Structure of Deep Eutectic Solvents (DESs): What We Know, What We Want to Know, and Why We Need to Know It

Stephens, Nicole M.; Smith, Emily A.

doi:10.1021/acs.langmuir.2c02116

Structure of Deep Eutectic Solvents (DESs): What We Know, What We Want to Know, and Why We Need to Know It

Journal Article · Tue Nov 08 00:00:00 EST 2022 · Langmuir

DOI:https://doi.org/10.1021/acs.langmuir.2c02116· OSTI ID:1899325

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Ames Laboratory, and Iowa State University, Ames, IA (United States)

We report deep eutectic solvents (DESs) are a tunable class of solvents with many advantageous properties including good thermal stability, facile synthesis, low vapor pressure, and low-to-negligible toxicity. DESs are composed of hydrogen bond donors and acceptors that, when combined, significantly decrease the freezing point of the resulting solvent. DESs have distinct interfacial and bulk structural heterogeneity compared to traditional solvents, in part due to various intramolecular and intermolecular interactions. Many of the physiochemical properties observed for DESs are influenced by structure. However, our understanding of the interfacial and bulk structure of DESs is incomplete. To fully exploit these solvents in a range of applications including catalysis, separations, and electrochemistry, a better understanding of DES structure must be obtained. In this Perspective, we provide an overview of the current knowledge of the interfacial and bulk structure of DESs and suggest future research directions to improve our understanding of this important information.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1899325

Report Number(s):: IS-J-10,933

Journal Information:: Langmuir, Journal Name: Langmuir Journal Issue: 46 Vol. 38; ISSN 0743-7463

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (79)

