Slug Flow Coprecipitation Synthesis of Uniformly-Sized Oxalate Precursor Microparticles for Improved Reproducibility and Tap Density of Li(Ni 0.8 Co 0.1 Mn 0.1 )O 2 Cathode Materials

Mou, Mingyao; Patel, Arjun; Mallick, Sourav; Jayanthi, K.; Sun, Xiao-Guang; Paranthaman, Mariappan Parans; Kothe, Sophie; Baral, Ena; Saleh, Selma; Mugumya, Jethrine H.; Rasche, Michael L.; Gupta, Ram B.; Lopez, Herman; Jiang, Mo

doi:10.1021/acsaem.2c03563

Title: Slug Flow Coprecipitation Synthesis of Uniformly-Sized Oxalate Precursor Microparticles for Improved Reproducibility and Tap Density of Li(Ni _0.8 Co _0.1 Mn _0.1 )O ₂ Cathode Materials

Journal Article · Mon Mar 06 00:00:00 EST 2023 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.2c03563· OSTI ID:1960072

Mou, Mingyao ^[1]; Patel, Arjun ^[1];

^[1];

^[2];

^[2]; Kothe, Sophie ^[1]; Baral, Ena ^[1]; Saleh, Selma ^[1];

^[1]; Rasche, Michael L. ^[1];

^[1]; Lopez, Herman ^[3];

^[1]

Department of Chemical and Life Science Engineering, Virginia Commonwealth University, Richmond, Virginia 23219, United States
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States
Ionblox Inc., Fremont, California 94538, United States

The microparticle quality and reproducibility of Li(Ni_0.8Co_0.1Mn_0.1)O₂ (NCM811) cathode materials are important for Li-ion battery performance but can be challenging to control directly from synthesis. Here, a scalable reproducible synthesis process is designed based on slug flow to rapidly generate uniform micron-size spherical-shape NCM oxalate precursor microparticles at 25–34 °C. The whole process takes only 10 min, from solution mixing to precursor microparticle generation, without needing agingthat typically takes hours. These oxalate precursors are convertible to spherical-shape NCM811 oxide microparticles, through a preliminary design of low heating rates (e.g., 0.1 and 0.8 °C/min) for calcination and lithiation. The outcome oxide cathode particles also demonstrate improved tap density (e.g., 2.4 g mL^–1 for NCM811) and good specific capacity (202 mAh g^–1 at 0.1 C) in coin cells and reasonably good cycling performance with LiF coating.

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Research Organization:: Virginia Commonwealth Univ., Richmond, VA (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Technology Development (EE-20); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Materials & Manufacturing Technologies Office (AMMTO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: EE0009110; AC05-00OR22725

OSTI ID:: 1960072

Alternate ID(s):: OSTI ID: 1963232; OSTI ID: 1963803; OSTI ID: 1965218

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Vol. 6 Journal Issue: 6; ISSN 2574-0962

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (66)

Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes: I. Nickel-Rich, LiNi Schipper, Florian; Erickson, Evan M.; Erk, Christoph Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0351701jes	journal	December 2016
A Review on Nanocomposite Materials for Rechargeable Li-ion Batteries Demirocak, Dervis; Srinivasan, Sesha; Stefanakos, Elias Applied Sciences, Vol. 7, Issue 7 https://doi.org/10.3390/app7070731	journal	July 2017
Full-gradient structured LiNi0.8Co0.1Mn0.1O2 cathode material with improved rate and cycle performance for lithium ion batteries Jiang, Yunpeng; Liu, Zhihao; Zhang, Yongzheng Electrochimica Acta, Vol. 309 https://doi.org/10.1016/j.electacta.2019.04.058	journal	June 2019
A Fast Approach to Obtain Layered Transition-Metal Cathode Material for Rechargeable Batteries Nisa, Shofirul Sholikhatun; Rahmawati, Mintarsih; Yudha, Cornelius Satria Batteries, Vol. 8, Issue 1 https://doi.org/10.3390/batteries8010004	journal	January 2022
Review on anionic redox for high-capacity lithium- and sodium-ion batteries Zhao, Chenglong; Wang, Qidi; Lu, Yaxiang Journal of Physics D: Applied Physics, Vol. 50, Issue 18 https://doi.org/10.1088/1361-6463/aa646d	journal	April 2017
Advances in continuous crystallization: toward microfluidic systems Moschou, Parthena; de Croon, Mart H. J. M.; van der Schaaf, John Reviews in Chemical Engineering, Vol. 30, Issue 2 https://doi.org/10.1515/revce-2013-0041	journal	January 2014
The effects of process parameters on the properties of manganese-rich carbonate precursors: A study of co-precipitation synthesis using semi-batch reactors Ngoepe, Noko; Gutierrez, Arturo; Barai, Pallab Chemical Engineering Science, Vol. 241 https://doi.org/10.1016/j.ces.2021.116694	journal	September 2021
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A. Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201201429	journal	September 2012
Growth mechanism of Ni0.3Mn0.7CO3 precursor for high capacity Li-ion battery cathodes Wang, Dapeng; Belharouak, Ilias; Koenig, Gary M. Journal of Materials Chemistry, Vol. 21, Issue 25 https://doi.org/10.1039/c1jm11077b	journal	January 2011
Chemically Modulated Microwave-Assisted Synthesis of MOF-74(Ni) and Preparation of Metal–Organic Framework-Matrix Based Membranes for Removal of Metal Ions from Aqueous Media Albuquerque, Gustavo H.; Herman, Gregory S. Crystal Growth & Design, Vol. 17, Issue 1 https://doi.org/10.1021/acs.cgd.6b01398	journal	December 2016
Cost and energy demand of producing nickel manganese cobalt cathode material for lithium ion batteries Ahmed, Shabbir; Nelson, Paul A.; Gallagher, Kevin G. Journal of Power Sources, Vol. 342 https://doi.org/10.1016/j.jpowsour.2016.12.069	journal	February 2017
Origin of Structural Phase Transitions in Ni-Rich Li_xNi_0.8Co_0.1Mn_0.1O₂ with Lithiation/Delithiation: A First-Principles Study Kuo, Liang-Yin; Guillon, Olivier; Kaghazchi, Payam ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 22 https://doi.org/10.1021/acssuschemeng.0c07675	journal	May 2021
Segmented Flow Reactors for Nanocrystal Synthesis Nightingale, Adrian M.; deMello, John C. Advanced Materials, Vol. 25, Issue 13 https://doi.org/10.1002/adma.201203252	journal	November 2012
Revealing the correlation between structural evolution and Li ⁺ diffusion kinetics of nickel-rich cathode materials in Li-ion batteries Hong, Chaoyu; Leng, Qianyi; Zhu, Jianping Journal of Materials Chemistry A, Vol. 8, Issue 17 https://doi.org/10.1039/D0TA00555J	journal	January 2020
Low-Cost Noninvasive Real-Time Imaging for Tubular Continuous-Flow Crystallization Jiang, Mo; Braatz, Richard D. Chemical Engineering & Technology, Vol. 41, Issue 1 https://doi.org/10.1002/ceat.201600276	journal	October 2017
Electrochemical Failure Results Inevitable Capacity Degradation in Li-Ion Batteries—A Review Li, Wei; Li, Hang; He, Zheng Energies, Vol. 15, Issue 23 https://doi.org/10.3390/en15239165	journal	December 2022
Understanding Reactivities of Ni-Rich Li[Ni _x Mn _y Co _{1– x – y} ]O ₂ Single-Crystal Cathode Materials Kim, Minkyung; Zhu, Jian; Li, Linze ACS Applied Energy Materials, Vol. 3, Issue 12 https://doi.org/10.1021/acsaem.0c02278	journal	November 2020
