Hydrodynamics Change Tafel Slopes in Electrochemical CO 2 Reduction on Copper

Watkins, Nicholas B.; Schiffer, Zachary J.; Lai, Yungchieh; Musgrave, III, Charles B.; Atwater, Harry A.; Goddard, III, William A.; Agapie, Theodor; Peters, Jonas C.; Gregoire, John M.

doi:10.1021/acsenergylett.3c00442

Hydrodynamics Change Tafel Slopes in Electrochemical CO ₂ Reduction on Copper

Journal Article · Thu Apr 13 00:00:00 EDT 2023 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.3c00442· OSTI ID:1969771

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Liquid Sunlight Alliance, California Institute of Technology, Pasadena, California 91125, United States, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States
Liquid Sunlight Alliance, California Institute of Technology, Pasadena, California 91125, United States, Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, United States
Liquid Sunlight Alliance, California Institute of Technology, Pasadena, California 91125, United States, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States, Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, United States

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Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0021266

OSTI ID:: 1969771

Alternate ID(s):: OSTI ID: 1973388

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 5 Vol. 8; ISSN 2380-8195

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (33)

Gastight rotating cylinder electrode: Toward decoupling mass transport and intrinsic kinetics in electrocatalysis Jang, Joonbaek; Rüscher, Martina; Winzely, Maximilian AIChE Journal, Vol. 68, Issue 5 https://doi.org/10.1002/aic.17605	journal	January 2022
Competition between H and CO for Active Sites Governs Copper-Mediated Electrosynthesis of Hydrocarbon Fuels Schreier, Marcel; Yoon, Youngmin; Jackson, Megan N. Angewandte Chemie International Edition, Vol. 57, Issue 32 https://doi.org/10.1002/anie.201806051	journal	July 2018
In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene Thevenon, Arnaud; Rosas-Hernández, Alonso; Peters, Jonas C. Angewandte Chemie International Edition, Vol. 58, Issue 47 https://doi.org/10.1002/anie.201907935	journal	October 2019
The rotating cylinder electrode: a review of development Gabe, D. R.; Walsh, F. C. Journal of Applied Electrochemistry, Vol. 13, Issue 1 https://doi.org/10.1007/BF00615883	journal	January 1983
Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions Gupta, N.; Gattrell, M.; MacDougall, B. Journal of Applied Electrochemistry, Vol. 36, Issue 2 https://doi.org/10.1007/s10800-005-9058-y	journal	October 2005
Effects of mass transfer on the electrocatalytic CO 2 reduction on Cu Lim, C. F. C.; Harrington, D. A.; Marshall, A. T. Electrochimica Acta, Vol. 238 https://doi.org/10.1016/j.electacta.2017.04.017	journal	June 2017
Temperature dependence of diffusion coefficient of carbon monoxide in water: A molecular dynamics study Poudyal, Ishwor; Adhikari, Narayan P. Journal of Molecular Liquids, Vol. 194 https://doi.org/10.1016/j.molliq.2014.01.004	journal	June 2014
Toward CO ₂ Electroreduction under Controlled Mass Flow Conditions: A Combined Inverted RDE and Gas Chromatography Approach Moreno-García, Pavel; Kovács, Noémi; Grozovski, Vitali Analytical Chemistry, Vol. 92, Issue 6 https://doi.org/10.1021/acs.analchem.9b04999	journal	February 2020
Continuum Modeling of Porous Electrodes for Electrochemical Synthesis Bui, Justin C.; Lees, Eric W.; Pant, Lalit M. Chemical Reviews, Vol. 122, Issue 12 https://doi.org/10.1021/acs.chemrev.1c00901	journal	May 2022
Progress and Perspectives of Electrochemical CO ₂ Reduction on Copper in Aqueous Electrolyte Nitopi, Stephanie; Bertheussen, Erlend; Scott, Soren B. Chemical Reviews, Vol. 119, Issue 12 https://doi.org/10.1021/acs.chemrev.8b00705	journal	April 2019
Analysis of the Reactive CO₂ Surface Flux in Electrocatalytic Aqueous Flow Reactors Lin, Tiras Y.; Baker, Sarah E.; Duoss, Eric B. Industrial & Engineering Chemistry Research, Vol. 60, Issue 31 https://doi.org/10.1021/acs.iecr.1c01851	journal	July 2021
An Algorithm for the Extraction of Tafel Slopes Agbo, Peter; Danilovic, Nemanja The Journal of Physical Chemistry C, Vol. 123, Issue 50 https://doi.org/10.1021/acs.jpcc.9b06820	journal	November 2019
Characterizing CO₂ Reduction Catalysts on Gas Diffusion Electrodes: Comparing Activity, Selectivity, and Stability of Transition Metal Catalysts Sassenburg, Mark; de Rooij, Reinier; Nesbitt, Nathan T. ACS Applied Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1021/acsaem.2c00160	journal	May 2022
Sequential Cascade Electrocatalytic Conversion of Carbon Dioxide to C–C Coupled Products No authors listed ACS Applied Energy Materials, Vol. 2, Issue 6 https://doi.org/10.1021/acsaem.9b00791	journal	May 2019
