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Kinetic simulations of ignited mode cesium vapor thermionic converters

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/5.0117599· OSTI ID:1924503
 [1];  [2];  [2];  [3]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); North Carolina State Univ., Raleigh, NC (United States)
  2. Modern Electron Inc., Bothell, WA (United States)
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Cesium vapor thermionic converters are an attractive method of converting high-temperature heat directly to electricity, but theoretical descriptions of the systems have been difficult due to the multi-step ionization of Cs through inelastic electron–neutral collisions. This work presents particle-in-cell simulations of these converters, using a direct simulation Monte Carlo collision model to track 52 excited states of Cs. Here, these simulations show the dominant role of multi-step ionization, which also varies significantly based on both the applied voltage bias and pressure. The electron energy distribution functions are shown to be highly non-Maxwellian in the cases analyzed here. A comparison with previous approaches is presented, and large differences are found in ionization rates due especially to the fact that previous approaches have assumed Maxwellian electron distributions. Finally, an open question regarding the nature of the plasma sheaths in the obstructed regime is discussed. The one-dimensional simulations did not produce stable obstructed regime operation and thereby do not support the double-sheath hypothesis.
Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Fusion Energy Sciences (FES)
Grant/Contract Number:
NA0003525
OSTI ID:
1924503
Alternate ID(s):
OSTI ID: 2311658
Report Number(s):
SAND2023-12185J
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 2 Vol. 133; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (29)

Principles of Plasma Discharges and Materials Processing book January 2005
Weighted Particles in Coulomb Collision Simulations Based on the Theory of a Cumulative Scattering Angle journal September 1998
Recombination, radiative energy loss and level populations in nonequilibrium cesium discharges journal February 1968
The Richardson constant for thermionic emission in Schottky barrier diodes journal April 1965
DC arc photography and modelling journal November 2002
A Unified Theoretical Description of Thermionic Converter Performance Characteristics journal April 1968
Transport Phenomena in Low‐Energy Plasmas journal August 1966
Theory of Thermionic Converter Extinguished‐Mode Operation with Applications to Converter Diagnostics journal January 1967
Ion‐Current and Schottky Effects in Thermionic Diodes journal October 1967
Thermionic Converters Operating in the Ignited Mode. Part I: Theoretical Output‐Current Characteristics journal June 1966
An analytical model of thermionic discharges journal March 1986
Final report on testing of TOPAZ II unit Ya-21u: Output power characteristics and system capabilities conference January 1996
Wall emission dominated discharge channel journal January 1981
Nonlinear dynamical behavior of thermionic low pressure discharges. I. Simulation journal June 1995
Solving the Boltzmann equation to obtain electron transport coefficients and rate coefficients for fluid models journal October 2005
Electron collisions with cesium atoms—benchmark calculations and application to modeling an excimer-pumped alkali laser journal May 2014
Power law fitting of the ion saturation current and the three-temperature Maxwellian EEDF in a multi-dipole confined hot cathode discharge: an experimental revisitation journal April 2022
Recombination between electrons and atomic ions, I. Optically thin plasmas
  • Bates, David Robert; Kingston, A. E.; McWhirter, R. W. P.
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 267, Issue 1330, p. 297-312 https://doi.org/10.1098/rspa.1962.0101
journal May 1962
Classical Theory of Atomic Collisions. I. Theory of Inelastic Collisions journal April 1965
The Effect of Space Charge and Residual Gases on Thermionic Currents in High Vacuum journal December 1913
Simulations of argon plasma decay in a thermionic converter journal February 2021
Theory of cumulative small-angle collisions in plasmas journal April 1997
Discharge From Hot Cao journal May 1911
Thermionic energy conversion plasmas journal January 1991
Analysis of the arc mode operation of the cesium vapor thermionic energy converter journal January 1963
Review on Thermionic Energy Converters journal June 2016
Introduction to Plasma Physics book January 1995
A New Overview of The Trilinos Project journal January 2012
Thermionic Energy Conversion in the Twenty-first Century: Advances and Opportunities for Space and Terrestrial Applications journal November 2017