A room temperature rechargeable Li2O-based lithium-air battery enabled by a solid electrolyte

Kondori, Alireza; Esmaeilirad, Mohammadreza; Harzandi, Ahmad Mosen; Amine, Rachid; Saray, Mahmoud Tamadoni; Yu, Lei; Liu, Tongchao; Wen, Jianguo; Shan, Nannan; Wang, Hsien-Hau; Ngo, Anh T.; Redfern, Paul C.; Johnson, Christopher S.; Amine, Khalil; Shahbazian-Yassar, Reza; Curtiss, Larry A.; Asadi, Mohammad

doi:10.1126/science.abq1347

A room temperature rechargeable Li₂O-based lithium-air battery enabled by a solid electrolyte

Journal Article · Fri Feb 03 00:00:00 EST 2023 · Science

DOI:https://doi.org/10.1126/science.abq1347· OSTI ID:1960522

^[1]; ^[1]; Harzandi, Ahmad Mosen ^[1]; Amine, Rachid ^[2]; Saray, Mahmoud Tamadoni ^[3]; Yu, Lei ^[4]; Liu, Tongchao ^[5]; ^[4]; ^[6]; ^[2]; Ngo, Anh T. ^[6]; ^[2]; ^[5]; ^[5]; ^[3]; ^[2]; ^[1]

Illinois Institute of Technology, Chicago, IL (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Materials Science Division
University of Illinois, Chicago, IL (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)
Argonne National Laboratory (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Argonne National Laboratory (ANL), Argonne, IL (United States). Materials Science Division; University of Illinois, Chicago, IL (United States)

Lithium-air batteries have scope to compete with gasoline in terms of energy density. However, in most systems, the reaction pathways either involve one- or two-electron transfer, leading to lithium peroxide (Li₂O₂) or lithium superoxide (LiO₂), respectively. Kondori et al. investigated a lithium-air battery that uses a ceramic-polyethylene oxide–based composite solid electrolyte and found that it can undergo a four-electron redox reaction through lithium oxide (Li₂O) formation and decomposition (see the Perspective by Dong and Lu). The composite electrolyte embedded with Li₁₀GeP₂S₁₂ nanoparticles shows high ionic conductivity and stability and high cycle stability through a four-electron transfer process.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Illinois Institute of Technology; Keck Foundation; National Science Foundation (NSF); State of Illinois; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1960522

Alternate ID(s):: OSTI ID: 2282004

Journal Information:: Science, Journal Name: Science Journal Issue: 6631 Vol. 379; ISSN 0036-8075

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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