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U.S. Department of Energy
Office of Scientific and Technical Information

July 2022 Semiannual Saltstone Toxicity Characteristic Leaching Procedure (TCLP) Results

Technical Report ·
DOI:https://doi.org/10.2172/1972838· OSTI ID:1972838

The aqueous waste from Tank 50 (salt solution) is sampled semiannually for transfers to the Saltstone Production Facility (SPF). Salt solution is treated at SPF and disposed of in the Salstone Disposal Facility (SDF). Per request of customer, X-TTR-Z-00025, Revision 0, two SDF waste form (salstone) samples were prepared in the Savannah River National Laboratory (SRNL) from the Tank 50 Waste Acceptance Criteria (WAC) sample and Z-Area premix material for the July 2022 Semiannual Toxicity Characteristic Leaching Procedure (TCLP) samples. One sample contained a Full Premix which included 10:45:45 (by weight) of cement, slag and fly ash. The second sample contained 60:40 (by weight) of slag and fly ash only referred to as the "Cement-Free grout sample." Results from this technical report support Task 2: 'Grout Leaching Analyses' of the Task Technical Request (TTR) prepared by Savannah River Mission Completion (SRMC). After at least 28 days cured, a sample of each of the SDF waste forms was collected and shipped to a certified laboratory for analysis using Toxicity Characteristic Leaching Procedure (TCLP). The July 2022 semiannual salstone (Full Premix) and the Cement-Free grout samples met the South Carolina (SC) Code of Regulations for Hazardous Waste Management Regulations (HWMR) 61-79.261.24 and 61-79-268.48 requirements for the non-hazardous waste form with respect to Resource Conservation and Recovery Act (RCRA) metals and Underlying Hazardous Constituents (UHCs), and also met the SPF WAC that was in effect at the time of the tank sampling.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States); Savannah River National Laboratory (SRNL), Aiken, SC (United States)
Sponsoring Organization:
USDOE Office of Environmental Management (EM)
DOE Contract Number:
89303321CEM000080
OSTI ID:
1972838
Report Number(s):
SRNL--STI-2022-00591
Country of Publication:
United States
Language:
English