Temperature-dependent behavior in the local structure of BaTiO3 nanocrystals

Cottingham, Patrick; Brutchey, Richard L.

doi:10.1039/d2ce00705c

Temperature-dependent behavior in the local structure of BaTiO₃ nanocrystals

Journal Article · Thu Jul 07 00:00:00 EDT 2022 · CrystEngComm

DOI:https://doi.org/10.1039/d2ce00705c· OSTI ID:1903211

Cottingham, Patrick ^[1]; Brutchey, Richard L. ^[2]

Univ. of Southern California, Los Angeles, CA (United States); University of Southern California
Univ. of Southern California, Los Angeles, CA (United States)

Here, we use pair distribution function analysis of synchrotron X-ray total scattering data to inspect the local structure of BaTiO₃ nanocrystals from 253 K < T < 413 K. The local structure consists of ca. r = 35 Å domains in which Ti⁴⁺ displacements have the same coherence length as the overall perovskite structure.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Southern California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0006812

OSTI ID:: 1903211

Alternate ID(s):: OSTI ID: 1875205
OSTI ID: 1900802

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 30 Vol. 24; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (19)

Template-Free, Low-Temperature Synthesis of Crystalline Barium Titanate Nanoparticles under Bio-Inspired Conditions Brutchey, Richard L.; Morse, Daniel E. Angewandte Chemie International Edition, Vol. 45, Issue 39, p. 6564-6566 https://doi.org/10.1002/anie.200602571	journal	October 2006
Effect of Ligand Polarity on the Internal Dipoles and Ferroelectric Distortion in BaTiO ₃ Nanocubes Jiang, Bo; Usher, Tedi‐Marie; Jothi, Palani Raja Chemistry – A European Journal, Vol. 27, Issue 32 https://doi.org/10.1002/chem.202100692	journal	May 2021
Room-Temperature Synthetic Pathways to Barium Titanate Nanocrystals Beier, Christopher W.; Cuevas, Marie A.; Brutchey, Richard L. Small, Vol. 4, Issue 12 https://doi.org/10.1002/smll.200800761	journal	December 2008
Size and scaling effects in barium titanate. An overview Buscaglia, Vincenzo; Randall, Clive A. Journal of the European Ceramic Society, Vol. 40, Issue 11 https://doi.org/10.1016/j.jeurceramsoc.2020.01.021	journal	September 2020
Depressed Phase Transitions and Thermally Persistent Local Distortions in CsPbBr ₃ Quantum Dots Cottingham, Patrick; Brutchey, Richard L. Chemistry of Materials, Vol. 30, Issue 19 https://doi.org/10.1021/acs.chemmater.8b02295	journal	September 2018
Coherent Nanotwins and Dynamic Disorder in Cesium Lead Halide Perovskite Nanocrystals Bertolotti, Federica; Protesescu, Loredana; Kovalenko, Maksym V. ACS Nano, Vol. 11, Issue 4 https://doi.org/10.1021/acsnano.7b00017	journal	April 2017
Probing Local Dipoles and Ligand Structure in BaTiO ₃ Nanoparticles Page, Katharine; Proffen, Thomas; Niederberger, Markus Chemistry of Materials, Vol. 22, Issue 15 https://doi.org/10.1021/cm100440p	journal	August 2010
Barium Titanium Glycolate: A New Barium Titanate Powder Precursor Day, Victor W.; Eberspacher, Todd A.; Frey, Matthew H. Chemistry of Materials, Vol. 8, Issue 2 https://doi.org/10.1021/cm950547q	journal	January 1996
Structures of the ferroelectric phases of barium titanate Kwei, G. H.; Lawson, A. C.; Billinge, S. J. L. The Journal of Physical Chemistry, Vol. 97, Issue 10 https://doi.org/10.1021/j100112a043	journal	March 1993
Crystal Structure and the Paraelectric-to-Ferroelectric Phase Transition of Nanoscale BaTiO ₃ Smith, Millicent B.; Page, Katharine; Siegrist, Theo Journal of the American Chemical Society, Vol. 130, Issue 22 https://doi.org/10.1021/ja0758436	journal	June 2008
Structural Evolution of BaTiO ₃ Nanocrystals Synthesized at Room Temperature Rabuffetti, Federico A.; Brutchey, Richard L. Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja303184w	journal	May 2012
Ferroelectric order in individual nanometre-scale crystals Polking, Mark J.; Han, Myung-Geun; Yourdkhani, Amin Nature Materials, Vol. 11, Issue 8 https://doi.org/10.1038/nmat3371	journal	July 2012
Complex perovskite oxide nanocrystals: low-temperature synthesis and crystal structure Rabuffetti, Federico A.; Brutchey, Richard L. Dalton Trans., Vol. 43, Issue 39 https://doi.org/10.1039/C4DT01376J	journal	January 2014
Grain-size effect on structure and phase transformations for barium titanate Frey, M. H.; Payne, D. A. Physical Review B, Vol. 54, Issue 5 https://doi.org/10.1103/PhysRevB.54.3158	journal	August 1996
Structural coherence and ferroelectricity decay in submicron- and nano-sized perovskites Petkov, V.; Buscaglia, V.; Buscaglia, M. T. Physical Review B, Vol. 78, Issue 5 https://doi.org/10.1103/PhysRevB.78.054107	journal	August 2008
NMR Evidence for the Coexistence of Order-Disorder and Displacive Components in Barium Titanate Zalar, Boštjan; Laguta, Valentin V.; Blinc, Robert Physical Review Letters, Vol. 90, Issue 3 https://doi.org/10.1103/PhysRevLett.90.037601	journal	January 2003
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions Juhás, P.; Davis, T.; Farrow, C. L. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813005190	journal	March 2013
Dependence of the Crystal Structure on Particle Size in Barium Titanate Uchino, Kenji; Sadanaga, Eiji; Hirose, Terukiyo Journal of the American Ceramic Society, Vol. 72, Issue 8 https://doi.org/10.1111/j.1151-2916.1989.tb07706.x	journal	August 1989

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