13C NMR study of amino acid salts in facilitated transport membranes for post-combustion carbon capture

Chen, Ting-Yu; Deng, Xuepeng; Lin, Li-Chiang; Ho, W. S. Winston

doi:10.1016/j.memsci.2022.121309

Title: ¹³C NMR study of amino acid salts in facilitated transport membranes for post-combustion carbon capture

Journal Article · Fri Dec 23 00:00:00 EST 2022 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2022.121309· OSTI ID:1922219

Chen, Ting-Yu ^[1]; Deng, Xuepeng ^[1]; Lin, Li-Chiang ^[2];

^[1]

The Ohio State Univ., Columbus, OH (United States)
The Ohio State Univ., Columbus, OH (United States); National Taiwan Univ., Taipei (Taiwan)

Some of amino acid salts (AASs) have been demonstrated to be effective mobile carriers in facilitated transport membranes (FTMs) to achieve superior CO₂ permeance and CO₂/N₂ selectivity for CO₂ capture from flue gas. Understandings of how the structures of different AASs affect the chemistry of the amine–CO₂ reaction are essential for the future development of more efficient AAS mobile carriers. In this study, the reaction chemistry of selected AASs with CO₂ was investigated by ¹³C nuclear magnetic resonance (NMR) spectroscopy. The CO₂ loading and the distribution of major reaction products, including carbamate and bicarbonate products of each studied AAS were quantitatively analyzed. The positive correlation between the CO₂ loading of AAS (mol CO₂/g AAS) and the CO₂ permeance of FTMs suggested that AAS with a higher CO₂ loading may improve the performance of FTMs. Our results also showed that increasing the steric hindrance of AAS could be a practical way to promote the bicarbonate reaction pathway and thus potentially increase the CO₂ loading (mol CO₂/mol AAS). Moreover, 2-(1-piperazinyl)ethylamine (PZEA) was found to be a more effective multi-amine than piperazine (PZ) for synthesizing AASs due to the presence of more effective nitrogen sites per molecule. The superior CO₂ permeance of the PZEA-Sar membrane is also attributed to its more uniform membrane formation. As a result, the knowledge gained from this study will inform the rational design of more effective AAS carriers for CO₂ capture.

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Research Organization:: The Ohio State Univ., Columbus, OH (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE), Clean Coal and Carbon Management

Grant/Contract Number:: FE0031731

OSTI ID:: 1922219

Journal Information:: Journal of Membrane Science, Vol. 671; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Carbon capture
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Title: 13C NMR study of amino acid salts in facilitated transport membranes for post-combustion carbon capture

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Title: ¹³C NMR study of amino acid salts in facilitated transport membranes for post-combustion carbon capture