Highly reversible Li2RuO3 cathodes in sulfide-based all solid-state lithium batteries

Wu, Yuqi; Zhou, Ke; Ren, Fucheng; Ha, Yang; Liang, Ziteng; Zheng, Xuefan; Wang, Zhenyu; Yang, Wu; Zhang, Maojie; Luo, Mingzeng; Battaglia, Corsin; Yang, Wanli; Zhu, Lingyun; Gong, Zhengliang; Yang, Yong

doi:10.1039/d2ee01067d

Title: Highly reversible Li₂RuO₃ cathodes in sulfide-based all solid-state lithium batteries

Journal Article · Wed Jul 06 00:00:00 EDT 2022 · Energy & Environmental Science

DOI:https://doi.org/10.1039/d2ee01067d· OSTI ID:1963045

Wu, Yuqi ^[1]; Zhou, Ke ^[2]; Ren, Fucheng ^[1];

^[3]; Liang, Ziteng ^[1]; Zheng, Xuefan ^[1]; Wang, Zhenyu ^[4]; Yang, Wu ^[1]; Zhang, Maojie ^[1]; Luo, Mingzeng ^[1]; Battaglia, Corsin ^[5];

^[3]; Zhu, Lingyun ^[4];

^[1];

^[1]

Xiamen Univ. (China)
Xiamen Univ. (China); Swiss Federal Laboratories for Materials Science and Technology (Empa), Dübendorf (Switzerland)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Guilin Electrical Equipment Scientific Research Institute Co., Ltd, Guilin (China)
Swiss Federal Laboratories for Materials Science and Technology (Empa), Dübendorf (Switzerland)

The practical application of high-capacity lithium-rich cathode materials in lithium-ion batteries has been largely restricted by severe side reactions with electrolytes. Herein, we report a highly stable lithium-rich Li₂RuO₃ cathode by forming a passivating solid electrolyte interphase at the interface with a sulfide solid electrolyte such as Li₆PS₅Cl in all-solid-state lithium batteries (ASSLBs), which efficiently suppresses serious parasitic interfacial reactions and fast-increasing interfacial impedance normally observed in liquid electrolytes. The exceptionally high interfacial stability of the Li₂RuO₃/sulfide electrolyte interface contributes to a high reversible capacity of 257 mA h g^–1 of Li₂RuO₃ at 0.05C rate, and unprecedented cycling stability with 90% capacity retention after 1000 cycles at 1C rate. Iin this work, comprehensive experimental characterizations and first-principles calculations disclose that electronically insulating interfacial reaction products forming at the interface between the Li₂RuO₃ cathode and Li₆PS₅Cl facilitate the formation of a stable and passivating interphase and block the continuous side reactions. Importantly, reversible oxygen redox activity of Li₂RuO₃ is well-maintained in this configuration of ASSLBs even after 600 cycles, thus the common voltage decay of the Li-rich material is also significantly reduced. These new discoveries demonstrate the critical role of interface design for achieving prolonged cycling stability of lithium-rich cathode materials.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-05CH11231; 21875196; 21935009; 22021001; 2021YFB2401800; 2019H0003

OSTI ID:: 1963045

Journal Information:: Energy & Environmental Science, Vol. 15, Issue 8; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (68)

