Examining Effects of Negative to Positive Capacity Ratio in Three-Electrode Lithium-Ion Cells with Layered Oxide Cathode and Si Anode

Luo, Mei; F. Rodrigues, Marco-Tulio; Shaw, Leon L.; Abraham, Daniel P.

doi:10.1021/acsaem.2c00665

Examining Effects of Negative to Positive Capacity Ratio in Three-Electrode Lithium-Ion Cells with Layered Oxide Cathode and Si Anode

Journal Article · Mon May 02 00:00:00 EDT 2022 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.2c00665· OSTI ID:1962347

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Argonne National Lab. (ANL), Argonne, IL (United States); Illinois Institute of Technology, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Illinois Institute of Technology, Chicago, IL (United States)

The negative to positive electrode capacity ratio (N:P) is crucial for lithium-ion cell design because it affects both energy density and long-term performance. Here, the effect of N:P ratio on electrochemical performance has been investigated for NMC₅₃₂/Si cells containing a reference electrode. By monitoring individual electrode potentials, depths of lithiation/delithiation at the anode and cathode could be determined. The superior performance of the higher N:P cell, including greater reversibility, better capacity retention and lower impedance rise, can be attributed to smaller volume changes in the silicon particles during electrochemical cycling.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1962347

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 5 Vol. 5; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Examining Effects of Negative to Positive Capacity Ratio in Three-Electrode Lithium-Ion Cells with Layered Oxide Cathode and Si Anode

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