Intergranular precipitation-enhanced wetting and phase transformation in an Al0.4CoCrFeNi high-entropy alloy exposed to lead-bismuth eutectic

Gong, Xing; Auger, Thierry; Zhu, Wenjian; Lei, Huasheng; Xiang, Congying; Yu, Zhiyang; Short, Michael P.; Wang, Pei; Yin, Yuan

doi:10.1016/j.corsci.2021.110038

Intergranular precipitation-enhanced wetting and phase transformation in an Al0.4CoCrFeNi high-entropy alloy exposed to lead-bismuth eutectic

Journal Article · Wed Dec 22 00:00:00 EST 2021 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2021.110038· OSTI ID:1977035

Gong, Xing ^[1]; Auger, Thierry ^[2]; Zhu, Wenjian ^[3]; Lei, Huasheng ^[4]; Xiang, Congying ^[4]; Yu, Zhiyang ^[4]; Short, Michael P. ^[5]; Wang, Pei ^[3]; Yin, Yuan ^[3]

Shenzhen University (China); OSTI
Hautes Écoles Sorbonne Arts et Métiers University (HESAM), Paris (France)
Shenzhen University (China)
Fuzhou University (China)
Massachusetts Institute of Technology (MIT), Cambridge, MA (United States)

We report after exposure to oxygen-poor (10^-13–10^-14 wt%) liquid lead-bismuth eutectic (LBE) at 500 °C for 500 h, LBE penetrates more than one order of magnitude deeper in an FCC Al_0.4CoCrFeNi high-entropy alloy (HEA) decorated with a network of BCC (Ni, Al)-rich intergranular (IG) precipitates than in a single-phase, FCC Al_0.3CoCrFeNi HEA without the IG precipitate network. This deterioration of corrosion resistance is attributed to the energetic nature of the BCC/FCC interphase boundaries (IBs) and resultant IB wetting. The LBE ingress film selectively leaches nickel located at those low-indexed crystalline planes, resulting in phase transformation from FCC to BCC structure.

View Accepted Manuscript (DOE)

Research Organization:: Massachusetts Institute of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: National Natural Science Foundation of China; USDOE Office of Nuclear Energy (NE); USDOE Office of Nuclear Energy (NE), Nuclear Energy University Program (NEUP)

Grant/Contract Number:: NE0008871

OSTI ID:: 1977035

Alternate ID(s):: OSTI ID: 1866279

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Journal Issue: C Vol. 196; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