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
In Situ Generated Li ₂ S–C Nanocomposite for High-Capacity and Long-Life All-Solid-State Lithium Sulfur Batteries with Ultrahigh Areal Mass Loading Yan, Hefeng; Wang, Hongchun; Wang, Donghao Nano Letters, Vol. 19, Issue 5 https://doi.org/10.1021/acs.nanolett.9b00882	journal	March 2019
A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE41655K	journal	January 2014
A reversible oxygen redox reaction in bulk-type all-solid-state batteries Nagao, Kenji; Nagata, Yuka; Sakuda, Atsushi Science Advances, Vol. 6, Issue 25 https://doi.org/10.1126/sciadv.aax7236	journal	June 2020
Influence of Ti ⁴⁺ on the Electrochemical Performance of Li-Rich Layered Oxides - High Power and Long Cycle Life of Li ₂ Ru _{1– x} Ti _x O ₃ Cathodes Kalathil, Abdul Kareem; Arunkumar, Paulraj; Kim, Da Hye ACS Applied Materials & Interfaces, Vol. 7, Issue 13 https://doi.org/10.1021/am507951x	journal	March 2015
Nanostructure Transformation as a Signature of Oxygen Redox in Li-Rich 3d and 4d Cathodes Grenier, Antonin; Kamm, Gabrielle E.; Li, Yixuan Journal of the American Chemical Society, Vol. 143, Issue 15 https://doi.org/10.1021/jacs.1c00497	journal	April 2021
Improving the Electrochemical Performance of Li ₂ RuO ₃ through Chemical Substitution: A Case Study of ( x )LiCoO ₂ ‐(1‐ x )Li ₂ RuO ₃ Solid Solution ( x ≤0.4) Neelakantaiah, Ramesha R.; Dasari, Bosu Babu; Ette, Pedda Masthanaiah ChemElectroChem, Vol. 7, Issue 1 https://doi.org/10.1002/celc.201902059	journal	December 2019
Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials Lee, Jinhyuk; Kitchaev, Daniil A.; Kwon, Deok-Hwang Nature, Vol. 556, Issue 7700 https://doi.org/10.1038/s41586-018-0015-4	journal	April 2018
Inhibition of oxygen dimerization by local symmetry tuning in Li-rich layered oxides for improved stability Ning, Fanghua; Li, Biao; Song, Jin Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18423-7	journal	October 2020
Passivation of the Cathode–Electrolyte Interface for 5 V-Class All-Solid-State Batteries Liu, Gaozhan; Lu, Yong; Wan, Hongli ACS Applied Materials & Interfaces, Vol. 12, Issue 25 https://doi.org/10.1021/acsami.0c03610	journal	May 2020
Oxygen Vacancy Diffusion and Condensation in Lithium‐Ion Battery Cathode Materials Lee, Sanghan; Jin, Wooyoung; Kim, Su Hwan Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201904469	journal	June 2019
Influence of Carbon Additives on the Decomposition Pathways in Cathodes of Lithium Thiophosphate-Based All-Solid-State Batteries Walther, Felix; Randau, Simon; Schneider, Yannik Chemistry of Materials, Vol. 32, Issue 14 https://doi.org/10.1021/acs.chemmater.0c01825	journal	July 2020
Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes Tan, Darren H. S.; Chen, Yu-Ting; Yang, Hedi Science, Vol. 373, Issue 6562 https://doi.org/10.1126/science.abg7217	journal	September 2021
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations Zhu, Yizhou; He, Xingfeng; Mo, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 42 https://doi.org/10.1021/acsami.5b07517	journal	October 2015
Solid Electrolyte: the Key for High-Voltage Lithium Batteries Li, Juchuan; Ma, Cheng; Chi, Miaofang Advanced Energy Materials, Vol. 5, Issue 4 https://doi.org/10.1002/aenm.201401408	journal	October 2014
Interface Stability of Argyrodite Li ₆ PS ₅ Cl toward LiCoO ₂ , LiNi _1/3 Co _1/3 Mn _1/3 O ₂ , and LiMn ₂ O ₄ in Bulk All-Solid-State Batteries Auvergniot, Jérémie; Cassel, Alice; Ledeuil, Jean-Bernard Chemistry of Materials, Vol. 29, Issue 9 https://doi.org/10.1021/acs.chemmater.6b04990	journal	April 2017
LiPO2F2 electrolyte additive for high-performance Li-rich cathode material Jiang, Bing; Li, Jingru; Luo, Bi Journal of Energy Chemistry, Vol. 60 https://doi.org/10.1016/j.jechem.2021.01.024	journal	September 2021
Distinct Oxygen Redox Activities in Li₂MO₃ (M = Mn, Ru, Ir) Zhuo, Zengqing; Dai, Kehua; Wu, Jinpeng ACS Energy Letters, Vol. 6, Issue 10 https://doi.org/10.1021/acsenergylett.1c01101	journal	September 2021
Engineering the interface between LiCoO ₂ and Li ₁₀ GeP ₂ S ₁₂ solid electrolytes with an ultrathin Li ₂ CoTi ₃ O ₈ interlayer to boost the performance of all-solid-state batteries Wang, Chuan-Wei; Ren, Fu-Cheng; Zhou, Yao Energy & Environmental Science, Vol. 14, Issue 1 https://doi.org/10.1039/D0EE03212C	journal	January 2021
Understanding the Stability for Li-Rich Layered Oxide Li ₂ RuO ₃ Cathode Li, Biao; Shao, Ruiwen; Yan, Huijun Advanced Functional Materials, Vol. 26, Issue 9 https://doi.org/10.1002/adfm.201504836	journal	February 2016
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering Yang, Wanli; Devereaux, Thomas P. Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.04.018	journal	June 2018
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
The Working Principle of a Li ₂ CO ₃ /LiNbO ₃ Coating on NCM for Thiophosphate-Based All-Solid-State Batteries Walther, Felix; Strauss, Florian; Wu, Xiaohan Chemistry of Materials, Vol. 33, Issue 6 https://doi.org/10.1021/acs.chemmater.0c04660	journal	March 2021