Dramatic HER Suppression on Ag Electrodes via Molecular Films for Highly Selective CO ₂ to CO Reduction Thevenon, Arnaud; Rosas-Hernández, Alonso; Fontani Herreros, Alex M. ACS Catalysis, Vol. 11, Issue 8 https://doi.org/10.1021/acscatal.1c00338	journal	March 2021
Using pH Dependence to Understand Mechanisms in Electrochemical CO Reduction Kastlunger, Georg; Wang, Lei; Govindarajan, Nitish ACS Catalysis, Vol. 12, Issue 8 https://doi.org/10.1021/acscatal.1c05520	journal	March 2022
Standards and Protocols for Data Acquisition and Reporting for Studies of the Electrochemical Reduction of Carbon Dioxide Clark, Ezra L.; Resasco, Joaquin; Landers, Alan ACS Catalysis, Vol. 8, Issue 7 https://doi.org/10.1021/acscatal.8b01340	journal	May 2018
Breaking Scaling Relationships in CO₂ Reduction on Copper Alloys with Organic Additives Lai, Yungchieh; Watkins, Nicholas B.; Rosas-Hernández, Alonso ACS Central Science, Vol. 7, Issue 10 https://doi.org/10.1021/acscentsci.1c00860	journal	October 2021
Narrow Pressure Stability Window of Gas Diffusion Electrodes Limits the Scale-Up of CO₂ Electrolyzers Baumgartner, Lorenz M.; Koopman, Christel I.; Forner-Cuenca, Antoni ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 14 https://doi.org/10.1021/acssuschemeng.2c00195	journal	March 2022
Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide Resasco, Joaquin; Chen, Leanne D.; Clark, Ezra Journal of the American Chemical Society, Vol. 139, Issue 32 https://doi.org/10.1021/jacs.7b06765	journal	August 2017
Electrochemical CO Reduction Builds Solvent Water into Oxygenate Products Lum, Yanwei; Cheng, Tao; Goddard, William A. Journal of the American Chemical Society, Vol. 140, Issue 30 https://doi.org/10.1021/jacs.8b03986	journal	July 2018
In Situ Infrared Spectroscopy Reveals Persistent Alkalinity near Electrode Surfaces during CO ₂ Electroreduction Yang, Kailun; Kas, Recep; Smith, Wilson A. Journal of the American Chemical Society, Vol. 141, Issue 40 https://doi.org/10.1021/jacs.9b07000	journal	September 2019
Competition between CO ₂ Reduction and Hydrogen Evolution on a Gold Electrode under Well-Defined Mass Transport Conditions Goyal, Akansha; Marcandalli, Giulia; Mints, Vladislav A. Journal of the American Chemical Society, Vol. 142, Issue 9 https://doi.org/10.1021/jacs.9b10061	journal	February 2020
Measurement and Correlation of Solubility Data for CO ₂ in NaHCO ₃ Aqueous Solution Han, Xiaoying; Yu, Zhihui; Qu, Jingkui Journal of Chemical & Engineering Data, Vol. 56, Issue 4 https://doi.org/10.1021/je1011168	journal	April 2011
Bayesian data analysis reveals no preference for cardinal Tafel slopes in CO2 reduction electrocatalysis Limaye, Aditya M.; Zeng, Joy S.; Willard, Adam P. Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-20924-y	journal	January 2021
Monitoring global carbon emissions in 2021 Liu, Zhu; Deng, Zhu; Davis, Steven J. Nature Reviews Earth & Environment, Vol. 3, Issue 4 https://doi.org/10.1038/s43017-022-00285-w	journal	March 2022
Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO ₂ reduction electrocatalysts Lobaccaro, Peter; Singh, Meenesh R.; Clark, Ezra Lee Physical Chemistry Chemical Physics, Vol. 18, Issue 38 https://doi.org/10.1039/C6CP05287H	journal	January 2016
The role of atomic carbon in directing electrochemical CO ₍₂₎ reduction to multicarbon products Peng, Hongjie; Tang, Michael T.; Liu, Xinyan Energy & Environmental Science, Vol. 14, Issue 1 https://doi.org/10.1039/D0EE02826F	journal	January 2021
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Reactor design and integration with product detection to accelerate screening of electrocatalysts for carbon dioxide reduction Jones, Ryan J. R.; Wang, Yu; Lai, Yungchieh Review of Scientific Instruments, Vol. 89, Issue 12 https://doi.org/10.1063/1.5049704	journal	December 2018
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Membraneless laminar flow cell for electrocatalytic CO ₂ reduction with liquid product separation Monroe, Morgan M.; Lobaccaro, Peter; Lum, Yanwei Journal of Physics D: Applied Physics, Vol. 50, Issue 15 https://doi.org/10.1088/1361-6463/aa6359	journal	March 2017
Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution Hori, Yoshio; Kikuchi, Katsuhei; Murata, Akira Chemistry Letters, Vol. 15, Issue 6 https://doi.org/10.1246/cl.1986.897	journal	June 1986

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Hydrodynamics Change Tafel Slopes in Electrochemical CO 2 Reduction on Copper

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References (33)

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Hydrodynamics Change Tafel Slopes in Electrochemical CO ₂ Reduction on Copper