Secondary phases in AlxCoCrFeNi high-entropy alloys: An in-situ TEM heating study and thermodynamic appraisal Rao, J. C.; Diao, H. Y.; Ocelík, V. Acta Materialia, Vol. 131 https://doi.org/10.1016/j.actamat.2017.03.066	journal	June 2017
High entropy alloys: A focused review of mechanical properties and deformation mechanisms George, E. P.; Curtin, W. A.; Tasan, C. C. Acta Materialia, Vol. 188 https://doi.org/10.1016/j.actamat.2019.12.015	journal	April 2020
Effect of Al content on the oxidation behavior of Y/Hf-doped AlCoCrFeNi high-entropy alloy Lu, Jie; Chen, Ying; Zhang, Han Corrosion Science, Vol. 170 https://doi.org/10.1016/j.corsci.2020.108691	journal	July 2020
High-temperature oxidation behaviour of CoCrNi medium-entropy alloy Agustianingrum, Maya Putri; Lee, Unhae; Park, Nokeun Corrosion Science, Vol. 173 https://doi.org/10.1016/j.corsci.2020.108755	journal	August 2020
Compatibility and microstructure evolution of Al-Cr-Fe-Ni high entropy model alloys exposed to oxygen-containing molten lead Shi, Hao; Jianu, Adrian; Fetzer, Renate Corrosion Science, Vol. 189 https://doi.org/10.1016/j.corsci.2021.109593	journal	August 2021
Effects of Al addition on the microstructure and mechanical property of AlxCoCrFeNi high-entropy alloys Wang, Woei-Ren; Wang, Wei-Lin; Wang, Shang-Chih Intermetallics, Vol. 26 https://doi.org/10.1016/j.intermet.2012.03.005	journal	July 2012
Thermal oxidation characteristics of Fe (CoCrMnNi) medium and high-entropy alloys Agustianingrum, Maya Putri; Latief, Fahamsyah Hamdan; Park, Nokeun Intermetallics, Vol. 120 https://doi.org/10.1016/j.intermet.2020.106757	journal	May 2020
Effect of aluminum addition on solid solution strengthening in CoCrNi medium-entropy alloy Agustianingrum, Maya Putri; Yoshida, Shuhei; Tsuji, Nobuhiro Journal of Alloys and Compounds, Vol. 781 https://doi.org/10.1016/j.jallcom.2018.12.065	journal	April 2019
Review of the studies on fundamental issues in LBE corrosion Zhang, Jinsuo; Li, Ning Journal of Nuclear Materials, Vol. 373, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2007.06.019	journal	February 2008
Influence of liquid lead and lead–bismuth eutectic on tensile, fatigue and creep properties of ferritic/martensitic and austenitic steels for transmutation systems Gorse, D.; Auger, T.; Vogt, J. -B. Journal of Nuclear Materials, Vol. 415, Issue 3 https://doi.org/10.1016/j.jnucmat.2011.04.047	journal	August 2011
Investigation of liquid LBE embrittlement effects on irradiated ferritic/martensitic steels by slow-strain-rate tensile tests Long, B.; Dai, Y.; Baluc, N. Journal of Nuclear Materials, Vol. 431, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2011.11.036	journal	December 2012
Corrosion scales on various steels after exposure to liquid lead–bismuth eutectic Lambrinou, K.; Koch, V.; Coen, G. Journal of Nuclear Materials, Vol. 450, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2013.09.034	journal	July 2014
Long-term corrosion of austenitic steels in flowing LBE at 400 °C and 10 −7 mass% dissolved oxygen in comparison with 450 and 550 °C Tsisar, Valentyn; Schroer, Carsten; Wedemeyer, Olaf Journal of Nuclear Materials, Vol. 468 https://doi.org/10.1016/j.jnucmat.2015.09.027	journal	January 2016
Opportunities for the LWR ATF materials development program to contribute to the LBE-cooled ADS materials qualification program Gong, Xing; Li, Rui; Sun, Maozhou Journal of Nuclear Materials, Vol. 482 https://doi.org/10.1016/j.jnucmat.2016.10.012	journal	December 2016
Dissolution corrosion of 316L austenitic stainless steels in contact with static liquid lead-bismuth eutectic (LBE) at 500 °C Lambrinou, Konstantina; Charalampopoulou, Evangelia; Van der Donck, Tom Journal of Nuclear Materials, Vol. 490 https://doi.org/10.1016/j.jnucmat.2017.04.004	journal	July 2017
The formation of B2-precipitate and its effect on grain growth behavior in aluminum-containing CoCrNi medium-entropy alloy Kim, Hyomin; Lee, Donghee; Kim, Hyungjun Materials Letters, Vol. 303 https://doi.org/10.1016/j.matlet.2021.130481	journal	November 2021
Creep failure of a solution-annealed 15-15Ti steel exposed to stagnant lead-bismuth eutectic at 550 and 600 °C Gong, Xing; Yang, Zhibin; Deng, Yangbin Materials Science and Engineering: A, Vol. 798 https://doi.org/10.1016/j.msea.2020.140230	journal	November 2020
Mechanical properties of high-entropy alloys with emphasis on face-centered cubic alloys Li, Zezhou; Zhao, Shiteng; Ritchie, Robert O. Progress in Materials Science, Vol. 102 https://doi.org/10.1016/j.pmatsci.2018.12.003	journal	May 2019
High-entropy alloys with heterogeneous microstructure: Processing and mechanical properties Sathiyamoorthi, Praveen; Kim, Hyoung Seop Progress in Materials Science https://doi.org/10.1016/j.pmatsci.2020.100709	journal	June 2020
