skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A Review on Gel Polymer Electrolytes for Dye-Sensitized Solar Cells

Journal Article · · Micromachines
DOI:https://doi.org/10.3390/mi13050680· OSTI ID:1907932

Significant growth has been observed in the research domain of dye-sensitized solar cells (DSSCs) due to the simplicity in its manufacturing, low cost, and high-energy conversion efficiency. The electrolytes in DSSCs play an important role in determining the photovoltaic performance of the DSSCs, e.g., volatile liquid electrolytes suffer from poor thermal stability. Although low volatility liquid electrolytes and solid polymer electrolytes circumvent the stability issues, gel polymer electrolytes with high ionic conductivity and enduring stability are stimulating substitutes for liquid electrolytes in DSSC. Here, in this review paper, the advantages of gel polymer electrolytes (GPEs) are discussed along with other types of electrolytes, e.g., solid polymer electrolytes and p-type semiconductor-based electrolytes. The benefits of incorporating ionic liquids into GPEs are highlighted in conjunction with the factors that affect the ionic conductivity of GPEs. The strategies on the improvement of the properties of DSSCs based on GPE are also presented.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE); USDOE Office of Environmental Management (EM); Indian Institute of Technology Jodhpur
Grant/Contract Number:
AC07-05ID14517; I/SEED/AKG/20190022
OSTI ID:
1907932
Report Number(s):
INL/JOU-22-70462; TRN: US2311977
Journal Information:
Micromachines, Vol. 13, Issue 5; ISSN 2072-666X
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
English

References (82)

