Mutual Ferromagnetic-Ferroelectric Coupling in Multiferroic Copper-Doped ZnO

Herng, Tun Seng; Wong, Meng Fei; Qi, Dongchen; Yi, Jiabao; Kumar, Amit; Huang, Alicia; Kartawidjaja, Fransiska Cecilia; Smadici, Serban; Abbamonte, Peter; Sánchez-Hanke, Cecilia; Shannigrahi, Santiranjan; Xue, Jun Min; Wang, John; Feng, Yuan Ping; Rusydi, Andrivo; Zeng, Kaiyang; Ding, Jun

doi:10.1002/adma.201004519

Mutual Ferromagnetic-Ferroelectric Coupling in Multiferroic Copper-Doped ZnO

Journal Article · Tue Feb 15 04:00:00 EST 2011 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201004519· OSTI ID:1958854

Herng, Tun Seng ^[1]; Wong, Meng Fei ^[2]; Qi, Dongchen ^[3]; Yi, Jiabao ^[2]; Kumar, Amit ^[2]; Huang, Alicia ^[4]; Kartawidjaja, Fransiska Cecilia ^[2]; Smadici, Serban ^[5]; Abbamonte, Peter ^[5]; Sánchez-Hanke, Cecilia ^[6]; Shannigrahi, Santiranjan ^[4]; Xue, Jun Min ^[2]; Wang, John ^[2]; Feng, Yuan Ping ^[2]; Rusydi, Andrivo ^[3]; Zeng, Kaiyang ^[2]; Ding, Jun ^[2]

National Univ. of Singapore (Singapore); University of Illinois
National Univ. of Singapore (Singapore)
National Univ. of Singapore (Singapore); National Univ. of Singapore (Singapore). Singapore Synchrotron Light Source
Institute of Materials Research and Engineering (IMRE) (Singapore)
Univ. of Illinois at Urbana-Champaign, IL (United States). Frederick Seitz Materials Research Lab. (FS-MRL)
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source (NSLS)

A mutual ferromagnetic and ferroelectric coupling (multiferroic behavior) in Cu-doped ZnO is demonstrated via deterministic control of Cu doping and defect engineering. The coexistence of multivalence Cu ions and oxygen vacancies is important to multiferroic behaviors in ZnO:Cu. The samples show clear ferroelectric and ferromagnetic domain patterns. These domain structures may be written reversibly via electric and magnetic bias.

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Ministry of Education Singapore

DOE Contract Number:: FG02-06ER46285; AC02-98CH10886

OSTI ID:: 1958854

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 14 Vol. 23; ISSN 0935-9648

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (26)

