Performance investigation of alkaline direct methanol fuel cell with commercial PGM-free cathodic materials

Vecchio, Carmelo Lo; Lyu, Xiang; Gatto, Irene; Zulevi, Barr; Serov, Alexey; Baglio, Vincenzo; Vecchio, Carmelo Lo; Gatto, Irene; Baglio, Vincenzo

doi:10.1016/j.jpowsour.2023.232732

Title: Performance investigation of alkaline direct methanol fuel cell with commercial PGM-free cathodic materials

Journal Article · Tue Jan 31 00:00:00 EST 2023 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2023.232732· OSTI ID:1923960

Vecchio, Carmelo Lo ^[1]; Lyu, Xiang ^[2]; Gatto, Irene ^[1]; Zulevi, Barr ^[3];

^[2]; Baglio, Vincenzo ^[1]; Vecchio, Carmelo Lo ^[1]; Gatto, Irene ^[1]; Baglio, Vincenzo ^[1]

Consiglio Nazionale delle Ricerche (CNR), Messina (Italy). Istituto di Tecnologie Avanzate per l’Energia (ITAE)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Pajarito Powder, LLC PPC, Albuquerque, NM (United States)

Because little progress has been made in investigating the performance of alkaline direct methanol fuel cells (ADMFCs) with commercial materials (including platinum group metal (PGM)-free catalysts, anion exchange ionomers (AEIs), and anion exchange membranes (AEMs)), the objective of this work is to evaluate the performance of ADMFCs with all commercial materials, in order to establish a reference against which the performance of newly developed materials can be compared. Fe-N-C catalysts, Fumasep (FAA-3-50) based AEMs, and FAA3 based AEIs are here employed, and the parameters such as of operating temperature and methanol concentration are investigated and optimized. Electrochemical measurements show a performance increase with the temperature from 40 to 60 °C, and with the methanol concentration (from 1 to 5 M); followed by insignificant decrease with the further increase to 10 M. The best performance is achieved with 5 M methanol at 60 °C, and the remarkable powder density of 48.2 mW cm^-2 was demonstrated under these conditions. This work provides insight into the large-scale application of ADMFC with commercial PGM-free materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725; EE0008419

OSTI ID:: 1923960

Alternate ID(s):: OSTI ID: 1923434

Journal Information:: Journal of Power Sources, Vol. 561; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (48)

