Will high-entropy carbides and borides be enabling materials for extreme environments?

Wang, Fei; Monteverde, Frederic; Cui, Bai

doi:10.1088/2631-7990/acbd6e

Will high-entropy carbides and borides be enabling materials for extreme environments?

Journal Article · Thu Mar 09 00:00:00 EST 2023 · International Journal of Extreme Manufacturing

DOI:https://doi.org/10.1088/2631-7990/acbd6e· OSTI ID:1960567

Wang, Fei; ;

Abstract

The concept of multi-principal component has created promising opportunities for the development of novel high-entropy ceramics for extreme environments encountered in advanced turbine engines, nuclear reactors, and hypersonic vehicles, as it expands the compositional space of ceramic materials with tailored properties within a single-phase solid solution. The unique physical properties of some high-entropy carbides and borides, such as higher hardness, high-temperature strength, lower thermal conductivity, and improved irradiation resistance than the constitute ceramics, have been observed. These promising properties may be attributed to the compositional complexity, atomic-level disorder, lattice distortion, and other fundamental processes related to defect formation and phonon scattering. This manuscript serves as a critical review of the recent progress in high-entropy carbides and borides, focusing on synthesis and evaluations of their performance in extreme high-temperature, irradiation, and gaseous environments.

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Research Organization:: West Virginia University, Morgantown, WV (United States)

Sponsoring Organization:: National Research Foundation (NSF); USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0001428

OSTI ID:: 1960567

Alternate ID(s):: OSTI ID: 2422376
OSTI ID: 1957836

Journal Information:: International Journal of Extreme Manufacturing, Journal Name: International Journal of Extreme Manufacturing Journal Issue: 2 Vol. 5; ISSN 2631-8644

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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High figure-of-merit and power generation in high-entropy GeTe-based thermoelectrics Jiang, Binbin; Wang, Wu; Liu, Shixuan Science, Vol. 377, Issue 6602 https://doi.org/10.1126/science.abq5815	journal	July 2022
Tungsten carbides and W-C phase diagram Kurlov, A. S.; Gusev, A. I. Inorganic Materials, Vol. 42, Issue 2 https://doi.org/10.1134/S0020168506020051	journal	February 2006
High-Entropy Ultra-High-Temperature Borides and Carbides: A New Class of Materials for Extreme Environments Feng, Lun; Fahrenholtz, William G.; Brenner, Donald W. Annual Review of Materials Research, Vol. 51, Issue 1 https://doi.org/10.1146/annurev-matsci-080819-121217	journal	July 2021
UHTCs: Ultra-High Temperature Ceramic Materials for Extreme Environment Applications Wuchina, Eric; Opila, Elizabeth; Opeka, Mark The Electrochemical Society Interface, Vol. 16, Issue 4 https://doi.org/10.1149/2.F04074IF	journal	December 2007
Direct selective laser sintering of high-entropy carbide ceramics Zhang, Xiang; Li, Nan; Chen, Xin Journal of Materials Research, Vol. 38, Issue 1 https://doi.org/10.1557/s43578-022-00766-0	journal	October 2022
Densification of ultra-refractory transition metal diboride ceramics Fahrenholtz, W. G.; Hilmas, G. E.; Li, Ruixing Science of Sintering, Vol. 52, Issue 1 https://doi.org/10.2298/SOS2001001F	journal	January 2020
Microstructural Evolution and Oxidation Behaviour of Spark Plasma Sintered Mn+1AXn Ceramics Cui, Bai Imperial College London https://doi.org/10.25560/9110	text	January 2011

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36 MATERIALS SCIENCE
Engineering
Materials Science
ceramics
extreme environments
high-entropy ceramics
high-entropy materials

Will high-entropy carbides and borides be enabling materials for extreme environments?

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