Thermal behavior of ammonium octafluorodirhenate(III)

Louis-Jean, James; Jang, Harry; Poineau, Frederic

doi:10.1007/s11164-022-04867-7

Thermal behavior of ammonium octafluorodirhenate(III)

Journal Article · Mon Nov 07 00:00:00 EST 2022 · Research on Chemical Intermediates

DOI:https://doi.org/10.1007/s11164-022-04867-7· OSTI ID:1907466

^[1]; ^[2]; Poineau, Frederic ^[2]

Univ. of Nevada, Las Vegas, NV (United States); Savannah River National Laboratory
Univ. of Nevada, Las Vegas, NV (United States)

The thermal behavior of (NH₄)₂[Re₂F₈]·2H₂O salt was studied in the temperature range 150–700 °C under flowing nitrogen gas. The decomposition products were studied by powder X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Results are consistent with the formation of (NH₄)₂[Re₂F₈] salt at 150 °C, amorphous rhenium metal at 300 and 400 °C, and crystalline rhenium metal at 500 and 700 °C. A mechanism of formation of rhenium metal from (NH₄)₂[Re₂F₈]·2H₂O was proposed. Here, the effect of crystallite size and lattice strain was evaluated at 500 and 700 °C from powder XRD peak broadenings using both Williamson–Hall and the modified Scherrer methods.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003180; NA0003948

OSTI ID:: 1907466

Journal Information:: Research on Chemical Intermediates, Journal Name: Research on Chemical Intermediates Journal Issue: 1 Vol. 49; ISSN 0922-6168

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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