Nano-FTIR Spectroscopy of the Solid Electrolyte Interphase Layer on a Thin-Film Silicon Li-Ion Anode

Dopilka, Andrew; Gu, Yueran; Larson, Jonathan M.; Zorba, Vassilia; Kostecki, Robert

doi:10.1021/acsami.2c19484

Nano-FTIR Spectroscopy of the Solid Electrolyte Interphase Layer on a Thin-Film Silicon Li-Ion Anode

Journal Article · Wed Jan 25 00:00:00 EST 2023 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.2c19484· OSTI ID:1922120

^[1]; Gu, Yueran ^[2]; ^[1]; Zorba, Vassilia ^[2]; Kostecki, Robert ^[1]

Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States, Department of Mechanical Engineering, University of California, Berkeley, California 94720, United States

Not Available

View Journal Article

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1922120

Alternate ID(s):: OSTI ID: 2234177

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 5 Vol. 15; ISSN 1944-8244

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium-Ion Batteries McDowell, Matthew T.; Lee, Seok Woo; Nix, William D. Advanced Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adma.201301795	journal	August 2013
A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase Tan, Jian; Matz, John; Dong, Pei Advanced Energy Materials, Vol. 11, Issue 16 https://doi.org/10.1002/aenm.202100046	journal	March 2021
Effects of various LiPF6 salt concentrations on PEO-based solid polymer electrolytes Ibrahim, Suriani; Yassin, Mariah Mohd; Ahmad, Roslina Ionics, Vol. 17, Issue 5 https://doi.org/10.1007/s11581-011-0524-8	journal	February 2011
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling An, Seong Jin; Li, Jianlin; Daniel, Claus Carbon, Vol. 105 https://doi.org/10.1016/j.carbon.2016.04.008	journal	August 2016
In situ FTIR study of the Cu electrode/ethylene carbonate+dimethyl carbonate solution interface Ikezawa, Yasunari; Nishi, Hironori Electrochimica Acta, Vol. 53, Issue 10 https://doi.org/10.1016/j.electacta.2007.12.038	journal	April 2008
Surface layer formation on Sn anode: ATR FTIR spectroscopic characterization Song, Seung-Wan; Baek, Seung-Won Electrochimica Acta, Vol. 54, Issue 4 https://doi.org/10.1016/j.electacta.2008.09.021	journal	January 2009
The Effect of Pre-Analysis Washing on the Surface Film of Graphite Electrodes Somerville, L.; Bareño, J.; Jennings, P. Electrochimica Acta, Vol. 206 https://doi.org/10.1016/j.electacta.2016.04.133	journal	July 2016
Calendar-life versus cycle-life aging of lithium-ion cells with silicon-graphite composite electrodes Kalaga, Kaushik; Rodrigues, Marco-Tulio F.; Trask, Stephen E. Electrochimica Acta, Vol. 280 https://doi.org/10.1016/j.electacta.2018.05.101	journal	August 2018
Unraveling the Nanoscale Heterogeneity of Solid Electrolyte Interphase Using Tip-Enhanced Raman Spectroscopy Nanda, Jagjit; Yang, Guang; Hou, Tingzheng Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.05.026	journal	August 2019
A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries Edström, Kristina; Herstedt, Marie; Abraham, Daniel P. Journal of Power Sources, Vol. 153, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.05.062	journal	February 2006
Surface film formation on electrodes in a LiCoO2/graphite cell: A step by step XPS study Dedryvère, R.; Martinez, H.; Leroy, S. Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.033	journal	December 2007
Deciphering the multi-step degradation mechanisms of carbonate-based electrolyte in Li batteries Gachot, Gregory; Grugeon, Sylvie; Armand, Michel Journal of Power Sources, Vol. 178, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.11.110	journal	March 2008
