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The state of zinc in methanol synthesis over a Zn/ZnO/Cu(211) model catalyst

Journal Article · · Science
 [1];  [2];  [3];  [2];  [4];  [5];  [6];  [2];  [2];  [3];  [3];  [3];  [3];  [3];  [3];  [3];  [7];  [3]
  1. Stockholm University (Sweden); SLAC
  2. University Innsbruck (Austria)
  3. Stockholm University (Sweden)
  4. Fritz Haber Institute of the Max-Planck Society, Berlin (Germany)
  5. Stockholm University (Sweden); Deutsches Elektronen-Synchrotron DESY, Hamburg (Germany)
  6. Technische University Wien, Vienna (Austria)
  7. Deutsches Elektronen-Synchrotron DESY, Hamburg (Germany)

The active chemical state of zinc (Zn) in a zinc-copper (Zn-Cu) catalyst during carbon dioxide/carbon monoxide (CO2/CO) hydrogenation has been debated to be Zn oxide (ZnO) nanoparticles, metallic Zn, or a Zn-Cu surface alloy. We used x-ray photoelectron spectroscopy at 180 to 500 millibar to probe the nature of Zn and reaction intermediates during CO2/CO hydrogenation over Zn/ZnO/Cu(211), where the temperature is sufficiently high for the reaction to rapidly turn over, thus creating an almost adsorbate-free surface. Tuning of the grazing incidence angle makes it possible to achieve either surface or bulk sensitivity. Hydrogenation of CO2 gives preference to ZnO in the form of clusters or nanoparticles, whereas in pure CO a surface Zn-Cu alloy becomes more prominent. Here, the results reveal a specific role of CO in the formation of the Zn-Cu surface alloy as an active phase that facilitates efficient CO2 methanol synthesis.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC); Swedish Research Council; Knut & Alice Wallenberg (KAW) Foundation; Stiftelsen för Strategisk Forskning (SSF)
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1908820
Journal Information:
Science, Journal Name: Science Journal Issue: 6593 Vol. 376; ISSN 0036-8075
Publisher:
AAASCopyright Statement
Country of Publication:
United States
Language:
English

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