An analysis of additional energy requirement to meet the sustainable development goals Simsek, Yeliz; Santika, Wayan G.; Anisuzzaman, M. Journal of Cleaner Production, Vol. 272 https://doi.org/10.1016/j.jclepro.2020.122646	journal	November 2020
Designing energy-efficient, economically sustainable and environmentally safe cropping system for the rainfed maize–fallow land of the Eastern Himalayas Babu, Subhash; Mohapatra, K. P.; Das, Anup Science of The Total Environment, Vol. 722 https://doi.org/10.1016/j.scitotenv.2020.137874	journal	June 2020
Analysis of Fossil Fuel Energy Consumption and Environmental Impacts in European Countries Martins, Florinda; Felgueiras, Carlos; Smitkova, Miroslava Energies, Vol. 12, Issue 6 https://doi.org/10.3390/en12060964	journal	March 2019
Symmetric and asymmetric impact of economic growth, capital formation, renewable and non-renewable energy consumption on environment in OECD countries Mujtaba, Aqib; Jena, Pabitra Kumar; Bekun, Festus Victor Renewable and Sustainable Energy Reviews, Vol. 160 https://doi.org/10.1016/j.rser.2022.112300	journal	May 2022
Assessment of lignite upgrade and hydrogen evolution via electrolysis Lyu, Xiang; Hu, Junyi Energy Conversion and Management, Vol. 253 https://doi.org/10.1016/j.enconman.2021.115181	journal	February 2022
Supported bimetallic nanoparticles as anode catalysts for direct methanol fuel cells: A review Kaur, Akaljot; Kaur, Gagandeep; Singh, Prit Pal International Journal of Hydrogen Energy, Vol. 46, Issue 29 https://doi.org/10.1016/j.ijhydene.2021.02.037	journal	April 2021
Development of a universal method for high yield of furfural and hydrogen from raw lignocellulosic biomass Lyu, Xiang Bioresource Technology Reports, Vol. 18 https://doi.org/10.1016/j.biteb.2022.101022	journal	June 2022
Graphene-templated synthesis of palladium nanoplates as novel electrocatalyst for direct methanol fuel cell Yang, Hujiang; Geng, Liang; Zhang, Yuting Applied Surface Science, Vol. 466 https://doi.org/10.1016/j.apsusc.2018.10.050	journal	February 2019
Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production Duan, Chuancheng; Kee, Robert; Zhu, Huayang Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0333-2	journal	March 2019
Advances in hybrid composite membranes engineering for high-performance direct methanol fuel cells by alignment of 2D nanostructures and a dual-layer approach Simari, Cataldo; Enotiadis, Apostolos; Lo Vecchio, Carmelo Journal of Membrane Science, Vol. 599 https://doi.org/10.1016/j.memsci.2020.117858	journal	April 2020
Platinum group metal-free Fe-based (Fe N C) oxygen reduction electrocatalysts for direct alcohol fuel cells Berretti, Enrico; Longhi, Mariangela; Atanassov, Plamen Current Opinion in Electrochemistry, Vol. 29 https://doi.org/10.1016/j.coelec.2021.100756	journal	October 2021
Catalyst layer formulations for slot-die coating of PEM fuel cell electrodes Sharma, Jaswinder; Lyu, Xiang; Reshetenko, Tatyana International Journal of Hydrogen Energy, Vol. 47, Issue 84 https://doi.org/10.1016/j.ijhydene.2022.08.157	journal	October 2022
Design of graded cathode catalyst layers with various ionomers for fuel cell application Lyu, Xiang; Van Cleve, Tim; Young, Erica Journal of Power Sources, Vol. 556 https://doi.org/10.1016/j.jpowsour.2022.232530	journal	February 2023
Palladium in fuel cell catalysis Antolini, Ermete Energy & Environmental Science, Vol. 2, Issue 9 https://doi.org/10.1039/b820837a	journal	January 2009
Renewable Methanol Synthesis Roode‐Gutzmer, Quirina I.; Kaiser, Doreen; Bertau, Martin ChemBioEng Reviews, Vol. 6, Issue 6 https://doi.org/10.1002/cben.201900012	journal	December 2019
A Direct Methanol Alkaline Fuel Cell Based on Poly(phenylene) Anion Exchange Membranes Janarthanan, Rajeswari; Kishore Pilli, Satyananda; Horan, James L. Journal of The Electrochemical Society, Vol. 161, Issue 9 https://doi.org/10.1149/2.1041409jes	journal	January 2014
Ionomer Significance in Alkaline Direct Methanol Fuel Cell to Achieve High Power with a Quarternized Poly(terphenylene) Membrane Galvan, Vicente; Shrimant, Bharat; Bae, Chulsung ACS Applied Energy Materials, Vol. 4, Issue 6 https://doi.org/10.1021/acsaem.1c00681	journal	June 2021
