Continuous hydrodeoxygenation of lignin to jet-range aromatic hydrocarbons

Stone, Michael L.; Webber, Matthew S.; Mounfield III, William P.; Bell, David C.; Christensen, Earl D.; Morais, Ana R.C.; Li, Yanding; Anderson, Eric M.; Heyne, Joshua S.; Beckham, Gregg T.; Román-Leshkov, Yuriy

doi:10.1016/j.joule.2022.08.005

Continuous hydrodeoxygenation of lignin to jet-range aromatic hydrocarbons

Journal Article · Thu Sep 22 00:00:00 EDT 2022 · Joule

DOI:https://doi.org/10.1016/j.joule.2022.08.005· OSTI ID:1957789

Stone, Michael L. ^[1]; Webber, Matthew S. ^[1]; Mounfield III, William P. ^[1]; Bell, David C. ^[2]; Christensen, Earl D. ^[3]; Morais, Ana R.C. ^[3]; Li, Yanding ^[1]; Anderson, Eric M. ^[1]; Heyne, Joshua S. ^[4]; Beckham, Gregg T. ^[3]; Román-Leshkov, Yuriy ^[1]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Washington State Univ., Richland, WA (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Washington State Univ., Richland, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sustainable aviation fuel (SAF) is essential to decrease the carbon footprint of the aviation industry. Although many strategies have been developed to provide the branched, aliphatic components of SAF, few viable strategies have been demonstrated to supply the aromatic and cycloalkane fraction of SAF at the necessary scale from bio-based feedstocks. Lignin is the largest natural source of renewable aromatic compounds, yet major challenges in deoxygenation have prevented its use as a feedstock for SAF. Here we report a continuous, two-stage catalytic process using molybdenum carbide to deoxygenate lignin from poplar into aromatic hydrocarbons with 87.5% selectivity towards aromatic hydrocarbons at 86% of the theoretical carbon recovery. This work demonstrates an effective approach to convert lignin into aromatic SAF blendstocks.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Bioenergy Technologies Office (BETO); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830; AC36-08GO28308

OSTI ID:: 1957789

Alternate ID(s):: OSTI ID: 1900006

Report Number(s):: PNNL-SA-177299

Journal Information:: Joule, Journal Name: Joule Journal Issue: 10 Vol. 6; ISSN 2542-4351

Publisher:: Elsevier - Cell PressCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Continuous hydrodeoxygenation of lignin to jet-range aromatic hydrocarbons

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