Micro-scale graded electrodes for improved dynamic and cycling performance of Li-ion batteries Cheng, Chuan; Drummond, Ross; Duncan, Stephen R. Journal of Power Sources, Vol. 413 https://doi.org/10.1016/j.jpowsour.2018.12.021	journal	February 2019
Progress in Preparation and Modification of LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Cathode Material for High Energy Density Li-Ion Batteries Xu, Lipeng; Zhou, Fei; Liu, Bing International Journal of Electrochemistry, Vol. 2018 https://doi.org/10.1155/2018/6930386	journal	July 2018
Superstructure of a Metal–Organic Framework Derived from Microdroplet Flow Reaction: An Intermediate State of Crystallization by Particle Attachment Wang, Ying; Li, Liangjun; Liang, Huimin ACS Nano, Vol. 13, Issue 3 https://doi.org/10.1021/acsnano.8b06706	journal	March 2019
Role of coprecipitation and calcination of precursors on phase homogeneity and electrochemical properties of battery active materials Dong, Hongxu; Wang, Anny; Koenig, Gary M. Powder Technology, Vol. 335 https://doi.org/10.1016/j.powtec.2018.05.020	journal	July 2018
Tuning the gas-liquid-solid segmented flow for enhanced heterogeneous photosynthesis of Azo- compounds Chen, Yuhang; Zhang, Yaheng; Zou, Hongwei Chemical Engineering Journal, Vol. 423 https://doi.org/10.1016/j.cej.2021.130226	journal	November 2021
Multiphase monolith reactors: Chemical reaction engineering of segmented flow in microchannels Kreutzer, Michiel T.; Kapteijn, Freek; Moulijn, Jacob A. Chemical Engineering Science, Vol. 60, Issue 22 https://doi.org/10.1016/j.ces.2005.03.022	journal	November 2005
Synthesis of spherical LiMn2O4 microparticles by a combination of spray pyrolysis and drying method Taniguchi, Izumi; Fukuda, Norifumi; Konarova, Muxina Powder Technology, Vol. 181, Issue 3 https://doi.org/10.1016/j.powtec.2007.05.011	journal	February 2008
Effect of high-temperature crystallization on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2 synthesized from a lithiated transition metal oxide precursor Xue, Longlong; Li, Yunjiao; Han, Qiang Ionics, Vol. 24, Issue 10 https://doi.org/10.1007/s11581-018-2467-9	journal	March 2018
Uniform Ni-rich LiNi0.6Co0.2Mn0.2O2 Porous Microspheres: Facile Designed Synthesis and Their Improved Electrochemical Performance Zheng, Zhuo; Guo, Xiao-Dong; Chou, Shu-Lei Electrochimica Acta, Vol. 191 https://doi.org/10.1016/j.electacta.2016.01.092	journal	February 2016
Bubble/droplet formation and mass transfer during gas-liquid-liquid segmented flow with soluble gas in a microchannel Yao, Chaoqun; Liu, Yanyan; Zhao, Shuainan AIChE Journal, Vol. 63, Issue 5 https://doi.org/10.1002/aic.15536	journal	October 2016
Monitoring the morphology evolution of LiNi0.8Mn0.1Co0.1O2 during high-temperature solid state synthesis via in situ SEM Tang, Liang; Cheng, Xiaopeng; Wu, Rui Journal of Energy Chemistry, Vol. 66 https://doi.org/10.1016/j.jechem.2021.07.021	journal	March 2022
Probing Dopant Redistribution, Phase Propagation, and Local Chemical Changes in the Synthesis of Layered Oxide Battery Cathodes Yang, Zhijie; Mu, Linqin; Hou, Dong Advanced Energy Materials, Vol. 11, Issue 1 https://doi.org/10.1002/aenm.202002719	journal	November 2020
An improved carbonate co-precipitation method for the preparation of spherical Li[Ni1/3Co1/3Mn1/3]O2 cathode material Zhang, S.; Deng, C.; Yang, S. Y. Journal of Alloys and Compounds, Vol. 484, Issue 1-2 https://doi.org/10.1016/j.jallcom.2009.04.149	journal	September 2009
Facile Surface Coatings for Performance Improvement of NMC811 Battery Cathode Material Sun, Xiao-Guang; Jafta, Charl J.; Tan, Susheng Journal of The Electrochemical Society, Vol. 169, Issue 2 https://doi.org/10.1149/1945-7111/ac5302	journal	February 2022
Precipitation and Crystallization Used in the Production of Metal Salts for Li-Ion Battery Materials: A Review Ma, Yiqian; Svärd, Michael; Xiao, Xiong Metals, Vol. 10, Issue 12 https://doi.org/10.3390/met10121609	journal	November 2020
Single‐Crystal LiNi _x Mn _y Co ₁₋ _x ₋ _y O ₂ Cathodes for Extreme Fast Charging Lu, Yanying; Zhu, Tianyu; McShane, Eric Small, Vol. 18, Issue 12 https://doi.org/10.1002/smll.202105833	journal	January 2022
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries Noh, Hyung-Joo; Youn, Sungjune; Yoon, Chong Seung Journal of Power Sources, Vol. 233 https://doi.org/10.1016/j.jpowsour.2013.01.063	journal	July 2013
