Lithium ions cell designs with high capacity anode materials and high cell capacities

Masarapu, Charan; Anguchamy, Yogesh Kumar; Han, Yongbong; Deng, Haixia; Kumar, Sujeet; Lopez, Herman A.

Lithium ions cell designs with high capacity anode materials and high cell capacities

Patent · 12 July 2022

OSTI ID:1924894

Masarapu, Charan; Anguchamy, Yogesh Kumar; Han, Yongbong; Deng, Haixia; Kumar, Sujeet; Lopez, Herman A.

Improved high energy capacity designs for lithium ion batteries are described that take advantage of the properties of high specific capacity anode active compositions and high specific capacity cathode active compositions. In particular, specific electrode designs provide for achieving very high energy densities. Furthermore, the complex behavior of the active materials is used advantageously in a radical electrode balancing design that significantly reduced wasted electrode capacity in either electrode when cycling under realistic conditions of moderate to high discharge rates and/or over a reduced depth of discharge.

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Research Organization:: Zenlabs Energy, Inc., Fremont, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); California Energy Commission

DOE Contract Number:: AR0000034

Assignee:: Zenlabs Energy, Inc. (Fremont, CA)

Patent Number(s):: 11,387,440

Application Number:: 16/876,234

OSTI ID:: 1924894

Country of Publication:: United States

Language:: English

References (47)

Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501010	journal	October 2015
Superior Storage Performance of a Si@SiO_x/C Nanocomposite as Anode Material for Lithium-Ion Batteries Hu, Yong-Sheng; Demir-Cakan, Rezan; Titirici, Maria-Magdalena Angewandte Chemie International Edition, Vol. 47, Issue 9, p. 1645-1649 https://doi.org/10.1002/anie.200704287	journal	February 2008
Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries Kim, Hyunjung; Han, Byunghee; Choo, Jaebum Angewandte Chemie International Edition, Vol. 47, Issue 52, p. 10151-10154 https://doi.org/10.1002/anie.200804355	journal	December 2008
SiO_x-based anodes for secondary lithium batteries Yang, J.; Takeda, Y.; Imanishi, N. Solid State Ionics, Vol. 152-153, p. 125-129 https://doi.org/10.1016/S0167-2738(02)00362-4	journal	December 2002
Two- and three-electrode impedance spectroscopy of lithium-ion batteries Song, J. Journal of Power Sources, Vol. 111, Issue 2 https://doi.org/10.1016/S0378-7753(02)00310-5	journal	September 2002
Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes McMillan, Rod; Slegr, Helen; Shu, Z. X. Journal of Power Sources, Vol. 81-82, p. 20-26 https://doi.org/10.1016/S0378-7753(98)00201-8	journal	September 1999
Significant improvement of high voltage cycling behavior AlF₃-coated LiCoO₂ cathode Sun, Y.; Han, J.; Myung, S. Electrochemistry Communications, Vol. 8, Issue 5, p. 821-826 https://doi.org/10.1016/j.elecom.2006.03.040	journal	May 2006
Comments on the structural complexity of lithium-rich Li_1+xM_1−xO₂ electrodes (M=Mn, Ni, Co) for lithium batteries Thackeray, M. M.; Kang, S.-H.; Johnson, C. S. Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538 https://doi.org/10.1016/j.elecom.2006.06.030	journal	September 2006
Enhancing the rate capability of high capacity xLi₂MnO₃ · (1−x)LiMO₂ (M=Mn, Ni, Co) electrodes by Li–Ni–PO₄ treatment Kang, Sun-Ho; Thackeray, Michael M. Electrochemistry Communications, Vol. 11, Issue 4, p. 748-751 https://doi.org/10.1016/j.elecom.2009.01.025	journal	April 2009
Synthesis of spherical Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ as positive electrode material for lithium-ion battery Kim, Gil-Ho; Myung, Seung-Taek; Kim, Hyun-Soo Electrochimica Acta, Vol. 51, Issue 12, p. 2447-2453 https://doi.org/10.1016/j.electacta.2005.07.026	journal	February 2006
Enhanced thermal properties of the solid electrolyte interphase formed on graphite in an electrolyte with fluoroethylene carbonate Profatilova, Irina A.; Kim, Sung-Soo; Choi, Nam-Soon Electrochimica Acta, Vol. 54, Issue 19, p. 4445-4450 https://doi.org/10.1016/j.electacta.2009.03.032	journal	July 2009
Lithium polyacrylate as a binder for tin–cobalt–carbon negative electrodes in lithium-ion batteries Li, Jing; Le, Dinh-Ba; Ferguson, P. P. Electrochimica Acta, Vol. 55, Issue 8 https://doi.org/10.1016/j.electacta.2010.01.011	journal	March 2010
Li-doping process for Li_xSiO-negative active material synthesized by chemical method for lithium-ion cells Tabuchi, Toru; Yasuda, Hideo; Yamachi, Masanori Journal of Power Sources, Vol. 146, Issue 1-2, p. 507-509 https://doi.org/10.1016/j.jpowsour.2005.03.100	journal	August 2005
Electrochemical behaviors of silicon based anode material Yoshio, Masaki; Tsumura, Takaaki; Dimov, Nikolay Journal of Power Sources, Vol. 146, Issue 1-2, p. 10-14 https://doi.org/10.1016/j.jpowsour.2005.03.143	journal	August 2005
Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries Kang, S.-H.; Amine, K. Journal of Power Sources, Vol. 146, Issue 1-2, p. 654-657 https://doi.org/10.1016/j.jpowsour.2005.03.152	journal	August 2005
The preparation and electrochemical performance of solid solutions LiCoO2–Li2MnO3 as cathode materials for lithium ion batteries Sun, Yucheng; Shiosaki, Yuki; Xia, Yonggao Journal of Power Sources, Vol. 159, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.12.037	journal	September 2006
Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode Choi, Nam-Soon; Yew, Kyoung Han; Lee, Kyu Youl Journal of Power Sources, Vol. 161, Issue 2, p. 1254-1259 https://doi.org/10.1016/j.jpowsour.2006.05.049	journal	October 2006
High capacity Li[Li_0.2Ni_0.2Mn_0.6]O₂ cathode materials via a carbonate co-precipitation method Lee, D.-K.; Park, S.-H.; Amine, K. Journal of Power Sources, Vol. 162, Issue 2, p. 1346-1350 https://doi.org/10.1016/j.jpowsour.2006.07.064	journal	November 2006
Nanosized silicon-based composite derived by in situ mechanochemical reduction for lithium ion batteries Yang, Xuelin; Wen, Zhaoyin; Xu, Xiaoxiong Journal of Power Sources, Vol. 164, Issue 2, p. 880-884 https://doi.org/10.1016/j.jpowsour.2006.11.010	journal	February 2007
Physical and electrochemical properties of spherical Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cathode materials Park, S. -H.; Kang, S. -H.; Belharouak, I. Journal of Power Sources, Vol. 177, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.10.062	journal	February 2008
A new SiO/C anode composition for lithium-ion battery Doh, Chil-Hoon; Park, Chul-Wan; Shin, Hye-Min Journal of Power Sources, Vol. 179, Issue 1, p. 367-370 https://doi.org/10.1016/j.jpowsour.2007.12.074	journal	April 2008
A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment Ito, Atsushi; Li, Decheng; Ohsawa, Yasuhiko Journal of Power Sources, Vol. 183, Issue 1, p. 344-346 https://doi.org/10.1016/j.jpowsour.2008.04.086	journal	August 2008
Improvement of cycle behaviour of SiO/C anode composite by thermochemically generated Li₄SiO₄ inert phase for lithium batteries Veluchamy, Angathevar; Doh, Chil-Hoon; Kim, Dong-Hun Journal of Power Sources, Vol. 188, Issue 2, p. 574-577 https://doi.org/10.1016/j.jpowsour.2008.11.137	journal	March 2009
Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating Liu, Y.; Wen, Z. Y.; Wang, X. Y. Journal of Power Sources, Vol. 189, Issue 1, p. 480-484 https://doi.org/10.1016/j.jpowsour.2008.12.045	journal	April 2009
Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni_0.17Li_0.2Co_0.07Mn_0.56]O₂ Ito, Atsushi; Li, Decheng; Sato, Yuichi Journal of Power Sources, Vol. 195, Issue 2, p. 567-573 https://doi.org/10.1016/j.jpowsour.2009.07.052	journal	January 2010
Nano-sized SiO_x/C composite anode for lithium ion batteries Wang, Jing; Zhao, Hailei; He, Jianchao Journal of Power Sources, Vol. 196, Issue 10, p. 4811-4815 https://doi.org/10.1016/j.jpowsour.2011.01.053	journal	May 2011
SiO_x–graphite as negative for high energy Li-ion batteries Guerfi, A.; Charest, P.; Dontigny, M. Journal of Power Sources, Vol. 196, Issue 13, p. 5667-5673 https://doi.org/10.1016/j.jpowsour.2011.02.018	journal	July 2011
Interweaved Si@SiO_x/C nanoporous spheres as anode materials for Li-ion batteries Tao, Hua-Chao; Huang, Mian; Fan, Li-Zhen Solid State Ionics, Vol. 220, p. 1-6 https://doi.org/10.1016/j.ssi.2012.05.014	journal	July 2012
A Nanostructured SiAl_0.2O Anode Material for Lithium Batteries Jeong, Goojin; Kim, Young-Ugk; Krachkovskiy, Sergey A. Chemistry of Materials, Vol. 22, Issue 19, p. 5570-5579 https://doi.org/10.1021/cm101747w	journal	October 2010
Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes Ruffo, Riccardo; Hong, Seung Sae; Chan, Candace K. The Journal of Physical Chemistry C, Vol. 113, Issue 26, p. 11390-11398 https://doi.org/10.1021/jp901594g	journal	June 2009
Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries Cui, Li-Feng; Yang, Yuan; Hsu, Ching-Mei Nano Letters, Vol. 9, Issue 9, p. 3370-3374 https://doi.org/10.1021/nl901670t	journal	September 2009
Electrochemical Intercalation of Lithium into Graphite in Acetonitrile Solutions: The Effect of the Anion Nature Popova, S. S.; Ol'shanskaya, L. N.; Pominova, T. V. Russian Journal of Electrochemistry, Vol. 38, Issue 4, p. 362-368 https://doi.org/10.1023/A:1015379603083	journal	April 2002
High-performance lithium-ion anodes using a hierarchical bottom-up approach Magasinski, A.; Dixon, P.; Hertzberg, B. Nature Materials, Vol. 9, Issue 4, p. 353-358 https://doi.org/10.1038/nmat2725	journal	March 2010
High-performance lithium battery anodes using silicon nanowires Chan, Candace K.; Peng, Hailin; Liu, Gao Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35 https://doi.org/10.1038/nnano.2007.411	journal	December 2007
Nano-SnSb alloy deposited on MCMB as an anode material for lithium ion batteries Shi, Lihong; Li, Hong; Wang, Zhaoxiang Journal of Materials Chemistry, Vol. 11, Issue 5, p. 1502-1505 https://doi.org/10.1039/b009907o	journal	January 2001
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/b702425h	journal	January 2007
Electrical transport in doped multiwalled carbon nanotubes Liu, K.; Avouris, Ph.; Martel, R. Physical Review B, Vol. 63, Issue 16, Article No. 161404(R) https://doi.org/10.1103/PhysRevB.63.161404	journal	April 2001
High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young‐Il Electrochemical and Solid-State Letters, Vol. 2, Issue 3, p. 107-110 https://doi.org/10.1149/1.1390750	journal	January 1999
Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling Wang, C. S.; Wu, G. T.; Zhang, X. B. Journal of The Electrochemical Society, Vol. 145, Issue 8, p. 2751-2758 https://doi.org/10.1149/1.1838709	journal	January 1998
Nano Si Cluster- SiO_x‐C Composite Material as High-Capacity Anode Material for Rechargeable Lithium Batteries Morita, Tomokazu; Takami, Norio Journal of The Electrochemical Society, Vol. 153, Issue 2, p. A425-A430 https://doi.org/10.1149/1.2142295	journal	January 2006
High Capacity, Surface-Modified Layered Li [Li _(1−x) ∕ ₃Mn _(2−x) ∕ ₃Ni_x ∕ ₃Co_{x ∕ 3} ] O₂ Cathodes with Low Irreversible Capacity Loss Wu, Y.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 9, Issue 5, p. A221-A224 https://doi.org/10.1149/1.2180528	journal	March 2006
AlF₃-Coating to Improve High Voltage Cycling Performance of Li[Ni_1∕3]Co_1∕3]Mn_1∕3]O₂ Cathode Materials for Lithium Secondary Batteries Sun, Y.-K.; Cho, S.-W.; Lee, S.-W. Journal of The Electrochemical Society, Vol. 154, Issue 3, p. A168-A172 https://doi.org/10.1149/1.2422890	journal	January 2007
Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries Miyachi, Mariko; Yamamoto, Hironori; Kawai, Hidemasa Journal of The Electrochemical Society, Vol. 154, Issue 4, p. A376-A380 https://doi.org/10.1149/1.2455963	journal	January 2007
Significant Improvement of Electrochemical Performance of AlF₃-Coated Li[Ni_0.8Co_0.1Mn_0.1]O₂ Cathode Materials Woo, S.-U.; Yoon, C. S.; Amine, K. Journal of The Electrochemical Society, Vol. 154, Issue 11, p. A1005-A1009 https://doi.org/10.1149/1.2776160	journal	January 2007
Nonflammable Hydrofluoroether for Lithium-Ion Batteries: Enhanced Rate Capability, Cyclability, and Low-Temperature Performance Naoi, Katsuhiko; Iwama, Etsuro; Ogihara, Nobuhiro Journal of The Electrochemical Society, Vol. 156, Issue 4, p. A272-A276 https://doi.org/10.1149/1.3073552	journal	January 2009
Electrochemical Behavior of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries Achiha, Takashi; Nakajima, Tsuyoshi; Ohzawa, Yoshimi Journal of The Electrochemical Society, Vol. 156, Issue 6, p. A483-A488 https://doi.org/10.1149/1.3111904	journal	January 2009
Li-Ion Battery Performance with FSI-Based Ionic Liquid Electrolyte and Fluorinated Solvent-Based Electrolyte Ishikawa, Masashi; Yamagata, Masaki; Sugimoto, Toshinori https://doi.org/10.1149/1.3563087	journal	January 2011

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