Donor–Acceptor Conjugated Copolymers Containing Transition-Metal Complex: Intrachain Magnetic Exchange Interactions and Magneto-Optical Activity

Liu, Xunshan; Xie, Jiaze; Niklas, Jens; Turner, Emigdio E.; Yuan, Dafei; Anderson, John S.; Rack, Jeffrey J.; Poluektov, Oleg G.; Yu, Luping

doi:10.1021/acs.chemmater.2c01433

Title: Donor–Acceptor Conjugated Copolymers Containing Transition-Metal Complex: Intrachain Magnetic Exchange Interactions and Magneto-Optical Activity

Journal Article · Thu Jun 16 00:00:00 EDT 2022 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.2c01433· OSTI ID:1962669

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^[3]; Turner, Emigdio E. ^[4];

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^[3]; Yu, Luping ^[2]

Zhejiang Sci-Tech Univ., Hangzhou (China); Univ. of Chicago, IL (United States)
Univ. of Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of New Mexico, Albuquerque, NM (United States)

A donor-acceptor conjugated copolymer containing thienothiophene (TT) (Donor) units and Co(II) complexes (Acceptor) has been synthesized and characterized. The studies of magnetic properties of the polymers by SQUID and EPR measurements showed antiferromagnetic exchange interaction between neighboring spin centers along with the polymer backbone through intrachain in-teractions. It is the first time that D-A conjugated polymer backbone serving as bridging ligands for magnetic couplings, making this type of polymers promising as magnetic materials. Moreover, the magneto-optical activity (MOA) of polymer LCP1 was char-acterized using magnetic circular dichroism (MCD) spectroscopy. It was found that the material exhibits a large magneto-optic rotation with a peak Verdet constant of 2980 deg*T^-1*m^-1 at 590 nm.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; Natural Science Foundation of Zhejiang Province; National Natural Science Foundation of China (NSFC); Zhejiang Sci-Tech University (ZSTU); National Science Foundation (NSF); Alfred P. Sloan Foundation; 3M

Grant/Contract Number:: AC02-06CH11357; LQ22B040003; 22105172; 21062113-Y; CHE 2102102; DMR-2002367; FG-2019-11497; CHE 1856492

OSTI ID:: 1962669

Journal Information:: Chemistry of Materials, Vol. 34, Issue 12; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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