Na 3 Zr 2 Si 2 PO 12 Solid Electrolyte Membrane for High‐Performance Seawater Battery

Li, Mengya; Dixit, Marm; Essehli, Rachid; Jafta, Charl J.; Amin, Ruhul; Balasubramanian, Mahalingam; Belharouak, Ilias

doi:10.1002/advs.202300920

Na ₃ Zr ₂ Si ₂ PO ₁₂ Solid Electrolyte Membrane for High‐Performance Seawater Battery

Journal Article · Wed Apr 12 00:00:00 EDT 2023 · Advanced Science

DOI:https://doi.org/10.1002/advs.202300920· OSTI ID:1969776

Li, Mengya ^[1]; Dixit, Marm ^[1]; Essehli, Rachid ^[1]; Jafta, Charl J. ^[1]; Amin, Ruhul ^[1]; Balasubramanian, Mahalingam ^[1]; ^[1]

Electrification and Energy Infrastructures Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA

Abstract

Seawater batteries (SWBs) have gained tremendous interest in the electrochemical energy storage research field because of their low cost, natural abundance, and potential use for long‐duration energy storage. Advancing a SWB to demonstration projects is plagued by the poor electrochemical performance stemming from the poor interfaces of the solid electrolyte (SE), as well as the structural and chemical instabilities and sluggish ionic transport properties. In this study, the anode compartment of a surrogate SWB is constructed with a Na | SE | hard carbon configuration, and tailored dopants are introduced into the Nasicon‐type Na ₃ Zr ₂ Si ₂ PO ₁₂ (NZSP) SE membrane. After doping with TiO ₂ , a much more densely packed pellet with uniformly distributed porous structure is obtained. Changes in surface chemistry and local structure in the bulk are observed, which are believed to contribute to the improved ionic conductivity and higher critical current density of the TiO ₂ ‐doped NZSP. Stable cycling performance with reversible capacities based on different Na storage mechanisms are also demonstrated.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1969776

Alternate ID(s):: OSTI ID: 1975349
OSTI ID: 1983476

Journal Information:: Advanced Science, Journal Name: Advanced Science Journal Issue: 17 Vol. 10; ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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