Preparation of defect-free asymmetric gas separation membranes with dihydrolevoglucosenone (CyreneTM) as a greener polar aprotic solvent

Bridge, Alexander T.; Pedretti, Benjamin J.; Brennecke, Joan F.; Freeman, Benny D.

doi:10.1016/j.memsci.2021.120173

Preparation of defect-free asymmetric gas separation membranes with dihydrolevoglucosenone (Cyrene^TM) as a greener polar aprotic solvent

Journal Article · Thu Dec 09 23:00:00 EST 2021 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2021.120173· OSTI ID:1977440

^[1]; ^[2]; Brennecke, Joan F. ^[2]; Freeman, Benny D. ^[2]

Univ. of Texas, Austin, TX (United States); OSTI
Univ. of Texas, Austin, TX (United States)

Nonsolvent-induced phase separation (NIPS) is widely used to prepare asymmetric gas separation membranes. Most industrial NIPS casting solution formulations are limited to a small group of glassy polymers and, importantly, require toxic polar aprotic solvents such as N,N-dimethylacetamide (DMAc), N,N-dimethylformamide (DMF), or N-methyl-2-pyrrolidone (NMP). Growing restrictions on the use of such solvents are spurring the search for more benign casting solution formulations that do not compromise membrane performance. Herein this study reports high-flux, defect-free asymmetric polysulfone (PSf) gas separation membranes prepared using dihydrolevoglucosenone (Cyrene^TM), a polar aprotic solvent that is believed to be safer than DMAc, DMF, and NMP, as the majority casting solution component. Optimized formulations and casting conditions produce membranes with hydrogen permeances exceeding 100 gas permeance units (GPU) and selectivities at or above those of dense PSf films. Dry/wet NIPS membrane performance improved with shorter dry step times and increased Cyrene^TM loadings relative to the volatile solvent, tetrahydrofuran (THF), in the casting solution. The high water-Cyrene^TM Flory-Huggins interaction parameter, _{$$\mathcal{X}12$$}, and high casting solution viscosities help suppress the formation of skin layer defects and sublayer macrovoids. In some cases, membrane selectivities were influenced by substructure resistance, providing insight into the relationship between sublayer morphology and membrane performance.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Texas, Austin, TX (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Materials for Water and Energy Systems (M-WET)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019272

OSTI ID:: 1977440

Journal Information:: Journal of Membrane Science, Journal Name: Journal of Membrane Science Journal Issue: C Vol. 644; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Defect-free
Dihydrolevoglucosenone (CyreneTM)
Engineering
Gas separation
Nonsolvent-induced phase separation
Polymer science
Polysulfone

Preparation of defect-free asymmetric gas separation membranes with dihydrolevoglucosenone (CyreneTM) as a greener polar aprotic solvent

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Preparation of defect-free asymmetric gas separation membranes with dihydrolevoglucosenone (Cyrene^TM) as a greener polar aprotic solvent