Separation, speciation, and mechanism of astatine and bismuth extraction from nitric acid into 1-octanol and methyl anthranilate

Tereshatov, Evgeny E.; Burns, Jonathan D.; Vonder Haar, Amy L.; Schultz, Steven J.; McIntosh, Lauren A.; Tabacaru, Gabriel C.; McCann, Laura A.; Avila, Geoffrey; Hannaman, Andrew; Lofton, Kylie N.; McCarthy, Mallory A.; Zhang, Bowen; Hall, Michael B.; Yennello, Sherry J.

doi:10.1016/j.seppur.2021.120088

Separation, speciation, and mechanism of astatine and bismuth extraction from nitric acid into 1-octanol and methyl anthranilate

Journal Article · Tue Nov 09 00:00:00 EST 2021 · Separation and Purification Technology

DOI:https://doi.org/10.1016/j.seppur.2021.120088· OSTI ID:1977641

Tereshatov, Evgeny E. ^[1]; Burns, Jonathan D. ^[2]; Vonder Haar, Amy L. ^[2]; Schultz, Steven J. ^[2]; McIntosh, Lauren A. ^[2]; Tabacaru, Gabriel C. ^[2]; McCann, Laura A. ^[2]; Avila, Geoffrey ^[2]; Hannaman, Andrew ^[2]; Lofton, Kylie N. ^[2]; McCarthy, Mallory A. ^[2]; Zhang, Bowen ^[2]; Hall, Michael B. ^[2]; Yennello, Sherry J. ^[2]

Texas A & M University, College Station, TX (United States); OSTI
Texas A & M University, College Station, TX (United States)

We report a detailed study of At and Bi extraction from nitric acid media into conventional solvents, namely 1-octanol and methyl anthranilate, has been performed. The analysis includes a mathematical modeling which allows the fitting of experimental data and determination of extraction constants of the two above mentioned elements. Also, this approach helped to estimate a stability constant of a weak AtO(NO3) complex along with thermodynamic constants describing the redox process of At species in the acidic solution and formation of an adduct of Bi in the presence of methyl anthranilate. The results of the fitting have been used to calculate corresponding separation factors of Bi and At as well. Moreover, a computational study has been performed to evaluate At interaction with the above mentioned solvents.

View Accepted Manuscript (DOE)

Research Organization:: Texas A & M University, College Station, TX (United States)

Sponsoring Organization:: Texas A&M University; USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: FG02-93ER40773; NA0003841; SC0020958

OSTI ID:: 1977641

Alternate ID(s):: OSTI ID: 1834665

Journal Information:: Separation and Purification Technology, Journal Name: Separation and Purification Technology Journal Issue: PB Vol. 282; ISSN 1383-5866

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Separation, speciation, and mechanism of astatine and bismuth extraction from nitric acid into 1-octanol and methyl anthranilate

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References (56)

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