Practically Accessible All-Solid-State Batteries Enabled by Organosulfide Cathodes and Sulfide Electrolytes

Ji, Weixiao; Zhang, Xiaoxiao; Zheng, Dong; Huang, He; Lambert, Tristan H.; Qu, Deyang

doi:10.1002/adfm.202202919

Practically Accessible All-Solid-State Batteries Enabled by Organosulfide Cathodes and Sulfide Electrolytes

Journal Article · Wed Apr 06 00:00:00 EDT 2022 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202202919· OSTI ID:1907115

Ji, Weixiao ^[1]; Zhang, Xiaoxiao ^[2]; Zheng, Dong ^[2]; Huang, He ^[3]; Lambert, Tristan H. ^[3]; ^[2]

Univ. of Wisconsin, Milwaukee, WI (United States); University of Wisconsin-Milwaukee
Univ. of Wisconsin, Milwaukee, WI (United States)
Cornell Univ., Ithaca, NY (United States)

The combination of organic electrode materials and sulfide electrolytes is expected to enable the development of all-solid-state organic batteries featuring high energy density and long-term sustainability. In this work, thiuram hexasulfide is reported as a low-cost and high-capacity organic cathode for solid-state batteries based on sulfide electrolytes, delivering a capacity of ~600 mAh g^-1 and retaining 80.8 % capacity after 500 cycles. An electrochemically reversible change of the cathode interface was revealed upon cycling. Full cell displays an oscillating stress change up to 0.6 MPa during cycling, predominated by the anode side. The energy density is 1140 Wh kg^-1 at the material level and 376 Wh kg^-1 at the electrode level, which are among the best-reported organic cathodes to date. A high areal capacity of 10.4 mAh cm^-2 is reached with a high mass loading cathode. A dry-film approach is further explored to manufacture sheet-type cells. Free-standing electrolyte film is merely ~48 μm thick and demonstrates an ultralow areal resistance of 3.9 Ω cm², significantly boosts the cell-level energy density and reduces the cell internal resistance.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Wisconsin, Milwaukee, WI (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008859; SC0012704

OSTI ID:: 1907115

Alternate ID(s):: OSTI ID: 1861441

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 27 Vol. 32; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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