Ferromagnetism of ZnO and GaN: A Review Liu, C.; Yun, F.; Morkoç, H. Journal of Materials Science: Materials in Electronics, Vol. 16, Issue 9 https://doi.org/10.1007/s10854-005-3232-1	journal	September 2005
Ferroelectricity in Strain-Free SrTiO 3 Thin Films Jang, H. W.; Kumar, A.; Denev, S. Physical Review Letters, Vol. 104, Issue 19, Article No. 197601 https://doi.org/10.1103/PhysRevLett.104.197601	journal	May 2010
A comprehensive review of ZnO materials and devices Özgür, Ü.; Alivov, Ya. I.; Liu, C. Journal of Applied Physics, Vol. 98, Issue 4 https://doi.org/10.1063/1.1992666	journal	August 2005
Multiferroics: a magnetic twist for ferroelectricity Cheong, Sang-Wook; Mostovoy, Maxim Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1804	journal	January 2007
Room-temperature ferromagnetism in Cu-doped ZnO thin films Buchholz, D. B.; Chang, R. P. H.; Song, J. -Y. Applied Physics Letters, Vol. 87, Issue 8 https://doi.org/10.1063/1.2032588	journal	August 2005
Multiferroics progress and prospects in thin films Ramesh, R.; Spaldin, Nicola A. Nature Materials, Vol. 6, Issue 1, p. 21-29 https://doi.org/10.1038/nmat1805	journal	January 2007
Room temperature p-type conductivity and coexistence of ferroelectric order in ferromagnetic Li doped ZnO nanoparticles Awan, Saif Ullah; Hasanain, S. K.; Anjum, D. H. Journal of Applied Physics, Vol. 116, Issue 16 https://doi.org/10.1063/1.4900413	journal	October 2014
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Weak ferromagnetism and nanodimensional ferroelectric domain structure stabilized in the polar phase of Bi_1−xNd_xFeO₃ multiferroics via Ti doping Khomchenko, V. A.; Pereira, L. C. J.; Paixão, J. A. Journal of Applied Physics, Vol. 115, Issue 16 https://doi.org/10.1063/1.4873121	journal	April 2014
Unoccupied electronic structure and core-hole effects in the x-ray-absorption spectra of Cu 2 O Grioni, M.; van Acker, J. F.; Czyžyk, M. T. Physical Review B, Vol. 45, Issue 7 https://doi.org/10.1103/PhysRevB.45.3309	journal	February 1992
Ferroelectric behavior of Li-doped ZnO thin films on Si(100) by pulsed laser deposition Joseph, M.; Tabata, H.; Kawai, T. Applied Physics Letters, Vol. 74, Issue 17 https://doi.org/10.1063/1.123889	journal	April 1999
Room temperature ferromagnetism in Zn1−xCuxO thin films Chakraborti, D.; Narayan, J.; Prater, J. T. Applied Physics Letters, Vol. 90, Issue 6 https://doi.org/10.1063/1.2450652	journal	February 2007
Room-temperature ferromagnetic and ferroelectric behavior in polycrystalline ZnO-based thin films Lin, Yuan-Hua; Ying, Minghao; Li, Ming Applied Physics Letters, Vol. 90, Issue 22 https://doi.org/10.1063/1.2745247	journal	May 2007
Room temperature multiferroic behavior of Cr-doped ZnO films Yang, Y. C.; Zhong, C. F.; Wang, X. H. Journal of Applied Physics, Vol. 104, Issue 6 https://doi.org/10.1063/1.2978221	journal	September 2008
The Electronic Structures and Ferromagnetism of Cu-Doped ZnO: the First-Principle Calculation Study Pan, Feng-chun; Lin, Xue-ling; Li, Juan Journal of Superconductivity and Novel Magnetism, Vol. 31, Issue 7 https://doi.org/10.1007/S10948-017-4417-6	journal	November 2017
Theory of low-frequency magnetoelectric coupling in magnetostrictive-piezoelectric bilayers Bichurin, M. I.; Petrov, V. M.; Srinivasan, G. Physical Review B, Vol. 68, Issue 5 https://doi.org/10.1103/PhysRevB.68.054402	journal	August 2003
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Role of donor defects in enhancing ferromagnetism of Cu-doped ZnO films Li, Xiao-Li; Xu, Xiao-Hong; Quan, Zhi-Yong Journal of Applied Physics, Vol. 105, Issue 10 https://doi.org/10.1063/1.3130104	journal	May 2009
Effects of interfacial layer structures on crystal structural properties of ZnO films Park, J. S.; Minegishi, T.; Lee, S. H. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 26, Issue 1 https://doi.org/10.1116/1.2821741	journal	January 2008
V5+ ionic displacement induced ferroelectric behavior in V-doped ZnO films Yang, Y. C.; Song, C.; Zeng, F. Applied Physics Letters, Vol. 90, Issue 24 https://doi.org/10.1063/1.2748081	journal	June 2007
Epitaxial ferroelectric Pb(Zr, Ti)O3 thin films on Si using SrTiO3 template layers Wang, Y.; Ganpule, C.; Liu, B. T. Applied Physics Letters, Vol. 80, Issue 1 https://doi.org/10.1063/1.1428413	journal	January 2002
Electric modulation of conduction in multiferroic Ca-doped BiFeO3 films Yang, C. -H.; Seidel, J.; Kim, S. Y. Nature Materials, Vol. 8, Issue 6 https://doi.org/10.1038/nmat2432	journal	April 2009
Structure and ferromagnetism of Mn+ ion-implanted ZnO thin films on sapphire Brauer, G.; Anwand, W.; Skorupa, W. Superlattices and Microstructures, Vol. 39, Issue 1-4 https://doi.org/10.1016/j.spmi.2005.08.030	journal	January 2006
Recent advances in processing of ZnO Pearton, S. J.; Norton, D. P.; Ip, K. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 22, Issue 3 https://doi.org/10.1116/1.1714985	journal	January 2004
Electron Trap Level of Cu-Doped ZnO Furukawa, Akio; Ogasawara, Naoto; Yokozawa, Ryoji Japanese Journal of Applied Physics, Vol. 47, Issue 12 https://doi.org/10.1143/JJAP.47.8799	journal	December 2008
Room-Temperature Ferromagnetism of Cu-Doped ZnO Films Probed by Soft X-Ray Magnetic Circular Dichroism Herng, T. S.; Qi, D. -C.; Berlijn, T. Physical Review Letters, Vol. 105, Issue 20 https://doi.org/10.1103/PhysRevLett.105.207201	journal	November 2010