The electrochemical behavior of poly 1-pyrenemethyl methacrylate binder and its effect on the interfacial chemistry of a silicon electrode Haregewoin, Atetegeb Meazah; Terborg, Lydia; Zhang, Liang Journal of Power Sources, Vol. 376 https://doi.org/10.1016/j.jpowsour.2017.11.060	journal	February 2018
Dynamic Structure and Chemistry of the Silicon Solid-Electrolyte Interphase Visualized by Cryogenic Electron Microscopy Huang, William; Wang, Jiangyan; Braun, Michael R. Matter, Vol. 1, Issue 5 https://doi.org/10.1016/j.matt.2019.09.020	journal	November 2019
Solid state vibrational spectroscopy of anhydrous lithium hexafluorophosphate (LiPF6) Kock, L. D.; Lekgoathi, M. D. S.; Crouse, P. L. Journal of Molecular Structure, Vol. 1026 https://doi.org/10.1016/j.molstruc.2012.05.053	journal	October 2012
Three-dimensional electronic resistivity mapping of solid electrolyte interphase on Si anode materials Stetson, Caleb; Yoon, Taeho; Coyle, Jaclyn Nano Energy, Vol. 55 https://doi.org/10.1016/j.nanoen.2018.11.007	journal	January 2019
Synchrotron infrared nano-spectroscopy and -imaging Bechtel, Hans A.; Johnson, Samuel C.; Khatib, Omar Surface Science Reports, Vol. 75, Issue 3 https://doi.org/10.1016/j.surfrep.2020.100493	journal	August 2020
Cryogenic Electron Microscopy for Energy Materials Zhang, Zewen; Cui, Yi; Vila, Rafael Accounts of Chemical Research, Vol. 54, Issue 18 https://doi.org/10.1021/acs.accounts.1c00183	journal	July 2021
Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase Cao, Chuntian; Pollard, Travis P.; Borodin, Oleg Chemistry of Materials, Vol. 33, Issue 18 https://doi.org/10.1021/acs.chemmater.1c01744	journal	September 2021
Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products Michan, Alison L.; Leskes, Michal; Grey, Clare P. Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04408	journal	December 2015
What Makes Fluoroethylene Carbonate Different? Shkrob, Ilya A.; Wishart, James F.; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 119, Issue 27 https://doi.org/10.1021/acs.jpcc.5b03591	journal	June 2015
Direct Determination of Solid-Electrolyte Interphase Thickness and Composition as a Function of State of Charge on a Silicon Anode Veith, Gabriel M.; Doucet, Mathieu; Baldwin, J. Kevin The Journal of Physical Chemistry C, Vol. 119, Issue 35 https://doi.org/10.1021/acs.jpcc.5b06817	journal	August 2015
Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF ₆ Parimalam, Bharathy S.; MacIntosh, Alex D.; Kadam, Rahul The Journal of Physical Chemistry C, Vol. 121, Issue 41 https://doi.org/10.1021/acs.jpcc.7b08433	journal	October 2017
IR Near-Field Study of the Solid Electrolyte Interphase on a Tin Electrode Ayache, Maurice; Lux, Simon Franz; Kostecki, Robert The Journal of Physical Chemistry Letters, Vol. 6, Issue 7 https://doi.org/10.1021/acs.jpclett.5b00263	journal	March 2015
NMR Study of the Degradation Products of Ethylene Carbonate in Silicon–Lithium Ion Batteries Jin, Yanting; Kneusels, Nis-Julian H.; Grey, Clare P. The Journal of Physical Chemistry Letters, Vol. 10, Issue 20 https://doi.org/10.1021/acs.jpclett.9b02454	journal	October 2019
Electrochemical Reactivity and Passivation of Silicon Thin-Film Electrodes in Organic Carbonate Electrolytes Hasa, Ivana; Haregewoin, Atetegeb M.; Zhang, Liang ACS Applied Materials & Interfaces, Vol. 12, Issue 36 https://doi.org/10.1021/acsami.0c09384	journal	August 2020