Structure and hydrogen bonds of hydrophobic deep eutectic solvent‐aqueous liquid–liquid interfaces Abbas, Usman L.; Qiao, Qi; Nguyen, Manh Tien AIChE Journal, Vol. 67, Issue 12 https://doi.org/10.1002/aic.17427	journal	September 2021
The Effect of Water upon Deep Eutectic Solvent Nanostructure: An Unusual Transition from Ionic Mixture to Aqueous Solution Hammond, Oliver S.; Bowron, Daniel T.; Edler, Karen J. Angewandte Chemie International Edition, Vol. 56, Issue 33 https://doi.org/10.1002/anie.201702486	journal	August 2017
Strong Microheterogeneity in Novel Deep Eutectic Solvents Alizadeh, Vahideh; Geller, David; Malberg, Friedrich ChemPhysChem, Vol. 20, Issue 14 https://doi.org/10.1002/cphc.201900307	journal	June 2019
Electrochemical interfaces in ionic liquids/deep eutectic solvents incorporated with water: A review Liu, Shuai; Tan, Zhuo; Wu, Jiedu Electrochemical Science Advances https://doi.org/10.1002/elsa.202100199	journal	March 2022
Thermo-oxidative stability of ionic liquids as lubricating fluids Minami, Ichiro; Kamimura, Hideto; Mori, Shigeyuki Journal of Synthetic Lubrication, Vol. 24, Issue 3 https://doi.org/10.1002/jsl.36	journal	January 2007
Simulation of deep eutectic solvents: Progress to promises Velez, Caroline; Acevedo, Orlando WIREs Computational Molecular Science, Vol. 12, Issue 4 https://doi.org/10.1002/wcms.1598	journal	January 2022
Basics and properties of deep eutectic solvents: a review El Achkar, Tracy; Greige-Gerges, Hélène; Fourmentin, Sophie Environmental Chemistry Letters, Vol. 19, Issue 4 https://doi.org/10.1007/s10311-021-01225-8	journal	April 2021
Investigating the effect of systematically modifying the molar ratio of hydrogen bond donor and acceptor on solvation characteristics of deep eutectic solvents formed using choline chloride salt and polyalcohols Abbasi, Nabeel Mujtaba; Farooq, Muhammad Qamar; Anderson, Jared L. Journal of Chromatography A, Vol. 1667 https://doi.org/10.1016/j.chroma.2022.462871	journal	March 2022
Nanostructure of a deep eutectic solvent at solid interfaces Elbourne, Aaron; Meftahi, Nastaran; Greaves, Tamar L. Journal of Colloid and Interface Science, Vol. 591 https://doi.org/10.1016/j.jcis.2021.01.089	journal	June 2021
Self-assembled nanostructure induced in deep eutectic solvents via an amphiphilic hydrogen bond donor Buzolic, Joshua J.; Li, Hua; Aman, Zachary M. Journal of Colloid and Interface Science, Vol. 616 https://doi.org/10.1016/j.jcis.2022.02.029	journal	June 2022
Deep eutectic solvents vs ionic liquids: Similarities and differences Płotka-Wasylka, Justyna; de la Guardia, Miguel; Andruch, Vasil Microchemical Journal, Vol. 159 https://doi.org/10.1016/j.microc.2020.105539	journal	December 2020
Molecular dynamics simulations of mixed deep eutectic solvents and their interaction with nanomaterials Atilhan, Mert; Aparicio, Santiago Journal of Molecular Liquids, Vol. 283 https://doi.org/10.1016/j.molliq.2019.03.068	journal	June 2019
Effect of water addition on choline chloride/glycol deep eutectic solvents: Characterization of their structural and physicochemical properties Gabriele, Francesco; Chiarini, Marco; Germani, Raimondo Journal of Molecular Liquids, Vol. 291 https://doi.org/10.1016/j.molliq.2019.111301	journal	October 2019
Computational and experimental study of propeline: A choline chloride based deep eutectic solvent Ferreira, Elisabete S. C.; Voroshylova, Iuliia V.; Figueiredo, Nádia M. Journal of Molecular Liquids, Vol. 298 https://doi.org/10.1016/j.molliq.2019.111978	journal	January 2020
Transition from molecular- to nano-scale segregation in a deep eutectic solvent - water mixture Busato, Matteo; Di Lisio, Valerio; Del Giudice, Alessandra Journal of Molecular Liquids, Vol. 331 https://doi.org/10.1016/j.molliq.2021.115747	journal	June 2021
Bulk liquid phase and interfacial behavior of cineole – Based deep eutectic solvents with regard to carbon dioxide Rozas, Sara; Atilhan, Mert; Aparicio, Santiago Journal of Molecular Liquids, Vol. 353 https://doi.org/10.1016/j.molliq.2022.118748	journal	May 2022