A new alkyl-imidazole polymer prepared as an inonic polymer electrolyte by in situ polymerization of dye sensitized solar cells journal June 2004
Photoelectrochemical cells journal November 2001
Fabrication of an Efficient Solid-State Dye-Sensitized Solar Cell journal March 2003
Syndiotactic Polystyrene-Based Ionogel Membranes for High Temperature Electrochemical Applications journal August 2017
Optimization the solid-state electrolytes for dye-sensitized solar cells journal January 2009
Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies journal October 1998
Pseudohalogens for Dye-Sensitized TiO 2 Photoelectrochemical Cells journal June 2001
Gel polymer electrolyte system based on starch grafted with ionic liquid: Synthesis, characterization and its application in dye-sensitized solar cell journal March 2019
A cobalt complex redox shuttle for dye-sensitized solar cells with high open-circuit potentials journal January 2012
Dye-Sensitized Solar Cells journal November 2010
Influence of different concentrations of 4-tert-butyl-pyridine in a gel polymer electrolyte towards improved performance of Dye-Sensitized Solar Cells (DSSC) journal March 2021
Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells journal June 2004
High-conversion-efficiency organic dye-sensitized solar cells with a novel indoline dye journal January 2008
Novel cobalt redox materials admitted in natrosol polymer with a thiophene based additive as a gel polymer electrolyte to tune up the efficiency of dye sensitized solar cells journal January 2020
Highly efficient semiconducting TiO2 photoelectrodes prepared by aerosol pyrolysis journal April 1995
Device Performance of Emerging Photovoltaic Materials (Version 2) journal November 2021
Device Performance of Emerging Photovoltaic Materials (Version 1) journal December 2020
Effect of Additives on the Photovoltaic Performance of Coumarin-Dye-Sensitized Nanocrystalline TiO 2 Solar Cells journal May 2004
Boosting Efficiencies of Gel Polymer Electrolyte Based Dye Sensitized Solar Cells Using Mixed Cations journal January 2017
A dye-sensitized nano-porous solid-state photovoltaic cell journal December 1995
A stable gel electrolyte based on poly butyl acrylate (PBA)-co-poly acrylonitrile (PAN) for solid-state dye-sensitized solar cells journal September 2020
Brief Overview of Dye-Sensitized Solar Cells journal March 2012
Stepwise Cosensitization of Nanocrystalline TiO2Films Utilizing Al2O3Layers in Dye-Sensitized Solar Cells journal October 2008
Free-standing polypyrrole films as substrate-free and Pt-free counter electrodes for quasi-solid dye-sensitized solar cells journal December 2012
Improved dye-sensitized solar cells using ionic nanocomposite gel electrolytes journal June 2004
Incorporation of organic additives with electron rich donors (N, O, S) in gelatin gel polymer electrolyte for dye sensitized solar cells journal April 2021
Guar gum-based polymer gel electrolyte for dye-sensitized solar cell applications journal September 2020
A New Silicon p‐n Junction Photocell for Converting Solar Radiation into Electrical Power journal May 1954
Rechargeable solid-state battery using a proton-conducting composite as electrolyte journal June 2002
Complexes of alkali metal ions with poly(ethylene oxide) journal November 1973
Augmentation of dye-sensitized solar cell photovoltaic conversion efficiency via incorporation of terpolymer Poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate) based gel polymer electrolytes journal May 2021
Naphthalene imides as novel p-type sensitizers for NiO-based p-type dye-sensitized solar cells journal January 2020
Recent research progress on polymer electrolytes for dye-sensitized solar cells journal August 2009
A Quasi-Solid State DSSC with 10.1% Efficiency through Molecular Design of the Charge-Separation and -Transport journal June 2016
Multifunctional Iodide-Free Polymeric Ionic Liquid for Quasi-Solid-State Dye-Sensitized Solar Cells with a High Open-Circuit Voltage journal June 2016
Optimization of distyryl-Bodipy chromophores for efficient panchromatic sensitization in dye sensitized solar cells journal January 2011
A technique to compare polythiophene solid-state dye sensitized TiO2 solar cells to liquid junction devices journal February 2003
Efficient Electron Transfer and Sensitizer Regeneration in Stable π-Extended Tetrathiafulvalene-Sensitized Solar Cells journal April 2010
A quasi solid state dye sensitized solar cell based on gelatin/multiwalled carbon nanotube gel electrolyte and ZnO nanorod photoanode journal April 2016
Performance of ZnO/ZnS nanocomposite based dye-sensitized solar cell with chitosan-polymer electrolyte journal January 2021
A study on the microstructural development of gel polymer electrolytes and different imidazolium-based ionic liquids for dye-sensitized solar cells journal January 2021
Solid-state metal-hydride batteries using heteropolyacid hydrate as an electrolyte journal November 2003
Advancing beyond current generation dye-sensitized solar cells journal January 2008
Strong and Flexible Composite Solid Polymer Electrolyte Membranes for Li-Ion Batteries journal October 2019
Quasi-Solid-State Dye-Sensitized TiO 2 Solar Cells:  Effective Charge Transport in Mesoporous Space Filled with Gel Electrolytes Containing Iodide and Iodine journal November 2001
Efficiency enhancement of dye-sensitized solar cell based gel polymer electrolytes using Poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate)/tetrapropylammonium iodide journal March 2019
New D-π-A dyes for efficient dye-sensitized solar cells journal March 2012
How the Nature of Triphenylamine-Polyene Dyes in Dye-Sensitized Solar Cells Affects the Open-Circuit Voltage and Electron Lifetimes journal February 2010
The application of P(MMA-co-MAA)/PEG polyblend gel electrolyte in quasi-solid state dye-sensitized solar cell at higher temperature journal December 2007
Recent developments in redox electrolytes for dye-sensitized solar cells journal January 2012
The polymer gel electrolyte based on poly(methyl methacrylate) and its application in quasi-solid-state dye-sensitized solar cells journal July 2008
Direct light-induced polymerization of cobalt-based redox shuttles: an ultrafast way towards stable dye-sensitized solar cells journal January 2015
A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte journal May 2003
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films journal October 1991
Metal Oxides for Dye-Sensitized Solar Cells journal February 2009
Dye-sensitized solar cells based on nanoparticle-decorated ZnO/TiO 2 core/shell nanorod arrays journal July 2009
Charge Transport and Back Reaction in Solid-State Dye-Sensitized Solar Cells:  A Study Using Intensity-Modulated Photovoltage and Photocurrent Spectroscopy journal August 2003
One- and two-dimensional carbon nanomaterials as counter electrodes for dye-sensitized solar cells journal August 2011
Long-term stability testing of dye-sensitized solar cells journal June 2004
Characterization of Titanium Dioxide Blocking Layers in Dye-Sensitized Nanocrystalline Solar Cells journal December 2003
Quasi-solid-state dye-sensitized solar cells employing ternary component polymer-gel electrolytes journal June 2008
Solid‐State Organic/Inorganic Hybrid Solar Cells Based on Poly(octylthiophene) and Dye‐Sensitized Nanobrookite and Nanoanatase TiO 2 Electrodes journal February 2008
Preparation of nano-sized UV-absorbing titanium-oxo-clusters via a photo-curing ceramer process journal January 2005
An all carbon counter electrode for dye sensitized solar cells journal January 2012
A Solvent-Free, SeCN - /(SeCN) 3 - Based Ionic Liquid Electrolyte for High-Efficiency Dye-Sensitized Nanocrystalline Solar Cells journal June 2004
π-Expanded dibenzo-BODIPY with near-infrared light absorption: Investigation of photosensitizing properties of NiO-based p-type dye-sensitized solar cells journal November 2019
Influence of alkylpyridine additives in electrolyte solution on the performance of dye-sensitized solar cell journal October 2003
New insights into dye-sensitized solar cells with polymer electrolytes journal January 2009
Synthesis of gel polymer electrolyte with PEO/RbI/I2 for DSSC applications journal January 2021
Nanochemistry aspects of titania in dye-sensitized solar cells journal January 2009
Characteristics of Dye-Sensitized Solar Cell Assembled from Modified Chitosan-Based Gel Polymer Electrolytes Incorporated with Potassium Iodide journal September 2020
A new ionic liquid based quasi-solid state electrolyte for dye-sensitized solar cells journal February 2008
Non-edible oil based polyurethane acrylate with tetrabutylammonium iodide gel polymer electrolytes for dye-sensitized solar cells journal September 2020
Performance of dye-sensitized solar cells employing polymer gel as an electrolyte and the influence of nano-porous materials as fillers journal September 2018
Anomaly of charge transport of an iodide/tri-iodide redox couple in an ionic liquid and its importance in dye-sensitized solar cells journal January 2005
Synthesis of a dibenzo-BODIPY-incorporating phenothiazine dye as a panchromatic sensitizer for dye-sensitized solar cells journal January 2017
An efficient quasi-solid state dye sensitized solar cells based on graphene oxide/gelatin gel electrolyte with NiO supported TiO2 photoanode journal February 2017
Physico-chemical processes in imidazolium ionic liquids journal January 2006
Kinetic and Energetic Paradigms for Dye-Sensitized Solar Cells: Moving from the Ideal to the Real journal November 2009
Preparation of porous, chemically cross-linked, PVdF-based gel polymer electrolytes for rechargeable lithium batteries journal August 2004
Stable high efficiency dye-sensitized solar cells based on a cobalt polymer gel electrolyte journal January 2013
Enhance the Performance of Dye-Sensitized Solar Cells by Co-grafting Amphiphilic Sensitizer and Hexadecylmalonic Acid on TiO 2 Nanocrystals journal December 2003