Stable Cuprous Hydroxide Nanostructures by Organic Ligand Functionalization

Liu, Qiming; Peng, Yi; Masood, Zaheer; DuBois, Davida; Tressel, John; Nichols, Forrest; Ashby, Paul; Mercado, Rene; Assafa, Tufa; Pan, Dingjie; Kuo, Han‐Lin; Lu, Jennifer Q.; Bridges, Frank; Millhauser, Glenn; Ge, Qingfeng; Chen, Shaowei

doi:10.1002/adma.202208665

Stable Cuprous Hydroxide Nanostructures by Organic Ligand Functionalization

Journal Article · Mon Dec 19 23:00:00 EST 2022 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202208665· OSTI ID:1905952

Liu, Qiming ^[1]; Peng, Yi ^[1]; Masood, Zaheer ^[2]; DuBois, Davida ^[1]; Tressel, John ^[1]; Nichols, Forrest ^[1]; Ashby, Paul ^[3]; Mercado, Rene ^[1]; Assafa, Tufa ^[1]; Pan, Dingjie ^[1]; Kuo, Han‐Lin ^[4]; Lu, Jennifer Q. ^[4]; Bridges, Frank ^[5]; Millhauser, Glenn ^[1]; Ge, Qingfeng ^[2]; ^[1]

Department of Chemistry and Biochemistry University of California 1156 High Street Santa Cruz CA 95064 USA
School of Chemical and Biomolecular Sciences Southern Illinois University Carbondale IL 62901 USA
Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
School of Engineering University of California 5200 North Lake Road Merced CA 95343 USA
Department of Physics University of California 1156 High Street Santa Cruz CA 95064 USA

Abstract

Copper compounds have been extensively investigated for diverse applications. However, studies of cuprous hydroxide (CuOH) have been scarce due to structural metastability. Herein, a facile, wet‐chemistry procedure is reported for the preparation of stable CuOH nanostructures via deliberate functionalization with select organic ligands, such as acetylene and mercapto derivatives. The resulting nanostructures are found to exhibit a nanoribbon morphology consisting of small nanocrystals embedded within a largely amorphous nanosheet‐like scaffold. The acetylene derivatives are found to anchor onto the CuOH forming CuC linkages, whereas CuS interfacial bonds are formed with the mercapto ligands. Effective electronic coupling occurs at the ligand‐core interface in the former, in contrast to mostly non‐conjugated interfacial bonds in the latter, as manifested in spectroscopic measurements and confirmed in theoretical studies based on first principles calculations. Notably, the acetylene‐capped CuOH nanostructures exhibit markedly enhanced photodynamic activity in the inhibition of bacteria growth, as compared to the mercapto‐capped counterparts due to a reduced material bandgap and effective photocatalytic generation of reactive oxygen species. Results from this study demonstrate that deliberate structural engineering with select organic ligands is an effective strategy in the stabilization and functionalization of CuOH nanostructures, a critical first step in exploring their diverse applications.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515; AC02-05CH11231

OSTI ID:: 1905952

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 8 Vol. 35; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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