Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks

Gonzalez, Miguel I.; Kapelewski, Matthew T.; Bloch, Eric D.; Milner, Phillip J.; Reed, Douglas A.; Hudson, Matthew R.; Mason, Jarad A.; Barin, Gokhan; Brown, Craig M.; Long, Jeffrey R.

doi:10.1021/jacs.7b13825

Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks

Journal Article · Thu Feb 15 04:00:00 EST 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b13825· OSTI ID:1974037

Gonzalez, Miguel I. ^[1]; Kapelewski, Matthew T. ^[1]; ^[2]; Milner, Phillip J. ^[1]; Reed, Douglas A. ^[1]; Hudson, Matthew R. ^[3]; Mason, Jarad A. ^[4]; Barin, Gokhan ^[1]; Brown, Craig M. ^[5]; ^[6]

Univ. of California, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Univ. of Delaware, Newark, DE (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Univ. of California, Berkeley, CA (United States); Harvard Univ., Cambridge, MA (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Delaware, Newark, DE (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Materials Sciences Division; Univ. of California, Berkeley, CA (United States)

Purification of the C₈ alkylaromatics o-xylene, m-xylene, p-xylene, and ethylbenzene remains among the most challenging industrial separations, due to the similar shapes, boiling points, and polarities of these molecules. We report the evaluation of the metal-organic frameworks Co₂(dobdc) (dobdc^4- = 2,5-dioxido-1,4-benzenedicarboxylate) and Co₂( m-dobdc) ( m-dobdc^4- = 4,6-dioxido-1,3-benzenedicarboxylate) for the separation of xylene isomers using single-component adsorption isotherms and multicomponent breakthrough measurements. Remarkably, Co₂(dobdc) distinguishes among all four molecules, with binding affinities that follow the trend o-xylene > ethylbenzene > m-xylene > p-xylene. Multicomponent liquid-phase adsorption measurements further demonstrate that Co₂(dobdc) maintains this selectivity over a wide range of concentrations. Structural characterization by single-crystal X-ray diffraction reveals that both frameworks facilitate the separation through the extent of interaction between each C₈ guest molecule with two adjacent cobalt(II) centers, as well as the ability of each isomer to pack within the framework pores. Moreover, counter to the presumed rigidity of the M₂(dobdc) structure, Co₂(dobdc) exhibits an unexpected structural distortion in the presence of either o-xylene or ethylbenzene that enables the accommodation of additional guest molecules.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Institutes of Health (NIH)

Grant/Contract Number:: AC02-05CH11231; SC0001015; AC02-06CH11357

OSTI ID:: 1974037

Alternate ID(s):: OSTI ID: 1460856

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 9 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks

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