Electrochemo‐Mechanical Effects on Structural Integrity of Ni‐Rich Cathodes with Different Microstructures in All Solid‐State Batteries Liu, Xiangsi; Zheng, Bizhu; Zhao, Jun Advanced Energy Materials, Vol. 11, Issue 8 https://doi.org/10.1002/aenm.202003583	journal	January 2021
Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study Auvergniot, Jérémie; Cassel, Alice; Foix, Dominique Solid State Ionics, Vol. 300 https://doi.org/10.1016/j.ssi.2016.11.029	journal	February 2017
The effect of electrochemically inactive Ti substituted for Ru in Li2Ru1-Ti O3 on structure and electrochemical performance Yao, Ye; Zhang, Lu; Sigel, Florian Journal of Energy Chemistry, Vol. 60 https://doi.org/10.1016/j.jechem.2020.12.037	journal	September 2021
Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes Eum, Donggun; Kim, Byunghoon; Kim, Sung Joo Nature Materials, Vol. 19, Issue 4 https://doi.org/10.1038/s41563-019-0572-4	journal	January 2020
Impact of Structural Transformation on Electrochemical Performances of Li-Rich Cathode Materials: The Case of Li ₂ RuO ₃ Zheng, Feng; Zheng, Shiyao; Zhang, Peng The Journal of Physical Chemistry C, Vol. 123, Issue 22 https://doi.org/10.1021/acs.jpcc.9b02887	journal	May 2019
Computation-Accelerated Design of Materials and Interfaces for All-Solid-State Lithium-Ion Batteries Nolan, Adelaide M.; Zhu, Yizhou; He, Xingfeng Joule, Vol. 2, Issue 10 https://doi.org/10.1016/j.joule.2018.08.017	journal	October 2018
Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification Ohta, N.; Takada, K.; Zhang, L. Advanced Materials, Vol. 18, Issue 17, p. 2226-2229 https://doi.org/10.1002/adma.200502604	journal	September 2006
Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes Assat, Gaurav; Foix, Dominique; Delacourt, Charles Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02291-9	journal	December 2017
Bidirectionally Compatible Buffering Layer Enables Highly Stable and Conductive Interface for 4.5 V Sulfide‐Based All‐Solid‐State Lithium Batteries Wang, Longlong; Sun, Xingwei; Ma, Jun Advanced Energy Materials, Vol. 11, Issue 32 https://doi.org/10.1002/aenm.202100881	journal	June 2021
Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
Editors' Choice—Practical Assessment of Anionic Redox in Li-Rich Layered Oxide Cathodes: A Mixed Blessing for High Energy Li-Ion Batteries Assat, Gaurav; Delacourt, Charles; Corte, Daniel Alves Dalla Journal of The Electrochemical Society, Vol. 163, Issue 14 https://doi.org/10.1149/2.0531614jes	journal	January 2016
Degradation Mechanisms at the Li ₁₀ GeP ₂ S ₁₂ /LiCoO ₂ Cathode Interface in an All-Solid-State Lithium-Ion Battery Zhang, Wenbo; Richter, Felix H.; Culver, Sean P. ACS Applied Materials & Interfaces, Vol. 10, Issue 26 https://doi.org/10.1021/acsami.8b05132	journal	June 2018
Cycling mechanism of Li2MnO3: Li–CO2 batteries and commonality on oxygen redox in cathode materials Zhuo, Zengqing; Dai, Kehua; Qiao, Ruimin Joule, Vol. 5, Issue 4 https://doi.org/10.1016/j.joule.2021.02.004	journal	April 2021
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries Zhu, Yizhou; He, Xingfeng; Mo, Yifei Journal of Materials Chemistry A, Vol. 4, Issue 9 https://doi.org/10.1039/C5TA08574H	journal	January 2016
Observation of Chemomechanical Failure and the Influence of Cutoff Potentials in All-Solid-State Li–S Batteries Ohno, Saneyuki; Koerver, Raimund; Dewald, Georg Chemistry of Materials, Vol. 31, Issue 8 https://doi.org/10.1021/acs.chemmater.9b00282	journal	March 2019
Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries Qiu, Bao; Zhang, Minghao; Wu, Lijun Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12108	journal	July 2016
XRD and XAFS study on structure and cation valence state of layered ruthenium oxide electrodes, Li2RuO3 and Li2Mn0.4Ru0.6O3, upon electrochemical cycling Mori, Daisuke; Kobayashi, Hironori; Okumura, Toyoki Solid State Ionics, Vol. 285 https://doi.org/10.1016/j.ssi.2015.09.025	journal	February 2016
High-performance Li ₆ PS ₅ Cl-based all-solid-state lithium-ion batteries Wang, Shuo; Xu, Xiaofu; Zhang, Xue Journal of Materials Chemistry A, Vol. 7, Issue 31 https://doi.org/10.1039/C9TA04289J	journal	January 2019
High-voltage positive electrode materials for lithium-ion batteries Li, Wangda; Song, Bohang; Manthiram, Arumugam Chemical Society Reviews, Vol. 46, Issue 10 https://doi.org/10.1039/C6CS00875E	journal	January 2017
Solvent-Engineered Design of Argyrodite Li ₆ PS ₅ X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity Zhou, Laidong; Park, Kern-Ho; Sun, Xiaoqi ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b01997	journal	November 2018
Covalency does not suppress O2 formation in 4d and 5d Li-rich O-redox cathodes House, Robert A.; Marie, John-Joseph; Park, Joohyuk Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23154-4	journal	May 2021
Solid-State Chemistries Stable with High-Energy Cathodes for Lithium-Ion Batteries Nolan, Adelaide M.; Liu, Yunsheng; Mo, Yifei ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01703	journal	September 2019
Deciphering Interfacial Chemical and Electrochemical Reactions of Sulfide‐Based All‐Solid‐State Batteries Wang, Changhong; Hwang, Sooyeon; Jiang, Ming Advanced Energy Materials, Vol. 11, Issue 24 https://doi.org/10.1002/aenm.202100210	journal	May 2021
