Charge Density Wave in Kagome Lattice Intermetallic ScV6Sn6

Suriya Arachchige, Hasitha W.; Meier, William R.; Marshall, Madalynn; Matsuoka, Takahiro; Xue, Rui; McGuire, Michael A.; Hermann, Raphael P.; Cao, Huibo; Mandrus, David

doi:10.1103/physrevlett.129.216402

Charge Density Wave in Kagome Lattice Intermetallic ScV₆Sn₆

Journal Article · Fri Nov 18 00:00:00 EST 2022 · Physical Review Letters

DOI:https://doi.org/10.1103/physrevlett.129.216402· OSTI ID:1965245

Suriya Arachchige, Hasitha W. ^[1]; ^[1]; Marshall, Madalynn ^[2]; ^[1]; Xue, Rui ^[1]; ^[2]; ^[2]; ^[2]; Mandrus, David ^[3]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Materials hosting kagome lattices have drawn interest for the diverse magnetic and electronic states generated by geometric frustration. In the AV₃Sb₅ compounds (A=K, Rb, Cs), stacked vanadium kagome layers give rise to unusual charge density waves (CDW) and superconductivity. In this work, we report single-crystal growth and characterization of ScV₆Sn₆, a hexagonal HfFe₆Ge₆-type compound that shares this structural motif. We identify a first-order phase transition at 92 K. Single crystal x-ray and neutron diffraction reveal a charge density wave modulation of the atomic lattice below this temperature. This is a distinctly different structural mode than that observed in the AV₃Sb₅ compounds, but both modes have been anticipated in kagome metals. The diverse HfFe₆Ge₆ family offers more opportunities to tune ScV₆Sn₆ and explore density wave order in kagome lattice materials.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Gordon and Betty Moore Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1965245

Journal Information:: Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 21 Vol. 129; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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