Identification of a bilayer grain boundary complexion in Bi-doped Cu Kundu, Animesh; Asl, Kaveh Meshinchi; Luo, Jian Scripta Materialia, Vol. 68, Issue 2 https://doi.org/10.1016/j.scriptamat.2012.10.012	journal	January 2013
Microstructure of liquid metal embrittlement cracks on Zn-coated 22MnB5 press-hardened steel Cho, Lawrence; Kang, Heeseung; Lee, Changwook Scripta Materialia, Vol. 90-91 https://doi.org/10.1016/j.scriptamat.2014.07.008	journal	November 2014
Supercritical area and critical nugget diameter for liquid metal embrittlement of Zn-coated twining induced plasticity steels Ashiri, Rouholah; Haque, Md Anwarul; Ji, Chang-Wook Scripta Materialia, Vol. 109 https://doi.org/10.1016/j.scriptamat.2015.07.006	journal	December 2015
Liquid metal embrittlement-free welds of Zn-coated twinning induced plasticity steels Ashiri, Rouholah; Shamanian, Morteza; Salimijazi, Hamid Reza Scripta Materialia, Vol. 114 https://doi.org/10.1016/j.scriptamat.2015.11.027	journal	March 2016
Twin boundary-accelerated ferritization of austenitic stainless steels in liquid lead–bismuth eutectic Hosemann, P.; Frazer, D.; Stergar, E. Scripta Materialia, Vol. 118 https://doi.org/10.1016/j.scriptamat.2016.02.029	journal	June 2016
Transgranular cracking in a liquid Zn embrittled high strength steel Bhattacharya, Diptak; Cho, Lawrence; van der Aa, Ellen Scripta Materialia, Vol. 175 https://doi.org/10.1016/j.scriptamat.2019.09.006	journal	January 2020
High entropy alloys: Key issues under passionate debate Biswas, Krishanu; Yeh, Jien-Wei; Bhattacharjee, Pinaki P. Scripta Materialia, Vol. 188 https://doi.org/10.1016/j.scriptamat.2020.07.010	journal	November 2020
Liquid metal embrittlement of a dual-phase Al0.7CoCrFeNi high-entropy alloy exposed to oxygen-saturated lead-bismuth eutectic Gong, Xing; Xiang, Congying; Auger, Thierry Scripta Materialia, Vol. 194 https://doi.org/10.1016/j.scriptamat.2020.113652	journal	March 2021
The interfacial structure underpinning the Al-Ga liquid metal embrittlement: disorder vs. order gradients Shen, Min; Li, Yanwen; Hu, Chongze Scripta Materialia, Vol. 204 https://doi.org/10.1016/j.scriptamat.2021.114149	journal	November 2021
Comparison of solid metal–metal oxide reference electrodes for potentiometric oxygen sensors in liquid lead–bismuth eutectic operating at low temperature ranges Manfredi, G.; Lim, J.; Rosseel, K. Sensors and Actuators B: Chemical, Vol. 214 https://doi.org/10.1016/j.snb.2015.03.004	journal	July 2015
Bismuth-induced embrittlement of copper grain boundaries Duscher, Gerd; Chisholm, Matthew F.; Alber, Uwe Nature Materials, Vol. 3, Issue 9 https://doi.org/10.1038/nmat1191	journal	August 2004
Grain boundary wetting and prewetting in Ni-doped Mo Shi, Xiaomeng; Luo, Jian Applied Physics Letters, Vol. 94, Issue 25 https://doi.org/10.1063/1.3155443	journal	June 2009
Direct Evidence of Nanometric Invasionlike Grain Boundary Penetration in the Al / Ga System Pereiro-López, E.; Ludwig, W.; Bellet, D. Physical Review Letters, Vol. 95, Issue 21 https://doi.org/10.1103/PhysRevLett.95.215501	journal	November 2005
The Role of a Bilayer Interfacial Phase on Liquid Metal Embrittlement Luo, J.; Cheng, H.; Asl, K. M. Science, Vol. 333, Issue 6050 https://doi.org/10.1126/science.1208774	journal	September 2011
Segregation-induced ordered superstructures at general grain boundaries in a nickel-bismuth alloy Yu, Zhiyang; Cantwell, Patrick R.; Gao, Qin Science, Vol. 358, Issue 6359 https://doi.org/10.1126/science.aam8256	journal	October 2017
Environmentally assisted cracking of T91 ferritic-martensitic steel in heavy liquid metals Hojná, Anna; Halodová, Patricie; Chocholoušek, Michal Corrosion Reviews, Vol. 38, Issue 2 https://doi.org/10.1515/corrrev-2019-0035	journal	March 2020
A Short Review of High-Temperature Wetting and Complexion Transitions with a Critical Assessment of Their Influence on Liquid Metal Embrittlement and Corrosion Luo, Jian Corrosion, Vol. 72, Issue 7 https://doi.org/10.5006/1925	journal	July 2016

Similar Records

In-situ visualization of corrosion behavior of Al CoCrFeNi high-entropy alloys during electrochemical polarization

Journal Article · Tue Jun 23 20:00:00 EDT 2020 · Journal of Alloys and Compounds · OSTI ID:1849107

Experimental and Computational Investigation of High Entropy Alloys for Elevated-Temperature Applications

Technical Report · Sat Jul 30 00:00:00 EDT 2016 · OSTI ID:1337018

Related Subjects

36 MATERIALS SCIENCE
LBE
corrosion
high entropy alloys
phase transformation
wetting

Intergranular precipitation-enhanced wetting and phase transformation in an Al0.4CoCrFeNi high-entropy alloy exposed to lead-bismuth eutectic

Citation Formats

References (36)

Similar Records

Related Subjects