Thin and Flexible Solid Electrolyte Membranes with Ultrahigh Thermal Stability Derived from Solution-Processable Li Argyrodites for All-Solid-State Li-Ion Batteries Kim, Dong Hyeon; Lee, Yong-Hyeok; Song, Yong Bae ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.0c00251	journal	February 2020
Interfacial Processes and Influence of Composite Cathode Microstructure Controlling the Performance of All-Solid-State Lithium Batteries Zhang, Wenbo; Weber, Dominik A.; Weigand, Harald ACS Applied Materials & Interfaces, Vol. 9, Issue 21 https://doi.org/10.1021/acsami.7b01137	journal	May 2017
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0207-z	journal	July 2018
High-Voltage Reactivity and Long-Term Stability of Cation-Disordered Rocksalt Cathodes Yue, Yuan; Ha, Yang; Giovine, Raynald Chemistry of Materials, Vol. 34, Issue 4 https://doi.org/10.1021/acs.chemmater.1c03115	journal	February 2022
Boosting the Electrochemical Performance of All‐Solid‐State Batteries with Sulfide Li ₆ PS ₅ Cl Solid Electrolyte Using Li ₂ WO ₄ ‐Coated LiCoO ₂ Cathode Sun, Zhen; Lai, Yanqing; lv, Na Advanced Materials Interfaces, Vol. 8, Issue 15 https://doi.org/10.1002/admi.202100624	journal	July 2021
Ni‐Rich Layered Cathode Materials with Electrochemo‐Mechanically Compliant Microstructures for All‐Solid‐State Li Batteries Jung, Sung Hoo; Kim, Un‐Hyuck; Kim, Jae‐Hyung Advanced Energy Materials, Vol. 10, Issue 6 https://doi.org/10.1002/aenm.201903360	journal	December 2019
Investigations on the Fundamental Process of Cathode Electrolyte Interphase Formation and Evolution of High-Voltage Cathodes Li, Qinghao; Wang, Yi; Wang, Xuelong ACS Applied Materials & Interfaces, Vol. 12, Issue 2 https://doi.org/10.1021/acsami.9b16727	journal	December 2019
Revealing Electronic Signatures of Lattice Oxygen Redox in Lithium Ruthenates and Implications for High-Energy Li-Ion Battery Material Designs Yu, Yang; Karayaylali, Pinar; Nowak, Stanisław H. Chemistry of Materials, Vol. 31, Issue 19 https://doi.org/10.1021/acs.chemmater.9b01821	journal	September 2019
Stacking Faults Hinder Lithium Insertion in Li ₂ RuO ₃ Han, Miao; Liu, Zepeng; Shen, Xing Advanced Energy Materials, Vol. 10, Issue 48 https://doi.org/10.1002/aenm.202002631	journal	November 2020
Injection of oxygen vacancies in the bulk lattice of layered cathodes Yan, Pengfei; Zheng, Jianming; Tang, Zhen-Kun Nature Nanotechnology, Vol. 14, Issue 6 https://doi.org/10.1038/s41565-019-0428-8	journal	April 2019
Unravelling the Chemistry and Microstructure Evolution of a Cathodic Interface in Sulfide-Based All-Solid-State Li-Ion Batteries Li, Xia; Ren, Zhouhong; Norouzi Banis, Mohammad ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01676	journal	September 2019
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
All-solid-state lithium batteries enabled by sulfide electrolytes: from fundamental research to practical engineering design Wang, Changhong; Liang, Jianwen; Zhao, Yang Energy & Environmental Science, Vol. 14, Issue 5 https://doi.org/10.1039/D1EE00551K	journal	January 2021
Liquid-phase syntheses of sulfide electrolytes for all-solid-state lithium battery Miura, Akira; Rosero-Navarro, Nataly Carolina; Sakuda, Atsushi Nature Reviews Chemistry, Vol. 3, Issue 3 https://doi.org/10.1038/s41570-019-0078-2	journal	February 2019
Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes Koerver, Raimund; Aygün, Isabel; Leichtweiß, Thomas Chemistry of Materials, Vol. 29, Issue 13 https://doi.org/10.1021/acs.chemmater.7b00931	journal	June 2017
Elucidating anionic oxygen activity in lithium-rich layered oxides Xu, Jing; Sun, Meiling; Qiao, Ruimin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03403-9	journal	March 2018
Li2MoO4 coated Ni-rich cathode for all-solid-state batteries Kwak, Hwan Wook; Park, Yong Joon Thin Solid Films, Vol. 660 https://doi.org/10.1016/j.tsf.2018.04.038	journal	August 2018
Insight of a Phase Compatible Surface Coating for Long‐Durable Li‐Rich Layered Oxide Cathode Hu, Sijiang; Li, Yu; Chen, Yuhua Advanced Energy Materials, Vol. 9, Issue 34 https://doi.org/10.1002/aenm.201901795	journal	July 2019
Observation of partial reduction of manganese in the lithium rich layered oxides, 0.4Li ₂ MnO ₃ –0.6LiNi _1/3 Co _1/3 Mn _1/3 O ₂ , during the first charge Shim, Hyung Cheoul; Kim, Donghan; Shin, Dongwook Physical Chemistry Chemical Physics, Vol. 19, Issue 2 https://doi.org/10.1039/C6CP07574F	journal	January 2017
Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques Zuo, Wenhua; Luo, Mingzeng; Liu, Xiangsi Energy & Environmental Science, Vol. 13, Issue 12 https://doi.org/10.1039/D0EE01694B	journal	January 2020
Tuning the Reversibility of Oxygen Redox in Lithium-Rich Layered Oxides Li, Biao; Yan, Huijun; Zuo, Yuxuan Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.6b04743	journal	March 2017
High Performance Li ₂ Ru _{1– y} Mn _y O ₃ (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding Sathiya, M.; Ramesha, K.; Rousse, G. Chemistry of Materials, Vol. 25, Issue 7 https://doi.org/10.1021/cm400193m	journal	March 2013