Degradation Mechanisms and Mitigation Strategies of Nickel-Rich NMC-Based Lithium-Ion Batteries Li, Tianyu; Yuan, Xiao-Zi; Zhang, Lei Electrochemical Energy Reviews, Vol. 3, Issue 1 https://doi.org/10.1007/s41918-019-00053-3	journal	October 2019
Stabilizing NMC 811 Li-Ion Battery Cathode through a Rapid Coprecipitation Process Lipson, Albert L.; Ross, Bradley J.; Durham, Jessica L. ACS Applied Energy Materials, Vol. 4, Issue 2 https://doi.org/10.1021/acsaem.0c03112	journal	January 2021
Improving electrochemical performance and thermal stability of LiNi0.8Co0.1Mn0.1O2 via a concentration gradient Nb doping Zhang, Qianru; Wang, Ruo; Zhang, Tesen Ionics, Vol. 26, Issue 12 https://doi.org/10.1007/s11581-020-03758-4	journal	September 2020
Oscillatory Microprocessor for Growth and in Situ Characterization of Semiconductor Nanocrystals Abolhasani, Milad; Coley, Connor W.; Xie, Lisi Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02821	journal	August 2015
Recent progress in advanced electrode materials, separators and electrolytes for lithium batteries Zhang, Hailin; Zhao, Hongbin; Khan, Muhammad Arif Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/C8TA05336G	journal	January 2018
Magnesium Substitution in Ni‐Rich NMC Layered Cathodes for High‐Energy Lithium Ion Batteries Gomez‐Martin, Aurora; Reissig, Friederike; Frankenstein, Lars Advanced Energy Materials, Vol. 12, Issue 8 https://doi.org/10.1002/aenm.202103045	journal	January 2022
An effective way of co-precipitating Ni2+, Mn2+ and Co2+ by using ammonium oxalate as precipitant for Ni-rich Li-ion batteries cathode Zeng, Tianbiao; Zhang, Chuhong Journal of Materials Science, Vol. 55, Issue 25 https://doi.org/10.1007/s10853-020-04753-w	journal	May 2020
Effective regeneration of LiCoO ₂ from spent lithium-ion batteries: a direct approach towards high-performance active particles Shi, Yang; Chen, Gen; Chen, Zheng Green Chemistry, Vol. 20, Issue 4 https://doi.org/10.1039/C7GC02831H	journal	January 2018
Continuous Microwave-Assisted Gas–Liquid Segmented Flow Reactor for Controlled Nucleation and Growth of Nanocrystals Kim, Ki-Joong; Oleksak, Richard P.; Hostetler, Eric B. Crystal Growth & Design, Vol. 14, Issue 11 https://doi.org/10.1021/cg500959m	journal	October 2014
Time-Controlled Microfluidic Seeding in nL-Volume Droplets To Separate Nucleation and Growth Stages of Protein Crystallization Gerdts, Cory J.; Tereshko, Valentina; Yadav, Maneesh K. Angewandte Chemie International Edition, Vol. 45, Issue 48 https://doi.org/10.1002/anie.200602946	journal	December 2006
Heterogeneous Reaction Activities and Statistical Characteristics of Particle Cracking in Battery Electrodes Lin, Feng; Zhao, Kejie; Liu, Yijin ACS Energy Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acsenergylett.1c02135	journal	October 2021
Synthesis and Theoretical Modeling of Suitable Co-precipitation Conditions for Producing NMC111 Cathode Material for Lithium-Ion Batteries Mugumya, Jethrine H.; Rasche, Michael L.; Rafferty, Robert F. Energy & Fuels, Vol. 36, Issue 19 https://doi.org/10.1021/acs.energyfuels.2c01805	journal	September 2022
Single-Crystal Ni-Rich Layered LiNi_0.9Mn_0.1O₂ Enables Superior Performance of Co-Free Cathodes for Lithium-Ion Batteries Dai, Pengpeng; Kong, Xiangbang; Yang, Huiya ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 14 https://doi.org/10.1021/acssuschemeng.1c06704	journal	April 2022
Graphene and its derivatives in lithium–sulfur batteries Zhang, Yunya; Gao, Zan; Song, Ningning Materials Today Energy, Vol. 9 https://doi.org/10.1016/j.mtener.2018.06.001	journal	September 2018
Gas-liquid-liquid multiphase flow in microfluidic systems – A review Chen, Zhuo; Xu, Jianhong; Wang, Yundong Chemical Engineering Science, Vol. 202 https://doi.org/10.1016/j.ces.2019.03.016	journal	July 2019
Structural self-reconstruction strategy empowering Ni-rich layered cathodes with low-strain for superior cyclabilities Tan, Zhouliang; Li, Yunjiao; Xi, Xiaoming Nano Research https://doi.org/10.1007/s12274-022-5161-1	journal	November 2022
Nanoparticle synthesis in microreactors Zhao, Chun-Xia; He, Lizhong; Qiao, Shi Zhang Chemical Engineering Science, Vol. 66, Issue 7 https://doi.org/10.1016/j.ces.2010.08.039	journal	April 2011
