Quasi-one-dimensional Ising-like antiferromagnetism in the rare-earth perovskite oxide TbScO3

Zhao, Nan; Sheng, Jieming; Wang, Jinchen; Ge, Han; Li, Tiantian; Yang, Jiong; Wang, Shanmin; Miao, Ping; He, Hua; Tong, Xin; Bao, Wei; Guo, Er-Jia; Mole, Richard; Yu, Dehong; Podlesnyak, Andrey A.; Wu, Liusuo

doi:10.1103/physrevmaterials.7.034401

Title: Quasi-one-dimensional Ising-like antiferromagnetism in the rare-earth perovskite oxide TbScO₃

Journal Article · Thu Mar 02 00:00:00 EST 2023 · Physical Review Materials

DOI:https://doi.org/10.1103/physrevmaterials.7.034401· OSTI ID:1961944

^[1]; Sheng, Jieming ^[1]; Wang, Jinchen ^[2];

^[1]; Li, Tiantian ^[1]; Yang, Jiong ^[1]; Wang, Shanmin ^[3]; Miao, Ping ^[4]; He, Hua ^[5]; Tong, Xin ^[6];

^[7]; Guo, Er-Jia ^[8]; Mole, Richard ^[9];

^[9];

^[10];

^[3]

Southern University of Science and Technology (SUSTech), Shenzhen (China)
Renmin Univ. of China, Beijing (China)
Southern University of Science and Technology (SUSTech), Shenzhen (China); Quantum Science Center of Guangdong-Hong Kong-Macao Greater Bay Area, Shenzhen (China)
Chinese Academy of Sciences (CAS), Beijing (China); Spallation Neutron Source Science Center, Dongguan (China)
University of Chinese Academy of Sciences, Beijing (China)
Chinese Academy of Sciences (CAS), Beijing (China); China Spallation Neutron Source (CSNS), Dongguan (China)
City Univ. of Hong Kong, Kowloon (Hong Kong)
Chinese Academy of Sciences (CAS), Beijing (China); University of Chinese Academy of Sciences, Beijing (China); Songshan Lake Materials Laboratory, Guangdong (China)
Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Heights, NSW (Australia)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The rare-earth perovskite TbScO₃ has been widely used as a substrate for the growth of epitaxial ferroelectric and multiferroic thin films, while its detailed low-temperature magnetic properties were rarely reported. In this paper, we performed detailed magnetization, specific heat, and single crystal neutron scattering measurements, along with the crystalline electric field calculations to study the low-temperature magnetic properties of TbScO_3. All our results suggest the magnetic Tb³⁺ has an Ising-like pseudo-doublet ground state at low temperatures. Due to the constrain of local point symmetry, these Tb³⁺ Ising moments are confined in the ab plane with a tilt angle of φ=±48° to the a axis. In zero field, the system undergoes an antiferromagnetic phase transition at T_N=2.53 K, and forms a G_xA_y noncollinear magnetic structure below T_N. Here, we find the dipole-dipole interactions play an important role to determine the magnetic ground state, which are also responsible for the quasi-one-dimensional magnetism in TbScO₃. The significant anisotropic diffuse scatterings further confirm the quasi-one-dimensional magnetism along the c axis. The magnetic phase diagram with the field along the easy b axis is well established. In addition to the G_xA_y antiferromagnetic state, there is an exotic field-induced phase emerged near the critical field B_c≃0.7 T, where three-dimensional magnetic order is suppressed but strong one-dimensional correlations may still exist.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); Guangdong Basic and Applied Basic Research Foundation; Shenzhen Key Laboratory of Advanced Quantum Functional Materials and Devices; Shenzhen Science and Technology Program

Grant/Contract Number:: AC05-00OR22725; 2021YFA1400400; 12134020; 11974157; 12174175; 12004426; 12005243; 12104255; 2021B1515120015; 2022B1515120014; ZDSYS20190902092905285; KQTD20200820113047086

OSTI ID:: 1961944

Journal Information:: Physical Review Materials, Vol. 7, Issue 3; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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