Application of ionic liquids in analytical chemistry Liu, Jing-fu; Jiang, Gui-bin; Liu, Jing-fu TrAC Trends in Analytical Chemistry, Vol. 24, Issue 1 https://doi.org/10.1016/j.trac.2004.09.005	journal	January 2005
Single-Molecule Resolution and Fluorescence Imaging of Mixed-Mode Sorption of a Dye at the Interface of C ₁₈ and Acetonitrile/Water Ludes, Melody D.; Wirth, Mary J. Analytical Chemistry, Vol. 74, Issue 2 https://doi.org/10.1021/ac010943u	journal	January 2002
Deep Eutectic Solvents: A Review of Fundamentals and Applications Hansen, Benworth B.; Spittle, Stephanie; Chen, Brian Chemical Reviews, Vol. 121, Issue 3 https://doi.org/10.1021/acs.chemrev.0c00385	journal	December 2020
Microstructural and Dynamical Heterogeneities in Ionic Liquids Wang, Yong-Lei; Li, Bin; Sarman, Sten Chemical Reviews, Vol. 120, Issue 13 https://doi.org/10.1021/acs.chemrev.9b00693	journal	April 2020
Theoretical Study of Oil Desulfuration by Ammonium-Based Deep Eutectic Solvents Gutiérrez, Alberto; Atilhan, Mert; Aparicio, Santiago Energy & Fuels, Vol. 32, Issue 7 https://doi.org/10.1021/acs.energyfuels.8b01403	journal	June 2018
Restructuring a Deep Eutectic Solvent by Water: The Nanostructure of Hydrated Choline Chloride/Urea Sapir, Liel; Harries, Daniel Journal of Chemical Theory and Computation, Vol. 16, Issue 5 https://doi.org/10.1021/acs.jctc.0c00120	journal	March 2020
Natural Deep Eutectic Solvents: Properties, Applications, and Perspectives Liu, Yang; Friesen, J. Brent; McAlpine, James B. Journal of Natural Products, Vol. 81, Issue 3 https://doi.org/10.1021/acs.jnatprod.7b00945	journal	November 2017
Subpicosecond Solvation Response and Partial Viscosity Decoupling of Solute Diffusion in Ionic Acetamide Deep Eutectic Solvents: Fluorescence Up-Conversion and Fluorescence Correlation Spectroscopic Measurements Subba, Navin; Tarif, Ejaj; Sen, Pratik The Journal of Physical Chemistry B, Vol. 124, Issue 10 https://doi.org/10.1021/acs.jpcb.0c00061	journal	February 2020
Liquid Structure and Transport Properties of the Deep Eutectic Solvent Ethaline Zhang, Yong; Poe, Derrick; Heroux, Luke The Journal of Physical Chemistry B, Vol. 124, Issue 25 https://doi.org/10.1021/acs.jpcb.0c04058	journal	May 2020
Partial Viscosity Decoupling of Solute Solvation, Rotation, and Translation Dynamics in Lauric Acid/Menthol Deep Eutectic Solvent: Modulation of Dynamic Heterogeneity with Length Scale Subba, Navin; Das, Nilimesh; Sen, Pratik The Journal of Physical Chemistry B, Vol. 124, Issue 31 https://doi.org/10.1021/acs.jpcb.0c04379	journal	July 2020
Microstructure of Deep Eutectic Solvents: Current Understanding and Challenges Kaur, Supreet; Kumari, Monika; Kashyap, Hemant K. The Journal of Physical Chemistry B, Vol. 124, Issue 47 https://doi.org/10.1021/acs.jpcb.0c07934	journal	November 2020
Significant Improvement in CO₂ Absorption by Deep Eutectic Solvents as Immobilized Sorbents: Computational Analysis Heydari Dokoohaki, Maryam; Zolghadr, Amin Reza The Journal of Physical Chemistry B, Vol. 125, Issue 35 https://doi.org/10.1021/acs.jpcb.1c03367	journal	July 2021
Interfacial Properties of Hydrophobic Deep Eutectic Solvents with Water Salehi, Hirad S.; Moultos, Othonas A.; Vlugt, Thijs J. H. The Journal of Physical Chemistry B, Vol. 125, Issue 44 https://doi.org/10.1021/acs.jpcb.1c07796	journal	October 2021
Resilience of Malic Acid Natural Deep Eutectic Solvent Nanostructure to Solidification and Hydration Hammond, Oliver S.; Bowron, Daniel T.; Jackson, Andrew J. The Journal of Physical Chemistry B, Vol. 121, Issue 31 https://doi.org/10.1021/acs.jpcb.7b05454	journal	July 2017
Glycerol Hydrogen-Bonding Network Dominates Structure and Collective Dynamics in a Deep Eutectic Solvent Faraone, A.; Wagle, D. V.; Baker, G. A. The Journal of Physical Chemistry B, Vol. 122, Issue 3 https://doi.org/10.1021/acs.jpcb.7b11224	journal	January 2018
Molecularly Heterogeneous Structure of a Nonionic Deep Eutectic Solvent Composed of N-Methylacetamide and Lauric Acid Cui, Yaowen; Rushing, Jeramie C.; Seifert, Soenke The Journal of Physical Chemistry B, Vol. 123, Issue 18 https://doi.org/10.1021/acs.jpcb.8b11732	journal	April 2019