Resolving Nanoscopic and Mesoscopic Heterogeneity of Fluorinated Species in Battery Solid-Electrolyte Interphases by Cryogenic Electron Microscopy Huang, William; Wang, Hansen; Boyle, David T. ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00194	journal	March 2020
An X-ray Photoelectron Spectroscopy Primer for Solid Electrolyte Interphase Characterization in Lithium Metal Anodes Oyakhire, Solomon T.; Gong, Huaxin; Cui, Yi ACS Energy Letters, Vol. 7, Issue 8 https://doi.org/10.1021/acsenergylett.2c01227	journal	July 2022
Promising Routes to a High Li ⁺ Transference Number Electrolyte for Lithium Ion Batteries Diederichsen, Kyle M.; McShane, Eric J.; McCloskey, Bryan D. ACS Energy Letters, Vol. 2, Issue 11 https://doi.org/10.1021/acsenergylett.7b00792	journal	October 2017
Quantifying Nanoscale Electromagnetic Fields in Near-Field Microscopy by Fourier Demodulation Analysis Mooshammer, Fabian; Huber, Markus A.; Sandner, Fabian ACS Photonics, Vol. 7, Issue 2 https://doi.org/10.1021/acsphotonics.9b01533	journal	January 2020
Role of the LiPF ₆ Salt for the Long-Term Stability of Silicon Electrodes in Li-Ion Batteries – A Photoelectron Spectroscopy Study Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303399v	journal	January 2013
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes Michan, Alison L.; Divitini, Giorgio; Pell, Andrew J. Journal of the American Chemical Society, Vol. 138, Issue 25 https://doi.org/10.1021/jacs.6b02882	journal	June 2016
Identifying the Structural Basis for the Increased Stability of the Solid Electrolyte Interphase Formed on Silicon with the Additive Fluoroethylene Carbonate Jin, Yanting; Kneusels, Nis-Julian H.; Magusin, Pieter C. M. M. Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b06834	journal	October 2017
Lithium Ethylene Dicarbonate Identified as the Primary Product of Chemical and Electrochemical Reduction of EC in 1.2 M LiPF ₆ /EC:EMC Electrolyte Zhuang, Guorong V.; Xu, Kang; Yang, Hui The Journal of Physical Chemistry B, Vol. 109, Issue 37 https://doi.org/10.1021/jp052474w	journal	September 2005
XPS Valence Characterization of Lithium Salts as a Tool to Study Electrode/Electrolyte Interfaces of Li-Ion Batteries Dedryvère, R.; Leroy, S.; Martinez, H. The Journal of Physical Chemistry B, Vol. 110, Issue 26 https://doi.org/10.1021/jp061624f	journal	July 2006
Computational Study on the Solubility of Lithium Salts Formed on Lithium Ion Battery Negative Electrode in Organic Solvents Tasaki, Ken; Harris, Stephen J. The Journal of Physical Chemistry C, Vol. 114, Issue 17 https://doi.org/10.1021/jp100013h	journal	April 2010
Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 1. Spectroscopic Observations of Radical Intermediates Generated in One-Electron Reduction of Carbonates Shkrob, Ilya A.; Zhu, Ye; Marin, Timothy W. The Journal of Physical Chemistry C, Vol. 117, Issue 38, p. 19255-19269 https://doi.org/10.1021/jp406274e	journal	September 2013
Quantitative Measurement of Local Infrared Absorption and Dielectric Function with Tip-Enhanced Near-Field Microscopy Govyadinov, Alexander A.; Amenabar, Iban; Huth, Florian The Journal of Physical Chemistry Letters, Vol. 4, Issue 9 https://doi.org/10.1021/jz400453r	journal	April 2013
Nano-FTIR Absorption Spectroscopy of Molecular Fingerprints at 20 nm Spatial Resolution Huth, Florian; Govyadinov, Alexander; Amarie, Sergiu Nano Letters, Vol. 12, Issue 8 https://doi.org/10.1021/nl301159v	journal	July 2012
