Pt Single Atom Electrocatalysts at Graphene Edges for Efficient Alkaline Hydrogen Evolution

Tsounis, Constantine; Subhash, Bijil; Kumar, Priyank V.; Bedford, Nicholas M.; Zhao, Yufei; Shenoy, Joel; Ma, Zhipeng; Zhang, Ding; Toe, Cui Ying; Cheong, Soshan; Tilley, Richard D.; Lu, Xunyu; Dai, Liming; Han, Zhaojun; Amal, Rose

doi:10.1002/adfm.202203067

Pt Single Atom Electrocatalysts at Graphene Edges for Efficient Alkaline Hydrogen Evolution

Journal Article · Thu Sep 01 00:00:00 EDT 2022 · Adv. Funct. Mater.

DOI:https://doi.org/10.1002/adfm.202203067· OSTI ID:1900976

Tsounis, Constantine; Subhash, Bijil; Kumar, Priyank V.; Bedford, Nicholas M.; Zhao, Yufei; Shenoy, Joel; Ma, Zhipeng; Zhang, Ding; Toe, Cui Ying; Cheong, Soshan; Tilley, Richard D.; Lu, Xunyu; Dai, Liming; Han, Zhaojun; Amal, Rose

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: DOE - Office Of Science; FOREIGN

OSTI ID:: 1900976

Journal Information:: Adv. Funct. Mater., Journal Name: Adv. Funct. Mater. Journal Issue: (38) Vol. 32

Country of Publication:: United States

Language:: ENGLISH

References (49)

