Long term oxidation of NiCoCrAlY coated Ni-based superalloys: A comparison of observed and simulated interdiffusion

Kane, Kenneth A.; Pillai, Rishi R.; Lance, Michael J.; Pint, Bruce A.

doi:10.1016/j.corsci.2023.111213

Long term oxidation of NiCoCrAlY coated Ni-based superalloys: A comparison of observed and simulated interdiffusion

Journal Article · Sun Apr 23 00:00:00 EDT 2023 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2023.111213· OSTI ID:1975339

Kane, Kenneth A. ^[1]; ^[1]; ^[1]; ^[1]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Lifetimes of MCrAlY-type coatings can easily surpass 25 kh when the criteria of ß-depletion is used. To reduce experimental effort, it’s necessary to develop models capable of simulating interdiffusion and oxidation. In the present study, NiCoCrAlY coatings were high velocity oxyfuel deposited on PWA 1483, MARM247, and CMSX-4 substrates, and samples were exposed at 900 °C for 5–20 kh in air+10 vol%H₂O to study interdiffusion rates. Here, Thermo-Calc/DICTRA was used to reproduce the observed differences, and microstructures were compared. Based on the agreement between calculated and observed rates, simulations were projected past the experimental exposures, utilizing ß-depletion as lifetime criteria.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1975339

Alternate ID(s):: OSTI ID: 2000127

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Journal Issue: 1 Vol. 219; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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