IR Near-Field Spectroscopy and Imaging of Single Li _x FePO ₄ Microcrystals Lucas, I. T.; McLeod, A. S.; Syzdek, J. S. Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl5010898	journal	December 2014
Subsurface chemical nanoidentification by nano-FTIR spectroscopy Mester, Lars; Govyadinov, Alexander A.; Chen, Shu Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17034-6	journal	July 2020
In situ infrared nanospectroscopy of the local processes at the Li/polymer electrolyte interface He, Xin; Larson, Jonathan M.; Bechtel, Hans A. Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29103-z	journal	March 2022
Revealing solid electrolyte interphase formation through interface-sensitive Operando X-ray absorption spectroscopy Swallow, Jack E. N.; Fraser, Michael W.; Kneusels, Nis-Julian H. Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-33691-1	journal	October 2022
Identifying the components of the solid–electrolyte interphase in Li-ion batteries Wang, Luning; Menakath, Anjali; Han, Fudong Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0304-z	journal	August 2019
Electrolyte design for LiF-rich solid–electrolyte interfaces to enable high-performance microsized alloy anodes for batteries Chen, Ji; Fan, Xiulin; Li, Qin Nature Energy, Vol. 5, Issue 5 https://doi.org/10.1038/s41560-020-0601-1	journal	April 2020
Calendar aging of silicon-containing batteries McBrayer, Josefine D.; Rodrigues, Marco-Tulio F.; Schulze, Maxwell C. Nature Energy, Vol. 6, Issue 9 https://doi.org/10.1038/s41560-021-00883-w	journal	September 2021
Determination of the Solid Electrolyte Interphase Structure Grown on a Silicon Electrode Using a Fluoroethylene Carbonate Additive Veith, Gabriel M.; Doucet, Mathieu; Sacci, Robert L. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-06555-8	journal	July 2017
Evaluating the solid electrolyte interphase formed on silicon electrodes: a comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry Fears, T. M.; Doucet, M.; Browning, J. F. Physical Chemistry Chemical Physics, Vol. 18, Issue 20 https://doi.org/10.1039/C6CP00978F	journal	January 2016
Intrinsic chemical reactivity of solid-electrolyte interphase components in silicon–lithium alloy anode batteries probed by FTIR spectroscopy Pekarek, Ryan T.; Affolter, Alec; Baranowski, Lauryn L. Journal of Materials Chemistry A, Vol. 8, Issue 16 https://doi.org/10.1039/C9TA13535A	journal	January 2020
Normal Vibrations of the Polymer Molecules of Helical Conformation. IV. Polyethylene Oxide and Polyethylene‐ d ₄ Oxide Yoshihara, Toshio; Tadokoro, Hiroyuki; Murahashi, Shunsuke The Journal of Chemical Physics, Vol. 41, Issue 9 https://doi.org/10.1063/1.1726373	journal	November 1964
Pseudoheterodyne detection for background-free near-field spectroscopy Ocelic, Nenad; Huber, Andreas; Hillenbrand, Rainer Applied Physics Letters, Vol. 89, Issue 10 https://doi.org/10.1063/1.2348781	journal	September 2006
Toward quantifying capacity losses due to solid electrolyte interphase evolution in silicon thin film batteries Steinrück, Hans-Georg; Cao, Chuntian; Veith, Gabriel M. The Journal of Chemical Physics, Vol. 152, Issue 8 https://doi.org/10.1063/1.5142643	journal	February 2020
The lithiation onset of amorphous silicon thin-film electrodes Hüger, Erwin; Uxa, Daniel; Yang, Fuqian Applied Physics Letters, Vol. 121, Issue 13 https://doi.org/10.1063/5.0109610	journal	September 2022
