018
Phase transition in lithium garnet oxide ionic conductors Li7La3Zr2O12: The role of Ta substitution and H2O/CO2 exposure journal February 2015
Combined temperature and water vapor effects on the lithium hydroxide-carbon dioxide reaction in underwater life support systems journal January 1979
Influence of Li + and H + Distribution on the Crystal Structure of Li 7– x H x La 3 Zr 2 O 12 (0 ≤ x ≤ 5) Garnets journal January 2016
Garnet Electrolytes for Solid State Batteries: Visualization of Moisture-Induced Chemical Degradation and Revealing Its Impact on the Li-Ion Dynamics journal May 2018
Interrelationships among Grain Size, Surface Composition, Air Stability, and Interfacial Resistance of Al-Substituted Li 7 La 3 Zr 2 O 12 Solid Electrolytes journal August 2015
A general, highly efficient, high temperature thermal pulse toward high performance solid state electrolyte journal February 2019
Excellent Stability of a Lithium-Ion-Conducting Solid Electrolyte upon Reversible Li + /H + Exchange in Aqueous Solutions journal October 2014
Reversible ion exchange and structural stability of garnet-type Nb-doped Li7La3Zr2O12 in water for applications in lithium batteries journal May 2015
A garnet structure-based all-solid-state Li battery without interface modification: resolving incompatibility issues on positive electrodes journal January 2019
The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes journal January 2014
Investigation of hydrolysis of lithium oxide by thermogravimetry, calorimetry and in situ FTIR spectroscopy journal January 2018
Chemical Heat Storage with LiOH/LiOH·H2O Reaction for Low-Temperature Heat below 373 K journal June 2014
Carbon Dioxide Separation through Polymeric Membrane Systems for Flue Gas Applications journal January 2010
Effect of Water Vapor on the LiOH-CO2 Reaction. Dynamic Isothermal System journal August 1970
Li7La3Zr2O12 electrolyte stability in air and fabrication of a Li/Li7La3Zr2O12/Cu0.1V2O5 solid-state battery journal October 2013
Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy journal January 2019
Direct measurements of water adsorption enthalpy on hafnia and zirconia journal October 2005
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data journal June 2011
Impact of Protonation on the Electrochemical Performance of Li7La3Zr2O12 Garnets journal March 2021
Thermodynamic properties of solid electrolyte Li7La3Zr2O12 journal January 2019
Impact of air exposure and surface chemistry on Li–Li 7 La 3 Zr 2 O 12 interfacial resistance journal January 2017
Studies on Reaction Kinetics of LiOH for Absorbing CO2 conference March 2009
Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li 7 La 3 Zr 2 O 12 journal January 2014
Structural and Computational Assessment of the Influence of Wet-Chemical Post-Processing of the Al-Substituted Cubic Li 7 La 3 Zr 2 O 12 journal October 2018

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