Cited By (6)

Enhanced room temperature ferromagnetism and green photoluminescence in Cu doped ZnO thin film synthesised by neutral beam sputtering Agarwal, D. C.; Singh, U. B.; Gupta, Srashti Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-43184-9	journal	April 2019
Spatially Correlated, Single Nanomaterial-Level Structural and Optical Profiling of Cu-Doped ZnO Nanorods Synthesized via Multifunctional Silicides Truong, Johnson; Hansen, Matthew; Szychowski, Brian Nanomaterials, Vol. 8, Issue 4 https://doi.org/10.3390/nano8040222	journal	April 2018
Probing the magnetic profile of diluted magnetic semiconductors using polarized neutron reflectivity Luo, X.; Tseng, L. T.; Lee, W. T. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-06793-w	journal	July 2017
Investigation of the non-volatile resistance change in noncentrosymmetric compounds Herng, T. S.; Kumar, A.; Ong, C. S. Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00587	journal	August 2012
Magnetic switching of ferroelectric domains at room temperature in multiferroic PZTFT Evans, D. M.; Schilling, A.; Kumar, Ashok Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2548	journal	February 2013
Reversible Tuning of Ferromagnetism and Resistive Switching in ZnO/Cu Thin Films Younas, Muhammad; Xu, Chi; Arshad, Muhammad ACS Omega, Vol. 2, Issue 12 https://doi.org/10.1021/acsomega.7b01192	journal	December 2017

Similar Records

Mutual Ferromagnetic-Ferroelectric Coupling in Multiferroic Copper Doped ZnO

Journal Article · Fri Dec 31 23:00:00 EST 2010 · Advanced Materials · OSTI ID:1019503

Room temperature p-type conductivity and coexistence of ferroelectric order in ferromagnetic Li doped ZnO nanoparticles

Journal Article · Tue Oct 28 00:00:00 EDT 2014 · Journal of Applied Physics · OSTI ID:22308177

Room temperature multiferroic behavior of Cr-doped ZnO films

Journal Article · Mon Sep 15 00:00:00 EDT 2008 · Journal of Applied Physics · OSTI ID:21182638

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
Oxide heterostructures
ferroelectric materials
magnetic materials
multiferroic materials
thin films
zinc oxide

Mutual Ferromagnetic-Ferroelectric Coupling in Multiferroic Copper-Doped ZnO

Citation Formats

References (26)

Cited By (6)

Similar Records

Related Subjects