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Capturing the swelling of solid-electrolyte interphase in lithium metal batteries Zhang, Zewen; Li, Yuzhang; Xu, Rong Science, Vol. 375, Issue 6576 https://doi.org/10.1126/science.abi8703	journal	January 2022
In Situ XRD and Electrochemical Study of the Reaction of Lithium with Amorphous Silicon Hatchard, T. D.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1739217	journal	January 2004
Identification of Li Battery Electrolyte Degradation Products Through Direct Synthesis and Characterization of Alkyl Carbonate Salts Gireaud, L.; Grugeon, S.; Laruelle, S. Journal of The Electrochemical Society, Vol. 152, Issue 5 https://doi.org/10.1149/1.1872673	journal	January 2005
An In Situ X-Ray Diffraction Study of the Reaction of Li with Crystalline Si Li, Jing; Dahn, J. R. Journal of The Electrochemical Society, Vol. 154, Issue 3 https://doi.org/10.1149/1.2409862	journal	January 2007
Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie Journal of The Electrochemical Society, Vol. 156, Issue 12 https://doi.org/10.1149/1.3239850	journal	January 2009
Crack Pattern Formation in Thin Film Lithium-Ion Battery Electrodes Li, Juchuan; Dozier, Alan K.; Li, Yunchao Journal of The Electrochemical Society, Vol. 158, Issue 6 https://doi.org/10.1149/1.3574027	journal	January 2011
Critical Evaluation of Potentiostatic Holds as Accelerated Predictors of Capacity Fade during Calendar Aging Schulze, Maxwell C.; Rodrigues, Marco-Tulio F.; McBrayer, Josefine D. Journal of The Electrochemical Society, Vol. 169, Issue 5 https://doi.org/10.1149/1945-7111/ac6f88	journal	May 2022
Near-Field IR Nanoscale Imaging of the Solid Electrolyte Interphase on a HOPG Electrode Ayache, Maurice; Jang, Dongyoun; Syzdek, Jaroslaw Journal of The Electrochemical Society, Vol. 162, Issue 13 https://doi.org/10.1149/2.0101513jes	journal	January 2015
Negative Transference Numbers in Poly(ethylene oxide)-Based Electrolytes Pesko, Danielle M.; Timachova, Ksenia; Bhattacharya, Rajashree Journal of The Electrochemical Society, Vol. 164, Issue 11 https://doi.org/10.1149/2.0581711jes	journal	January 2017
Review—SEI: Past, Present and Future Peled, E.; Menkin, S. Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1441707jes	journal	January 2017
Enhanced resolution in subsurface near-field optical microscopy Krutokhvostov, Roman; Govyadinov, Alexander A.; Stiegler, Johannes M. Optics Express, Vol. 20, Issue 1 https://doi.org/10.1364/OE.20.000593	journal	December 2011
A Secondary Ion Mass Spectrometry Study on the Mechanisms of Amorphous Silicon Electrode Lithiation in Li-Ion Batteries Hüger, Erwin; Jerliu, Bujar; Dörrer, Lars Zeitschrift für Physikalische Chemie, Vol. 229, Issue 9 https://doi.org/10.1515/zpch-2014-0650	journal	January 2015
Gwyddion: an open-source software for SPM data analysis Nečas, David; Klapetek, Petr Open Physics, Vol. 10, Issue 1 https://doi.org/10.2478/s11534-011-0096-2	journal	January 2012

Similar Records

Solid Electrolyte Interphase on Native Oxide-Terminated Silicon Anodes for Li-Ion Batteries

Journal Article · Thu Feb 28 19:00:00 EST 2019 · Joule · OSTI ID:1605600

Related Subjects

25 ENERGY STORAGE
FTIR
SEI
anode
electrodes
electrolyte
electrolytes
infrared light
interface
layers
silicon
spectroscopy
surface chemistry

Nano-FTIR Spectroscopy of the Solid Electrolyte Interphase Layer on a Thin-Film Silicon Li-Ion Anode

Citation Formats

References (69)

Similar Records

Related Subjects