Thermodynamic analysis of hydrogel swelling in aqueous sodium chloride solutions

Tanveer, Sheik; Chen, Chau-Chyun

doi:10.1016/j.molliq.2021.118421

Title: Thermodynamic analysis of hydrogel swelling in aqueous sodium chloride solutions

Journal Article · Thu Dec 30 00:00:00 EST 2021 · Journal of Molecular Liquids

DOI:https://doi.org/10.1016/j.molliq.2021.118421· OSTI ID:1977459

Tanveer, Sheik ^[1]; Chen, Chau-Chyun ^[1]

Texas Tech Univ., Lubbock, TX (United States)

Here, a comprehensive thermodynamic model is presented for swelling and salt partitioning of poly (n-isopropyl acrylamide) hydrogels in aqueous sodium chloride (NaCl) solutions at 298 K. Together with a Helmholtz energy expression for network elastic energy, a modified electrolyte Nonradom Two-Liquid activity coefficient model is used to represent both the long-range electrostatic interactions and the short-range van der Waals interactions present in the gel phase. The model parameters include one network parameter per hydrogel system plus two binary parameters per interaction pair in the polymer–solvent-salt systems. With semiquantitave agreement with experimental data for both hydrogel swelling and salt partitioning up to salt saturation, the analysis suggests the ion hydration between NaCl and water is the root cause for hydrogel deswelling in aqueous NaCl solution at high NaCl concentrations, i.e., NaCl weight fraction >0.03. On the other hand, the strong repulsive interaction between NaCl and hydrogel polymer is the dominant factor for salt partitioning.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: American Institute of Chemical Engineers (AIChE), New York, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007888

OSTI ID:: 1977459

Alternate ID(s):: OSTI ID: 1838557

Journal Information:: Journal of Molecular Liquids, Vol. 348; ISSN 0167-7322

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (20)