Molecular-Level Insights into the Microstructure of a Hydrated and Nanoconfined Deep Eutectic Solvent Panda, Somenath; Kundu, Kaushik; Kiefer, Johannes The Journal of Physical Chemistry B, Vol. 123, Issue 15 https://doi.org/10.1021/acs.jpcb.9b01603	journal	March 2019
Liquid Structure and Dynamics of Tetraalkylammonium Bromide-Based Deep Eutectic Solvents: Effect of Cation Chain Length Hossain, Sk Saddam; Paul, Sneha; Samanta, Anunay The Journal of Physical Chemistry B, Vol. 123, Issue 31 https://doi.org/10.1021/acs.jpcb.9b04955	journal	July 2019
Anatomy of Microscopic Structure of Ethaline Deep Eutectic Solvent Decoded through Molecular Dynamics Simulations Kaur, Supreet; Malik, Akshay; Kashyap, Hemant K. The Journal of Physical Chemistry B, Vol. 123, Issue 39 https://doi.org/10.1021/acs.jpcb.9b06624	journal	August 2019
Temperature-Dependent Ultrafast Solvation Response and Solute Diffusion in Acetamide–Urea Deep Eutectic Solvent Subba, Navin; Polok, Kamil; Piatkowski, Piotr The Journal of Physical Chemistry B, Vol. 123, Issue 43 https://doi.org/10.1021/acs.jpcb.9b07794	journal	October 2019
Deep Eutectic Solvent Reline at 2D Nanomaterial Interfaces Rozas, Sara; Atilhan, Mert; Aparicio, Santiago The Journal of Physical Chemistry B, Vol. 124, Issue 7 https://doi.org/10.1021/acs.jpcb.9b08873	journal	January 2020
How Hydration Affects the Microscopic Structural Morphology in a Deep Eutectic Solvent Kaur, Supreet; Gupta, Aditya; Kashyap, Hemant K. The Journal of Physical Chemistry B, Vol. 124, Issue 11 https://doi.org/10.1021/acs.jpcb.9b11753	journal	February 2020
Interfacial Properties of Deep Eutectic Solvents Regarding to CO ₂ Capture García, Gregorio; Atilhan, Mert; Aparicio, Santiago The Journal of Physical Chemistry C, Vol. 119, Issue 37 https://doi.org/10.1021/acs.jpcc.5b04585	journal	September 2015
Nanostructure of Deep Eutectic Solvents at Graphite Electrode Interfaces as a Function of Potential Chen, Zhengfei; McLean, Ben; Ludwig, Michael The Journal of Physical Chemistry C, Vol. 120, Issue 4 https://doi.org/10.1021/acs.jpcc.5b10624	journal	January 2016
Relationships between Molecular Structure, Interfacial Structure, and Dynamics of Ionic Liquids near Neutral and Charged Surfaces Gil, Phwey S.; Jorgenson, Sara J.; Riet, Adriaan R. The Journal of Physical Chemistry C, Vol. 122, Issue 48 https://doi.org/10.1021/acs.jpcc.8b08644	journal	November 2018
Water-Induced Restructuring of the Surface of a Deep Eutectic Solvent Gera, Rahul; Moll, Carolyn J.; Bhattacherjee, Aditi The Journal of Physical Chemistry Letters, Vol. 13, Issue 2 https://doi.org/10.1021/acs.jpclett.1c03907	journal	January 2022
How Viscous Is the Solidlike Structure at the Interface of Ionic Liquids? A Study Using Total Internal Reflection Fluorescence Spectroscopy with a Fluorescent Molecular Probe Sensitive to High Viscosity Nishi, Naoya; Yamazawa, Takashi; Sakka, Tetsuo Langmuir, Vol. 36, Issue 35 https://doi.org/10.1021/acs.langmuir.0c01528	journal	August 2020
The Influence of Anion Structure on the Ionic Liquids/Au (100) Interface by Molecular Dynamics Simulations Wang, Yue; Tian, Guocai Langmuir, Vol. 37, Issue 48 https://doi.org/10.1021/acs.langmuir.1c02129	journal	November 2021
Investigation of Multilayered Structures of Ionic Liquids on Graphite and Platinum Using Atomic Force Microscopy and Molecular Simulations Chen, Zhichao; Li, Zixuan; Zhao, Wei Langmuir, Vol. 38, Issue 13 https://doi.org/10.1021/acs.langmuir.2c00024	journal	March 2022
Elucidating the Properties of Graphene–Deep Eutectic Solvents Interface Atilhan, Mert; Costa, Luciano T.; Aparicio, Santiago Langmuir, Vol. 33, Issue 21 https://doi.org/10.1021/acs.langmuir.7b00767	journal	May 2017
Effect of Concentration on the Interfacial and Bulk Structure of Ionic Liquids in Aqueous Solution Cheng, H. -W.; Weiss, H.; Stock, P. Langmuir, Vol. 34, Issue 8 https://doi.org/10.1021/acs.langmuir.7b03757	journal	February 2018