Cold-plasma technique enabled supported Pt single atoms with tunable coordination for hydrogen evolution reaction Li, Jing; Zhou, Yanan; Tang, Weijing Applied Catalysis B: Environmental, Vol. 285 https://doi.org/10.1016/j.apcatb.2020.119861	journal	May 2021
Engineering the Coordination Environment of Single-Atom Platinum Anchored on Graphdiyne for Optimizing Electrocatalytic Hydrogen Evolution Yin, Xue-Peng; Wang, Hong-Juan; Tang, Shang-Feng Angewandte Chemie International Edition, Vol. 57, Issue 30 https://doi.org/10.1002/anie.201804817	journal	June 2018
Energy Bandgap and Edge States in an Epitaxially Grown Graphene/h-BN Heterostructure Hwang, Beomyong; Hwang, Jeongwoon; Yoon, Jong Keon Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep31160	journal	August 2016
Induced spin–orbit splitting in graphene: the role of atomic number of the intercalated metal andπ–d hybridization Shikin, Alexander M.; Rybkin, Artem G.; Marchenko, Dmitry New Journal of Physics, Vol. 15, Issue 1 https://doi.org/10.1088/1367-2630/15/1/013016	journal	January 2013
Density functional theory in surface chemistry and catalysis Norskov, J. K.; Abild-Pedersen, F.; Studt, F. Proceedings of the National Academy of Sciences, Vol. 108, Issue 3 https://doi.org/10.1073/pnas.1006652108	journal	January 2011
Oxygen Reduction Reaction in a Droplet on Graphite: Direct Evidence that the Edge Is More Active than the Basal Plane Shen, Anli; Zou, Yuqin; Wang, Qiang Angewandte Chemie International Edition, Vol. 53, Issue 40 https://doi.org/10.1002/anie.201406695	journal	August 2014
Soft X-ray Absorption Spectroscopy Studies of the Electronic Structure Recovery of Graphene Oxide upon Chemical Defunctionalization Lee, Vincent; Dennis, Robert V.; Schultz, Brian J. The Journal of Physical Chemistry C, Vol. 116, Issue 38 https://doi.org/10.1021/jp306497f	journal	September 2012
RuO₂-coated vertical graphene hybrid electrodes for high-performance solid-state supercapacitors Han, Zhao Jun; Pineda, Shafique; Murdock, Adrian T. Journal of Materials Chemistry A, Vol. 5, Issue 33 https://doi.org/10.1039/C7TA03355A	journal	January 2017
Atomistic Insights into the Stability of Pt Single-Atom Electrocatalysts Speck, Florian D.; Paul, Michael T. Y.; Ruiz-Zepeda, Francisco Journal of the American Chemical Society, Vol. 142, Issue 36 https://doi.org/10.1021/jacs.0c07138	journal	August 2020
Probing the spontaneous reduction mechanism of platinum ions confined in the nanospace by X-ray absorption fine structure spectroscopy Jiang, Fangling; Li, Cheng; Fu, Haiying Physical Chemistry Chemical Physics, Vol. 18, Issue 28 https://doi.org/10.1039/C6CP02565J	journal	January 2016
X-Ray Spectroscopic Investigation of Chlorinated Graphene: Surface Structure and Electronic Effects Zhang, Xu; Schiros, Theanne; Nordlund, Dennis Advanced Functional Materials, Vol. 25, Issue 26 https://doi.org/10.1002/adfm.201500541	journal	May 2015
Nanowire-Mesh-Templated Growth of Out-of-Plane Three-Dimensional Fuzzy Graphene Garg, Raghav; Rastogi, Sahil K.; Lamparski, Michael ACS Nano, Vol. 11, Issue 6 https://doi.org/10.1021/acsnano.7b02612	journal	May 2017
Quick AS NEXAFS Tool ( QANT ): a program for NEXAFS loading and analysis developed at the Australian Synchrotron Gann, Eliot; McNeill, Christopher R.; Tadich, Anton Journal of Synchrotron Radiation, Vol. 23, Issue 1 https://doi.org/10.1107/S1600577515018688	journal	January 2016
Engineering the Coordination Environment of Single Cobalt Atoms for Efficient Oxygen Reduction and Hydrogen Evolution Reactions Sun, Tao; Zang, Wenjie; Yan, Huan ACS Catalysis, Vol. 11, Issue 8 https://doi.org/10.1021/acscatal.0c05577	journal	March 2021
Improved crystallographic data for graphite Howe, J. Y.; Rawn, C. J.; Jones, L. E. Powder Diffraction, Vol. 18, Issue 2 https://doi.org/10.1154/1.1536926	journal	June 2003
Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes Ledezma-Yanez, Isis; Wallace, W. David Z.; Sebastián-Pascual, Paula Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.31	journal	March 2017
Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution Liu, Daobin; Li, Xiyu; Chen, Shuangming Nature Energy, Vol. 4, Issue 6 https://doi.org/10.1038/s41560-019-0402-6	journal	June 2019
Edge state on hydrogen-terminated graphite edges investigated by scanning tunneling microscopy Kobayashi, Yousuke; Fukui, Ken-ichi; Enoki, Toshiaki Physical Review B, Vol. 73, Issue 12 https://doi.org/10.1103/PhysRevB.73.125415	journal	March 2006
Formation of nonbondingπelectronic states of graphite due to Pt-C hybridization Kondo, Takahiro; Iwasaki, Yosuke; Honma, Yujiro Physical Review B, Vol. 80, Issue 23 https://doi.org/10.1103/PhysRevB.80.233408	journal	December 2009
Development of efficient membrane electrode assembly for low cost hydrogen production by anion exchange membrane electrolysis Vincent, Immanuel; Kruger, Andries; Bessarabov, Dmitri International Journal of Hydrogen Energy, Vol. 42, Issue 16 https://doi.org/10.1016/j.ijhydene.2017.03.069	journal	April 2017
Is There Anything Better than Pt for HER? Hansen, Johannes Novak; Prats, Hector; Toudahl, Karl Krøjer ACS Energy Letters, Vol. 6, Issue 4 https://doi.org/10.1021/acsenergylett.1c00246	journal	March 2021
Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2 Cheng, Yi; Zhao, Shiyong; Li, Haobo Applied Catalysis B: Environmental, Vol. 243 https://doi.org/10.1016/j.apcatb.2018.10.046	journal	April 2019
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob Nature Materials, Vol. 5, Issue 11, p. 909-913 https://doi.org/10.1038/nmat1752	journal	October 2006
Edge state in graphene ribbons: Nanometer size effect and edge shape dependence Nakada, Kyoko; Fujita, Mitsutaka; Dresselhaus, Gene Physical Review B, Vol. 54, Issue 24 https://doi.org/10.1103/PhysRevB.54.17954	journal	December 1996
