Antimony redox processes in the environment: A critical review of associated oxidants and reductants

Zhang, Yidan; O’Loughlin, Edward J.; Kwon, Man Jae

doi:10.1016/j.jhazmat.2022.128607

Antimony redox processes in the environment: A critical review of associated oxidants and reductants

Journal Article · Tue Mar 01 00:00:00 UTC 2022 · Journal of Hazardous Materials

DOI:https://doi.org/10.1016/j.jhazmat.2022.128607· OSTI ID:1915396

Zhang, Yidan ^[1]; O’Loughlin, Edward J. ^[2]; Kwon, Man Jae ^[1]

Korea Univ., Seoul, (Korea, Republic of)
Argonne National Lab. (ANL), Argonne, IL (United States)

The environmental behavior of antimony (Sb) has recently received greater attention due to the increasing global use of Sb in a range of industrial applications. Although present at trace levels in most natural systems, elevated Sb concentrations in aquatic and terrestrial environments may result from anthropogenic activities. The mobility and toxicity of Sb largely depend on its speciation, which is dependent to a large extent on its oxidation state. To a certain extent, our understanding of the environmental behavior of Sb has been informed by studies of the environmental behavior of arsenic (As), as Sb and As have somewhat similar chemical properties. However, recently it has become evident that the speciation of Sb and As, especially in the context of redox reactions, may be fundamentally different. Therefore, it is crucial to study the biogeochemical processes impacting Sb redox transformations to understand the behavior of Sb in natural and engineered environments. Currently, there is a growing body of literature involving the speciation, mobility, toxicity, and remediation of Sb, and several reviews on these general topics are available; however, a comprehensive review focused on Sb environmental redox chemistry is lacking. Herein, we provide a review of research conducted within the past two decades examining the redox chemistry of Sb in aquatic and terrestrial environments and identifies knowledge gaps that need to be addressed to develop a better understanding of Sb biogeochemistry for improved management of Sb in natural and engineered systems.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Korea Environmental Industry & Technology Institute (KEITI); National Research Foundation (NRF) of Korea; USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1915396

Journal Information:: Journal of Hazardous Materials, Journal Name: Journal of Hazardous Materials Vol. 431; ISSN 0304-3894

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Abiotic
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Antimony redox processes in the environment: A critical review of associated oxidants and reductants

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