Modeling swelling behavior of hydrogels in aqueous organic solvents Islam, Md Rashedul; Tanveer, Sheik; Chen, Chau-Chyun Chemical Engineering Science, Vol. 242 https://doi.org/10.1016/j.ces.2021.116744	journal	October 2021
Symmetric Electrolyte Nonrandom Two-Liquid Activity Coefficient Model Song, Yuhua; Chen, Chau-Chyun Industrial & Engineering Chemistry Research, Vol. 48, Issue 16 https://doi.org/10.1021/ie9004578	journal	August 2009
Thermodynamics of phase equilibrium for systems containing gels Maurer, G.; Prausnitz, J. M. Fluid Phase Equilibria, Vol. 115, Issue 1-2 https://doi.org/10.1016/0378-3812(95)02829-3	journal	February 1996
Simple presentation of network theory of rubber, with a discussion of other theories James, Hubert M.; Guth, Eugene Journal of Polymer Science, Vol. 4, Issue 2 https://doi.org/10.1002/pol.1949.120040206	journal	April 1949
Poly(vinyl alcohol) hydrogels as soft contact lens material Hyon, Suong-Hyu; Cha, Won-Ill; Ikada, Yoshito Journal of Biomaterials Science, Polymer Edition, Vol. 5, Issue 5 https://doi.org/10.1163/156856294X00103	journal	January 1994
Swelling of N-isopropyl acrylamide hydrogels in aqueous solutions of sodium chloride Hüther, Andreas; Xu, Xiaoping; Maurer, Gerd Fluid Phase Equilibria, Vol. 240, Issue 2 https://doi.org/10.1016/j.fluid.2005.12.025	journal	February 2006
Environment-sensitive hydrogels for drug delivery Qiu, Yong; Park, Kinam Advanced Drug Delivery Reviews, Vol. 53, Issue 3 https://doi.org/10.1016/S0169-409X(01)00203-4	journal	December 2001
Sodium chloride-induced phase transition in nonionic poly(N-isopropylacrylamide) gel Park, Tae Gwan; Hoffman, Allan S. Macromolecules, Vol. 26, Issue 19 https://doi.org/10.1021/ma00071a010	journal	September 1993
Effects of Salt on the Lower Critical Solution Temperature of Poly ( N -Isopropylacrylamide) Du, Hongbo; Wickramasinghe, Ranil; Qian, Xianghong The Journal of Physical Chemistry B, Vol. 114, Issue 49 https://doi.org/10.1021/jp105652c	journal	December 2010
A segment-based local composition model for the gibbs energy of polymer solutions Chen, Chau-Chyun Fluid Phase Equilibria, Vol. 83 https://doi.org/10.1016/0378-3812(93)87033-W	journal	February 1993
Swelling of n-isopropyl acrylamide hydrogels in water and aqueous solutions of ethanol and acetone Hüther, Andreas; Xu, Xiaoping; Maurer, Gerd Fluid Phase Equilibria, Vol. 219, Issue 2 https://doi.org/10.1016/j.fluid.2003.08.002	journal	May 2004
Modeling Poly( N -isopropylacrylamide) Hydrogels in Water/Alcohol Mixtures with PC-SAFT Arndt, Markus C.; Sadowski, Gabriele Macromolecules, Vol. 45, Issue 16 https://doi.org/10.1021/ma300683k	journal	July 2012
Generalized electrolyte-NRTL model for mixed-solvent electrolyte systems Chen, Chau-Chyun; Song, Yuhua AIChE Journal, Vol. 50, Issue 8 https://doi.org/10.1002/aic.10151	journal	January 2004
Swelling equilibria for positively ionized polyacrylamide hydrogels Hooper, Herbert H.; Baker, John P.; Blanch, Harvey W. Macromolecules, Vol. 23, Issue 4 https://doi.org/10.1021/ma00206a031	journal	February 1990
Local composition model for excess Gibbs energy of electrolyte systems. Part I: Single solvent, single completely dissociated electrolyte systems Chen, Chau-Chyun; Britt, H. I.; Boston, J. F. AIChE Journal, Vol. 28, Issue 4 https://doi.org/10.1002/aic.690280410	journal	July 1982
PNIPAM-MAPOSS Hybrid Hydrogels with Excellent Swelling Behavior and Enhanced Mechanical Performance: Preparation and Drug Release of 5-Fluorouracil Li, Peihong; Hou, Xiaoman; Qu, Lijie Polymers, Vol. 10, Issue 2 https://doi.org/10.3390/polym10020137	journal	January 2018
Thermo-Responsive Poly(N-Isopropylacrylamide)-Cellulose Nanocrystals Hybrid Hydrogels for Wound Dressing Zubik, Katarzyna; Singhsa, Pratyawadee; Wang, Yinan Polymers, Vol. 9, Issue 12 https://doi.org/10.3390/polym9040119	journal	March 2017
Temperature dependence of interaction parameters in electrolyte NRTL model Hossain, Nazir; Bhattacharia, Sanjoy K.; Chen, Chau-Chyun AIChE Journal, Vol. 62, Issue 4 https://doi.org/10.1002/aic.15080	journal	November 2015
Thermodynamic representation of the NaCl+Na2SO4+H2O system with electrolyte NRTL model Yan, Yizhuan; Chen, Chau-Chyun Fluid Phase Equilibria, Vol. 306, Issue 2 https://doi.org/10.1016/j.fluid.2011.03.023	journal	July 2011
A local composition model for the excess Gibbs energy of aqueous electrolyte systems Chen, Chau-Chyun; Evans, L. B. AIChE Journal, Vol. 32, Issue 3 https://doi.org/10.1002/aic.690320311	journal	March 1986

Similar Records

Modeling swelling behavior of hydrogels in aqueous organic solvents

Journal Article · Thu May 06 00:00:00 EDT 2021 · Chemical Engineering Science · OSTI ID:1977459

Islam, Md Rashedul; Tanveer, Sheik; Chen, Chau-Chyun

Non-monotonic swelling of surface grafted hydrogels induced by pH and/or salt concentration

Journal Article · Sun Sep 28 00:00:00 EDT 2014 · Journal of Chemical Physics · OSTI ID:1977459

Longo, Gabriel S.

Swelling properties of cassava starch grafted with poly (potassium acrylate-co-acrylamide) superabsorbent hydrogel prepared by ionizing radiation

Journal Article · Tue Dec 29 00:00:00 EST 2015 · AIP Conference Proceedings · OSTI ID:1977459

Ulfiyani, Fida; Istiqomah, Shafina; Rahmayetty, ; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Electrolyte NRTL model
Hydrogel swelling
Polymer NRTL model
Salt partitioning

Title: Thermodynamic analysis of hydrogel swelling in aqueous sodium chloride solutions

Citation Formats

References (20)

Similar Records

Related Subjects