On the Performance of Confined Deep Eutectic Solvents and Ionic Liquids for Separations of Carbon Dioxide from Methane: Molecular Dynamics Simulations Shen, Yan; Abedin, Rubaiyet; Hung, Francisco R. Langmuir, Vol. 35, Issue 10 https://doi.org/10.1021/acs.langmuir.8b03990	journal	February 2019
Influence of Hydration on the Structure of Reline Deep Eutectic Solvent: A Molecular Dynamics Study Kumari, Pratibha; Shobhna, Kapoor; Kaur, Supreet ACS Omega, Vol. 3, Issue 11, p. 15246-15255 https://doi.org/10.1021/acsomega.8b02447	journal	November 2018
Elucidating the Role of Hydrogen Bond Donor and Acceptor on Solvation in Deep Eutectic Solvents Formed by Ammonium/Phosphonium Salts and Carboxylic Acids Farooq, Muhammad Qamar; Odugbesi, Gabriel A.; Abbasi, Nabeel Mujtaba ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 49 https://doi.org/10.1021/acssuschemeng.0c06926	journal	November 2020
Investigating the Variation in Solvation Interactions of Choline Chloride-Based Deep Eutectic Solvents Formed Using Different Hydrogen Bond Donors Abbasi, Nabeel Mujtaba; Farooq, Muhammad Qamar; Anderson, Jared L. ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 35 https://doi.org/10.1021/acssuschemeng.1c04375	journal	August 2021
Structure and Properties of “Type IV” Lanthanide Nitrate Hydrate:Urea Deep Eutectic Solvents Hammond, Oliver S.; Bowron, Daniel T.; Edler, Karen J. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 5 https://doi.org/10.1021/acssuschemeng.8b05548	journal	January 2019
Looking at the “Water-in-Deep-Eutectic-Solvent” System: A Dilution Range for High Performance Eutectics López-Salas, Nieves; Vicent-Luna, José Manuel; Imberti, Silvia ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 21 https://doi.org/10.1021/acssuschemeng.9b05096	journal	October 2019
Deep Eutectic Solvents (DESs) and Their Applications Smith, Emma L.; Abbott, Andrew P.; Ryder, Karl S. Chemical Reviews, Vol. 114, Issue 21 https://doi.org/10.1021/cr300162p	journal	October 2014
Structure and Nanostructure in Ionic Liquids Hayes, Robert; Warr, Gregory G.; Atkin, Rob Chemical Reviews, Vol. 115, Issue 13 https://doi.org/10.1021/cr500411q	journal	June 2015
Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids: Versatile Alternatives to Ionic Liquids Abbott, Andrew P.; Boothby, David; Capper, Glen Journal of the American Chemical Society, Vol. 126, Issue 29 https://doi.org/10.1021/ja048266j	journal	July 2004
Molecular Dynamic Simulations of Ionic Liquids at Graphite Surface Wang, Shu; Li, Shu; Cao, Zhen The Journal of Physical Chemistry C, Vol. 114, Issue 2 https://doi.org/10.1021/jp902225n	journal	December 2009
Interfacial Structure of Room-Temperature Ionic Liquids at the Solid–Liquid Interface as Probed by Sum Frequency Generation Spectroscopy Baldelli, Steven The Journal of Physical Chemistry Letters, Vol. 4, Issue 2 https://doi.org/10.1021/jz301835j	journal	December 2012
Atomic Force Microscopy in Viscous Ionic Liquids Labuda, Aleksander; Grütter, Peter Langmuir, Vol. 28, Issue 12 https://doi.org/10.1021/la300557u	journal	March 2012
Evolution of microscopic heterogeneity and dynamics in choline chloride-based deep eutectic solvents Spittle, Stephanie; Poe, Derrick; Doherty, Brian Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-021-27842-z	journal	January 2022
Applications of ionic liquids in the chemical industry Plechkova, Natalia V.; Seddon, Kenneth R. Chem. Soc. Rev., Vol. 37, Issue 1 https://doi.org/10.1039/B006677J	journal	January 2008
Energy applications of ionic liquids MacFarlane, Douglas R.; Tachikawa, Naoki; Forsyth, Maria Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42099J	journal	January 2014
Molecular and ionic diffusion in aqueous – deep eutectic solvent mixtures: probing inter-molecular interactions using PFG NMR D’Agostino, Carmine; Gladden, Lynn F.; Mantle, Mick D. Physical Chemistry Chemical Physics, Vol. 17, Issue 23 https://doi.org/10.1039/C5CP01493J	journal	January 2015
A detailed study of cholinium chloride and levulinic acid deep eutectic solvent system for CO ₂ capture via experimental and molecular simulation approaches Ullah, Ruh; Atilhan, Mert; Anaya, Baraa Physical Chemistry Chemical Physics, Vol. 17, Issue 32 https://doi.org/10.1039/C5CP03364K	journal	January 2015