Preparation and electrochemical investigation of LiMn2 − xMexO4 (Me: Ni, Fe, and x = 0.5, 1) cathode materials for secondary lithium batteries Amine, K.; Tukamoto, H.; Yasuda, H. Journal of Power Sources, Vol. 68, Issue 2 https://doi.org/10.1016/S0378-7753(96)02590-6	journal	October 1997
Recent Insights into Rate Performance Limitations of Li‐ion Batteries Heubner, Christian; Nikolowski, Kristian; Reuber, Sebastian Batteries & Supercaps, Vol. 4, Issue 2 https://doi.org/10.1002/batt.202000227	journal	November 2020
Continuous-Flow Tubular Crystallization in Slugs Spontaneously Induced by Hydrodynamics Jiang, Mo; Zhu, Zhilong; Jimenez, Ernesto Crystal Growth & Design, Vol. 14, Issue 2 https://doi.org/10.1021/cg401715e	journal	January 2014
Fast Continuous Non-Seeded Cooling Crystallization of Glycine in Slug Flow: Pure α-Form Crystals with Narrow Size Distribution Mou, Mingyao; Jiang, Mo Journal of Pharmaceutical Innovation, Vol. 15, Issue 2 https://doi.org/10.1007/s12247-020-09438-0	journal	March 2020
Preparation and characterization of layered LiMn1/3Ni1/3Co1/3O2 as a cathode material by an oxalate co-precipitation method Cho, Tae-Hyung; Shiosaki, Yuki; Noguchi, Hideyuki Journal of Power Sources, Vol. 159, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.11.080	journal	September 2006
Next‐Generation Cobalt‐Free Cathodes – A Prospective Solution to the Battery Industry's Cobalt Problem Muralidharan, Nitin; Self, Ethan C.; Dixit, Marm Advanced Energy Materials, Vol. 12, Issue 9 https://doi.org/10.1002/aenm.202103050	journal	January 2022
High-energy cathode material for long-life and safe lithium batteries Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun Nature Materials, Vol. 8, Issue 4 https://doi.org/10.1038/nmat2418	journal	March 2009
Status, promises, and challenges of nanocomposite solid-state electrolytes for safe and high performance lithium batteries Wan, J.; Xie, J.; Mackanic, D. G. Materials Today Nano, Vol. 4 https://doi.org/10.1016/j.mtnano.2018.12.003	journal	December 2018
Boron in Ni-Rich NCM811 Cathode Material: Impact on Atomic and Microscale Properties Roitzheim, Christoph; Kuo, Liang-Yin; Sohn, Yoo Jung ACS Applied Energy Materials, Vol. 5, Issue 1 https://doi.org/10.1021/acsaem.1c03000	journal	December 2021
Core–shell and concentration-gradient cathodes prepared via co-precipitation reaction for advanced lithium-ion batteries Hou, Peiyu; Zhang, Hongzhou; Zi, Zhongyue Journal of Materials Chemistry A, Vol. 5, Issue 9 https://doi.org/10.1039/C6TA10297B	journal	January 2017
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives Myung, Seung-Taek; Maglia, Filippo; Park, Kang-Joon ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00594	journal	December 2016
A two-phase segmented microfluidic technique for one-step continuous versatile preparation of zeolites Yu, Liang; Pan, Yichang; Wang, Chongqing Chemical Engineering Journal, Vol. 219 https://doi.org/10.1016/j.cej.2013.01.009	journal	March 2013
Capacity Fading of Ni-Rich Li[Ni _x Co _y Mn _{1– x – y} ]O ₂ (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? Ryu, Hoon-Hee; Park, Kang-Joon; Yoon, Chong S. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05269	journal	January 2018
Designs of continuous-flow pharmaceutical crystallizers: developments and practice Jiang, Mo; Braatz, Richard D. CrystEngComm, Vol. 21, Issue 23 https://doi.org/10.1039/C8CE00042E	journal	January 2019
Nanostructured Silicon Anodes for Lithium Ion Rechargeable Batteries Teki, Ranganath; Datta, Moni K.; Krishnan, Rahul Small, Vol. 5, Issue 20 https://doi.org/10.1002/smll.200900382	journal	October 2009

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tap density
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electrodes
materials
microparticles
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Title: Slug Flow Coprecipitation Synthesis of Uniformly-Sized Oxalate Precursor Microparticles for Improved Reproducibility and Tap Density of Li(Ni 0.8 Co 0.1 Mn 0.1 )O 2 Cathode Materials

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Title: Slug Flow Coprecipitation Synthesis of Uniformly-Sized Oxalate Precursor Microparticles for Improved Reproducibility and Tap Density of Li(Ni _0.8 Co _0.1 Mn _0.1 )O ₂ Cathode Materials