Photocatalyst-free, light-induced carbon-sulfur cross-coupling methods

Miyake, Garret; Liu, Bin; Lim, Chern-Hooi

Photocatalyst-free, light-induced carbon-sulfur cross-coupling methods

Patent · Tue Aug 30 04:00:00 EDT 2022

OSTI ID:1925030

Miyake, Garret; Liu, Bin; Lim, Chern-Hooi

In one aspect, the invention provides a method of promoting a carbon-sulfur bond forming reaction. In certain embodiments, the reaction comprises cross-coupling of a(n) (hetero)aryl halide with a thiol to form the carbon-sulfur bond, wherein the method is promoted by light irradiation in the absence of a photocatalyst. In other embodiments, the cross-coupling reaction can be promoted through visible light irradiation, including sunlight.

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Research Organization:: Univ. of Colorado, Denver, CO (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000683

Assignee:: The Regents of the University of Colorado, A Body Corporate (Denver, CO)

Patent Number(s):: 11,427,536

Application Number:: 16/019,914

OSTI ID:: 1925030

Country of Publication:: United States

Language:: English

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