Liquid structure of the choline chloride-urea deep eutectic solvent (reline) from neutron diffraction and atomistic modelling Hammond, Oliver S.; Bowron, Daniel T.; Edler, Karen J. Green Chemistry, Vol. 18, Issue 9 https://doi.org/10.1039/C5GC02914G	journal	January 2016
Impact of water on the melting temperature of urea + choline chloride deep eutectic solvent Meng, Xiangqian; Ballerat-Busserolles, Karine; Husson, Pascale New Journal of Chemistry, Vol. 40, Issue 5 https://doi.org/10.1039/C5NJ02677F	journal	January 2016
Nanostructure, hydrogen bonding and rheology in choline chloride deep eutectic solvents as a function of the hydrogen bond donor Stefanovic, Ryan; Ludwig, Michael; Webber, Grant B. Physical Chemistry Chemical Physics, Vol. 19, Issue 4 https://doi.org/10.1039/C6CP07932F	journal	January 2017
Molecular dynamics simulations of pyrrolidinium and imidazolium ionic liquids at graphene interfaces Begić, Srđan; Jónsson, Erlendur; Chen, Fangfang Physical Chemistry Chemical Physics, Vol. 19, Issue 44 https://doi.org/10.1039/C7CP03389C	journal	January 2017
The peculiar effect of water on ionic liquids and deep eutectic solvents Ma, Chunyan; Laaksonen, Aatto; Liu, Chang Chemical Society Reviews, Vol. 47, Issue 23 https://doi.org/10.1039/C8CS00325D	journal	January 2018
Nanostructure of the deep eutectic solvent/platinum electrode interface as a function of potential and water content Hammond, Oliver S.; Li, Hua; Westermann, Christian Nanoscale Horizons, Vol. 4, Issue 1 https://doi.org/10.1039/C8NH00272J	journal	January 2019
Long-ranged heterogeneous structure in aqueous solutions of the deep eutectic solvent choline and geranate at the liquid–vapor interface Felipe, Alfredo; Lovenduski, Christopher A.; Baker, Joseph L. Physical Chemistry Chemical Physics, Vol. 24, Issue 22 https://doi.org/10.1039/D2CP01530G	journal	January 2022
Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains Abbott, Andrew P.; Capper, Glen; Davies, David L. Chemical Communications, Issue 19 https://doi.org/10.1039/b106357j	journal	January 2001
Novel solvent properties of choline chloride/urea mixturesElectronic supplementary information (ESI) available: spectroscopic data. See http://www.rsc.org/suppdata/cc/b2/b210714g/ Abbott, Andrew P.; Capper, Glen; Davies, David L. Chemical Communications, Issue 1 https://doi.org/10.1039/b210714g	journal	November 2002
Organized 3D-alkyl imidazolium ionic liquids could be used to control the size of in situ generated ruthenium nanoparticles? Gutel, Thibaut; Santini, Catherine C.; Philippot, Karine Journal of Materials Chemistry, Vol. 19, Issue 22 https://doi.org/10.1039/b821659b	journal	January 2009
Molecular motion and ion diffusion in choline chloride based deep eutectic solvents studied by 1H pulsed field gradient NMR spectroscopy D'Agostino, Carmine; Harris, Robert C.; Abbott, Andrew P. Physical Chemistry Chemical Physics, Vol. 13, Issue 48 https://doi.org/10.1039/c1cp22554e	journal	January 2011
Deep eutectic solvents: syntheses, properties and applications Zhang, Qinghua; De Oliveira Vigier, Karine; Royer, Sébastien Chemical Society Reviews, Vol. 41, Issue 21 https://doi.org/10.1039/c2cs35178a	journal	January 2012
Effect of alkyl chain length and anion species on the interfacial nanostructure of ionic liquids at the Au(111)–ionic liquid interface as a function of potential Li, Hua; Endres, Frank; Atkin, Rob Physical Chemistry Chemical Physics, Vol. 15, Issue 35 https://doi.org/10.1039/c3cp52421c	journal	January 2013
Bulk and interfacial structures of reline deep eutectic solvent: A molecular dynamics study Kaur, Supreet; Sharma, Shobha; Kashyap, Hemant K. The Journal of Chemical Physics, Vol. 147, Issue 19 https://doi.org/10.1063/1.4996644	journal	November 2017
Ionic Liquids in Tribology Minami, Ichiro Molecules, Vol. 14, Issue 6 https://doi.org/10.3390/molecules14062286	journal	June 2009

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