Active site identification and CO oxidation in UiO-66-XX thin films

Eads, Calley N.; Hu, Tianhao; Tian, Yi; Kisslinger, Kim; Tenney, Samuel A.; Head, Ashley R.

doi:10.1088/1361-6528/acbcd8

Active site identification and CO oxidation in UiO-66-XX thin films

Journal Article · Sun Mar 05 23:00:00 EST 2023 · Nanotechnology

DOI:https://doi.org/10.1088/1361-6528/acbcd8· OSTI ID:1963191

Eads, Calley N. ^[1]; ^[2]; Tian, Yi ^[3]; Kisslinger, Kim ^[1]; Tenney, Samuel A. ^[1]; ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States)

Metal-organic frameworks (MOFs) offer an intrinsically porous and chemically tunable platform for gas adsorption, separation, and catalysis. Herein we investigate thin film derivatives of the well-studied Zr–O based MOF powders to understand their adsorption properties and reactivity with their adaption to thin films, involving diverse functionality with the incorporation of different linker groups and the inclusion of embedded metal nanoparticles: UiO-66, UiO-66-NH₂, and Pt@UiO-66-NH₂. Using transflectance IR spectroscopy, we determine the active sites in each film upon consideration of the acid-base properties of the adsorption sites and guest species, and perform metal-based catalysis with CO oxidation of a Pt@UiO-66-NH₂ film. Our study shows how surface science characterization techniques can be used to characterize the reactivity and the chemical and electronic structure of MOFs.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: SC0012704

OSTI ID:: 1963191

Report Number(s):: BNL-224157-2023-JAAM

Journal Information:: Nanotechnology, Journal Name: Nanotechnology Journal Issue: 20 Vol. 34; ISSN 0957-4484

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Active site identification and CO oxidation in UiO-66-XX thin films

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