Similar Records

F and N Rich Solid Electrolyte for Stable All-Solid-State Battery

Journal Article · Sun Dec 26 00:00:00 EST 2021 · Advanced Functional Materials · OSTI ID:1963045

Wan, Hongli L.; Zhang, Jiaxun X.; Xia, Jiale L.; +4 more

Interface stability of LiCl-rich argyrodite Li₆PS₅Cl with propylene carbonate boosts high-performance lithium batteries

Journal Article · Fri Sep 25 00:00:00 EDT 2020 · Electrochimica Acta · OSTI ID:1963045

Li, Yang; Arnold, William; Jasinski, Jacek B.; +6 more

Different interfacial reactivity of lithium metal chloride electrolytes with high voltage cathodes determines solid-state battery performance

Journal Article · Fri Jul 29 00:00:00 EDT 2022 · Energy & Environmental Science · OSTI ID:1963045

Kochetkov, Ivan; Zuo, Tong-Tong; Ruess, Raffael; +5 more

Related Subjects

25 ENERGY STORAGE

Title: Highly reversible Li2RuO3 cathodes in sulfide-based all solid-state lithium batteries

Citation Formats

References (68)

Similar Records

Related Subjects

Title: Highly reversible Li₂RuO₃ cathodes in sulfide-based all solid-state lithium batteries