Part II: Predicting performance of $$\mathrm{DOWEX 21K}$$ resin for remediation of comingled contaminants in groundwater

Journal Article · Thu Mar 02 00:00:00 EST 2023 · Journal of Environmental Chemical Engineering (Online)

DOI:https://doi.org/10.1016/j.jece.2023.109620· OSTI ID:1969010

Saslow, Sarah A. ^[1]; Levitskaia, Tatiana G. ^[1]; Cordova, Elsa A. ^[1]; Avalos, Nancy M. ^[1]; Boglaienko, Daria ^[1]; Fang, Yilin ^[1]; Song, Xuehang ^[1]; Lawter, Amanda ^[1]; Emerson, Hilary ^[1]; Szecsody, Jim ^[1]; Johnson, Christian D. ^[1]; Pearce, Carolyn I. ^[1]; Freedman, Vicky L. ^[1]; Mackley, Rob D. ^[1]

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1. Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

The selectivity of ion exchange (IX) resins for aqueous contaminant removal can be impacted by changing concentrations of competing natural groundwater ions. In a two-part investigation, the Hanford Site 200 West Area pump-and-treat (P&T) facility in Washington State, USA is used as a case study to evaluate the performance of two IX resins for groundwater treatment: Purolite® A532E for pertechnetate (TcO₄^-) removal, explored in Part I, and DOWEX 21K (DOWEX) for uranium (U) removal. In Part II, DOWEX selectivity for U, as uranyl carbonate species, and uptake kinetics is quantified in a series of laboratory-scale aqueous batch experiments containing Hanford-relevant concentrations of competing anions nitrate (NO₃^-), sulfate (SO₄^2-), chloride (Cl^-), and carbonate (CO₃^2-), as well as co-mingled contaminant TcO_4-. Here the results demonstrate that DOWEX trimethylammonium functional groups are highly selective for U carbonate species (85–100 % uptake) under all conditions investigated. Only NO_3- concentrations of 100 mM were shown to decrease U removal, with the extent (85–99 %) depending on competing anion concentrations present in solution. However, at the highest NO₃^- concentrations reported for groundwaters treated at the P&T facility (25 mM), the effect on U uptake is minimal. The batch sorption results are modeled to obtain chloride normalized equilibrium exchange coefficients (K) for predicting DOWEX performance: K_SO4--/Cl- = 2.0, K_NO3-/Cl- = 5.0, K_HCO3-/Cl- = 1.5, K_TcO4-/Cl- = 2,000, and K_U/Cl- = 50,000. These K values predict little effect of current and future influent chemistries on U removal by DOWEX, where both uranyl carbonate species and TcO₄^- are removed such that effluent concentrations meet groundwater treatment requirements.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• Grant/Contract Number: AC05-76RL01830
• OSTI ID: 1969010
• Report Number(s): PNNL-SA-178093
• Journal Information: Journal of Environmental Chemical Engineering (Online), Journal Name: Journal of Environmental Chemical Engineering (Online) Journal Issue: 3 Vol. 11; ISSN 2213-3437
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
Hanford
anion exchange
pump-and-treat
technetium
uranium