Anion-exchange membranes in electrochemical energy systems Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R. Energy & Environmental Science, Vol. 7, Issue 10, p. 3135-3191 https://doi.org/10.1039/C4EE01303D	journal	January 2014
Active direct methanol fuel cell: An overview Alias, M. S.; Kamarudin, S. K.; Zainoodin, A. M. International Journal of Hydrogen Energy, Vol. 45, Issue 38 https://doi.org/10.1016/j.ijhydene.2020.04.202	journal	July 2020
Recent advances in multi-scale design and construction of materials for direct methanol fuel cells Xia, Zhangxun; Zhang, Xiaoming; Sun, Hai Nano Energy, Vol. 65 https://doi.org/10.1016/j.nanoen.2019.104048	journal	November 2019
Chemical Vapor Deposition for N/S-Doped Single Fe Site Catalysts for the Oxygen Reduction in Direct Methanol Fuel Cells Li, Xiaohang; Yang, Xiaoxuan; Liu, Liting ACS Catalysis, Vol. 11, Issue 12 https://doi.org/10.1021/acscatal.0c05446	journal	June 2021
Surface Adsorption Affects the Performance of Alkaline Anion-Exchange Membrane Fuel Cells Maurya, Sandip; Dumont, Joseph H.; Villarrubia, Claudia Narvaez ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b03227	journal	August 2018
Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs Omasta, Travis J.; Park, Andrew M.; LaManna, Jacob M. Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C8EE00122G	journal	January 2018
Catalytic Advantages, Challenges, and Priorities in Alkaline Membrane Fuel Cells Firouzjaie, Horie Adabi; Mustain, William E. ACS Catalysis, Vol. 10, Issue 1 https://doi.org/10.1021/acscatal.9b03892	journal	November 2019
Direct Methanol Anion Exchange Membrane Fuel Cell with a Non-Platinum Group Metal Cathode based on Iron-Aminoantipyrine Catalyst Janarthanan, Rajeswari; Serov, Alexey; Pilli, Satyananda Kishore Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.209	journal	September 2015
Design of PGM-free cathodic catalyst layers for advanced PEM fuel cells Reshetenko, Tatyana; Odgaard, Madeleine; Randolf, Günter Applied Catalysis B: Environmental, Vol. 312 https://doi.org/10.1016/j.apcatb.2022.121424	journal	September 2022
Mesoporous textured Fe-N-C electrocatalysts as highly efficient cathodes for proton exchange membrane fuel cells Akula, Srinu; Mooste, Marek; Zulevi, Barr Journal of Power Sources, Vol. 520 https://doi.org/10.1016/j.jpowsour.2021.230819	journal	February 2022
Mesoporous iron-nitrogen co-doped carbon material as cathode catalyst for the anion exchange membrane fuel cell Lilloja, Jaana; Mooste, Marek; Kibena-Põldsepp, Elo Journal of Power Sources Advances, Vol. 8 https://doi.org/10.1016/j.powera.2021.100052	journal	April 2021
Characterizing Complex Gas–Solid Interfaces with in Situ Spectroscopy: Oxygen Adsorption Behavior on Fe–N–C Catalysts Dzara, Michael J.; Artyushkova, Kateryna; Sougrati, Moulay Tahar The Journal of Physical Chemistry C, Vol. 124, Issue 30 https://doi.org/10.1021/acs.jpcc.0c05244	journal	July 2020
Structure of Active Sites of Fe-N-C Nano-Catalysts for Alkaline Exchange Membrane Fuel Cells Kishi, Hirofumi; Sakamoto, Tomokazu; Asazawa, Koichiro Nanomaterials, Vol. 8, Issue 12 https://doi.org/10.3390/nano8120965	journal	November 2018
Anionic Exchange Membrane for Photo-Electrolysis Application Lo Vecchio, Carmelo; Carbone, Alessandra; Trocino, Stefano Polymers, Vol. 12, Issue 12 https://doi.org/10.3390/polym12122991	journal	December 2020
Investigation of Supported Pd-Based Electrocatalysts for the Oxygen Reduction Reaction: Performance, Durability and Methanol Tolerance Lo Vecchio, Carmelo; Alegre, Cinthia; Sebastián, David Materials, Vol. 8, Issue 12 https://doi.org/10.3390/ma8125438	journal	November 2015
Tailoring active sites of iron-nitrogen-carbon catalysts for oxygen reduction in alkaline environment: Effect of nitrogen-based organic precursor and pyrolysis atmosphere Freitas, Williane da Silva; D'Epifanio, Alessandra; Ficca, Valerio C. A. Electrochimica Acta, Vol. 391 https://doi.org/10.1016/j.electacta.2021.138899	journal	September 2021