Why gold is the noblest of all the metals Hammer, B.; Norskov, J. K. Nature, Vol. 376, Issue 6537 https://doi.org/10.1038/376238a0	journal	July 1995
Topographic and Spectroscopic Characterization of Electronic Edge States in CVD Grown Graphene Nanoribbons Pan, Minghu; Girão, E. Costa; Jia, Xiaoting Nano Letters, Vol. 12, Issue 4 https://doi.org/10.1021/nl204392s	journal	January 2012
Raman spectroscopy as a versatile tool for studying the properties of graphene Ferrari, Andrea C.; Basko, Denis M. Nature Nanotechnology, Vol. 8, Issue 4 https://doi.org/10.1038/nnano.2013.46	journal	April 2013
Scaling Properties of Adsorption Energies for Hydrogen-Containing Molecules on Transition-Metal Surfaces Abild-Pedersen, F.; Greeley, J.; Studt, F. Physical Review Letters, Vol. 99, Issue 1 https://doi.org/10.1103/PhysRevLett.99.016105	journal	July 2007
Defect formation in graphene during low-energy ion bombardment Ahlberg, P.; Johansson, F. O. L.; Zhang, Z. -B. APL Materials, Vol. 4, Issue 4 https://doi.org/10.1063/1.4945587	journal	April 2016
Dual-metallic single Ru and Ni atoms decoration of MoS2 for high-efficiency hydrogen production Ge, Jingmin; Zhang, Dongbin; Qin, Yang Applied Catalysis B: Environmental, Vol. 298 https://doi.org/10.1016/j.apcatb.2021.120557	journal	December 2021
Edge Functionalization of Graphene and Two-Dimensional Covalent Organic Polymers for Energy Conversion and Storage Xiang, Zhonghua; Dai, Quanbin; Chen, Jian-Feng Advanced Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adma.201505788	journal	April 2016
1D metallic edge states of oxygen-terminated zigzag graphene edges Li, Y. Y.; Chen, M. X.; Weinert, M. 2D Materials, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1583/aaefdb	journal	March 2019
Raman Spectroscopy of Graphene Edges Casiraghi, C.; Hartschuh, A.; Qian, H. Nano Letters, Vol. 9, Issue 4 https://doi.org/10.1021/nl8032697	journal	April 2009
Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction Zhou, Kai Ling; Wang, Zelin; Han, Chang Bao Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-24079-8	journal	June 2021
Recommended Practices and Benchmark Activity for Hydrogen and Oxygen Electrocatalysis in Water Splitting and Fuel Cells Wei, Chao; Rao, Reshma R.; Peng, Jiayu Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201806296	journal	December 2018
Highly Selective Metal‐Free Electrochemical Production of Hydrogen Peroxide on Functionalized Vertical Graphene Edges Zhang, Ding; Tsounis, Constantine; Ma, Zhipeng Small, Vol. 18, Issue 1 https://doi.org/10.1002/smll.202105082	journal	November 2021
Enhanced Electrochemical CO ₂ Reduction of Cu@Cu _x O Nanoparticles Decorated on 3D Vertical Graphene with Intrinsic sp ³ ‐type Defect Ma, Zhipeng; Tsounis, Constantine; Kumar, Priyank V. Advanced Functional Materials, Vol. 30, Issue 24 https://doi.org/10.1002/adfm.201910118	journal	May 2020
Non-Noble Metal-based Carbon Composites in Hydrogen Evolution Reaction: Fundamentals to Applications Wang, Jing; Xu, Fan; Jin, Haiyan Advanced Materials, Vol. 29, Issue 14 https://doi.org/10.1002/adma.201605838	journal	February 2017
Observation of zigzag and armchair edges of graphite using scanning tunneling microscopy and spectroscopy Kobayashi, Yousuke; Fukui, Ken-ichi; Enoki, Toshiaki Physical Review B, Vol. 71, Issue 19 https://doi.org/10.1103/PhysRevB.71.193406	journal	May 2005
Considerations for the scaling-up of water splitting catalysts Kibsgaard, Jakob; Chorkendorff, Ib Nature Energy, Vol. 4, Issue 6 https://doi.org/10.1038/s41560-019-0407-1	journal	May 2019
Atomic Structure and Local Electronic States of Single Pt Atoms Dispersed on Graphene Yamazaki, Kenji; Maehara, Yosuke; Lee, Chi-Cheng The Journal of Physical Chemistry C, Vol. 122, Issue 48 https://doi.org/10.1021/acs.jpcc.8b04529	journal	November 2018
Role of edge geometry and chemistry in the electronic properties of graphene nanostructures Fujii, Shintaro; Ziatdinov, Maxim; Ohtsuka, Misako Faraday Discuss., Vol. 173 https://doi.org/10.1039/C4FD00073K	journal	January 2014
Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction Fang, Shi; Zhu, Xiaorong; Liu, Xiaokang Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14848-2	journal	February 2020
Opportunities and Challenges for Renewable Power-to-X Daiyan, Rahman; MacGill, Iain; Amal, Rose ACS Energy Letters, Vol. 5, Issue 12 https://doi.org/10.1021/acsenergylett.0c02249	journal	November 2020
Carbon-Defect-Driven Electroless Deposition of Pt Atomic Clusters for Highly Efficient Hydrogen Evolution Cheng, Qingqing; Hu, Chuangang; Wang, Guoliang Journal of the American Chemical Society, Vol. 142, Issue 12 https://doi.org/10.1021/jacs.9b11524	journal	February 2020
Valence Alignment of Mixed Ni–Fe Hydroxide Electrocatalysts through Preferential Templating on Graphene Edges for Enhanced Oxygen Evolution Tsounis, Constantine; Lu, Xunyu; Bedford, Nicholas M. ACS Nano, Vol. 14, Issue 9 https://doi.org/10.1021/acsnano.0c03380	journal	August 2020
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces Sheng, Wenchao; Myint, MyatNoeZin; Chen, Jingguang G. Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee00045a	journal	January 2013
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015

Similar Records

Descriptors for Hydrogen Evolution on Single Atom Catalysts in Nitrogen-Doped Graphene

Journal Article · Wed Aug 12 00:00:00 EDT 2020 · Journal of Physical Chemistry. C · OSTI ID:1657895

Co,N-codoped graphene as efficient electrocatalyst for hydrogen evolution reaction: Insight into the active centre

Journal Article · Mon Jul 31 00:00:00 EDT 2017 · Journal of Power Sources · OSTI ID:1463692

Pt Single Atom Electrocatalysts at Graphene Edges for Efficient Alkaline Hydrogen Evolution

Citation Formats

References (49)

Similar Records

Related Subjects