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Water-Assisted Lift-Off Process for Flexible CdTe Solar Cells

Journal Article · · ACS Applied Energy Materials
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  1. University of Toledo, OH (United States). Wright Center for Photovoltaics Innovation and Commercialization (PVIC)
  2. Department of Physics and Astronomy, and Wright Center for Photovoltaics Innovation and Commercialization (PVIC), University of Toledo, Toledo, Ohio 43606, Unites States
  3. National Renewable Energy Laboratory (NREL), Golden, CO (United States). Materials Science Center
  4. Rensselaer Polytechnic Institute, Troy, NY (United States)

In recent years, various lift-off methods have been developed to fabricate lightweight and flexible cadmium telluride (CdTe)-based solar cells. In this work, we report flexible cadmium sulfide (CdS)/CdTe solar cells using a water-assisted lift-off approach. Here we demonstrate that an additional cadmium chloride treatment for the CdS film is critical to improve the grain size of CdS and the post-deposited CdTe film and the electron conductivity of the CdS film. As a result, the quality of the CdS/CdTe front junction is significantly improved with reduced nonradiative recombination. Finally, our lightweight and flexible polycrystalline CdTe solar cells demonstrate a champion power conversion efficiency of 12.6%.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; Air Force Research Laboratory; US Department of Defense (DoD)
Grant/Contract Number:
AC36-08GO28308; EE0008974
OSTI ID:
1924017
Report Number(s):
NREL/JA--5K00-85273; MainId:86046; UUID:4516c8c8-4f78-4518-be1a-1efabf88bdf1; MainAdminID:68696
Journal Information:
ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 2 Vol. 6; ISSN 2574-0962
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (22)

Water‐Assisted Liftoff of Polycrystalline CdS/CdTe Thin Films Using Heterogeneous Interfacial Engineering journal May 2019
Solar cell efficiency tables (version 57) journal November 2020
Flexible CdTe solar cells on polymer films journal January 2001
The effect of oxygen on interface microstructure evolution in CdS/CdTe solar cells journal January 2002
Water-assisted exfoliation of epitaxial CdTe film from mica analyzed with azimuthal RHEED journal January 2021
Effect of CdCl2 annealing treatment on thin CdS films prepared by chemical bath deposition journal September 2010
Epitaxial CdTe Thin Films on Mica by Vapor Transport Deposition for Flexible Solar Cells journal April 2020
Eliminating S-Kink To Maximize the Performance of MgZnO/CdTe Solar Cells journal March 2019
Effects of Cu Precursor on the Performance of Efficient CdTe Solar Cells journal August 2021
Two-Dimensional Cadmium Chloride Nanosheets in Cadmium Telluride Solar Cells journal June 2017
Thermomechanical Lift-Off and Recontacting of CdTe Solar Cells journal November 2018
SnO 2 -Catalyzed Oxidation in High-Efficiency CdTe Solar Cells journal March 2019
Revealing the Importance of Front Interface Quality in Highly Doped CdSe x Te 1– x Solar Cells journal November 2021
Doping of polycrystalline CdTe for high-efficiency solar cells on flexible metal foil journal August 2013
20%-efficient polycrystalline Cd(Se,Te) thin-film solar cells with compositional gradient near the front junction journal December 2022
14%-efficient flexible CdTe solar cells on ultra-thin glass substrates journal April 2014
High-efficiency, flexible CdTe solar cells on ultra-thin glass substrates journal March 2015
Ambient CdCl 2 treatment on CdS buffer layer for improved performance of Sb 2 Se 3 thin film photovoltaics journal October 2015
Epitaxial lift-off CdTe/MgCdTe double heterostructures for thin-film and flexible solar cells applications journal May 2021
(Cd,Zn,Mg)Te-based microcavity on MgTe sacrificial buffer: Growth, lift-off, and transmission studies of polaritons journal April 2018
Chemical structure of buried interfaces in CdTe thin film solar cells conference June 2010
CuSCN as the Back Contact for Efficient ZMO/CdTe Solar Cells journal April 2020

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