Insights on the extraordinary tolerance to alcohols of Fe-N-C cathode catalysts in highly performing direct alcohol fuel cells Sebastián, D.; Serov, A.; Matanovic, I. Nano Energy, Vol. 34 https://doi.org/10.1016/j.nanoen.2017.02.039	journal	April 2017
Performance, methanol tolerance and stability of Fe-aminobenzimidazole derived catalyst for direct methanol fuel cells Sebastián, David; Serov, Alexey; Artyushkova, Kateryna Journal of Power Sources, Vol. 319 https://doi.org/10.1016/j.jpowsour.2016.04.067	journal	July 2016
Methanol-Tolerant M–N–C Catalysts for Oxygen Reduction Reactions in Acidic Media and Their Application in Direct Methanol Fuel Cells Lo Vecchio, Carmelo; Sebastián, David; Lázaro, María Catalysts, Vol. 8, Issue 12 https://doi.org/10.3390/catal8120650	journal	December 2018
Study of operating conditions and cell design on the performance of alkaline anion exchange membrane based direct methanol fuel cells Prakash, G. K. Surya; Krause, Frederick C.; Viva, Federico A. Journal of Power Sources, Vol. 196, Issue 19 https://doi.org/10.1016/j.jpowsour.2011.05.056	journal	October 2011
High-Performance Polymer Fiber Membrane Based Direct Methanol Fuel Cell System with Non-Platinum Catalysts Tan, Qiang; Qu, Ting; Shu, Cheng-yong ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 20 https://doi.org/10.1021/acssuschemeng.9b03497	journal	September 2019
Poly (2, 6-dimethyl-1, 4-phenylene)/polysulfone anion exchange membrane blended with TiO2 with improved water uptake for alkaline fuel cell application Msomi, P. F.; Nonjola, P. T.; Ndungu, P. G. International Journal of Hydrogen Energy, Vol. 45, Issue 53 https://doi.org/10.1016/j.ijhydene.2020.08.012	journal	October 2020
Electrooxidation study of pure ethanol/methanol and their mixture for the application in direct alcohol alkaline fuel cells (DAAFCs) Gupta, Uday Kumar; Pramanik, Hiralal International Journal of Hydrogen Energy, Vol. 44, Issue 1 https://doi.org/10.1016/j.ijhydene.2018.03.008	journal	January 2019
Novel fluoropolymer anion exchange membranes for alkaline direct methanol fuel cells Zhang, Yanmei; Fang, Jun; Wu, Yongbin Journal of Colloid and Interface Science, Vol. 381, Issue 1 https://doi.org/10.1016/j.jcis.2012.05.043	journal	September 2012
Guanidinium based blend anion exchange membranes for direct methanol alkaline fuel cells (DMAFCs) Sajjad, Syed D.; Liu, Dong; Wei, Zi Journal of Power Sources, Vol. 300 https://doi.org/10.1016/j.jpowsour.2015.08.002	journal	December 2015
Transition metal-nitrogen co-doped carbide-derived carbon catalysts for oxygen reduction reaction in alkaline direct methanol fuel cell Ratso, Sander; Kruusenberg, Ivar; Käärik, Maike Applied Catalysis B: Environmental, Vol. 219 https://doi.org/10.1016/j.apcatb.2017.07.036	journal	December 2017
High-performance oxygen reduction electrocatalysts derived from uniform cobalt–adenine assemblies Shen, Mengxia; Zheng, Li-Rong; He, Wenhui Nano Energy, Vol. 17 https://doi.org/10.1016/j.nanoen.2015.08.007	journal	October 2015
Scalable preparation of sized-controlled Co-N-C electrocatalyst for efficient oxygen reduction reaction Ai, Kelong; Li, Zelun; Cui, Xiaoqiang Journal of Power Sources, Vol. 368 https://doi.org/10.1016/j.jpowsour.2017.09.067	journal	November 2017
Commercial platinum group metal-free cathodic electrocatalysts for highly performed direct methanol fuel cell applications Lo Vecchio, C.; Serov, A.; Romero, H. Journal of Power Sources, Vol. 437 https://doi.org/10.1016/j.jpowsour.2019.226948	journal	October 2019
Recent trends on the application of PGM-free catalysts at the cathode of anion exchange membrane fuel cells Osmieri, Luigi; Pezzolato, Lorenzo; Specchia, Stefania Current Opinion in Electrochemistry, Vol. 9 https://doi.org/10.1016/j.coelec.2018.05.011	journal	June 2018
State-of-the-art and developmental trends in platinum group metal-free cathode catalyst for anion exchange membrane fuel cell (AEMFC) Hossen, Md. Mosaddek; Hasan, Md. Shamim; Sardar, Md. Riajul Islam Applied Catalysis B: Environmental, Vol. 325 https://doi.org/10.1016/j.apcatb.2022.121733	journal	May 2023

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