Carbazole-Based Hole Transport Polymer for Methylammonium-Free Tin-Lead Perovskite Solar Cells with Enhanced Efficiency and Stability

Wang, Jiantao; Yu, Zhenhua; Astridge, Daniel D.; Ni, Zhenyi; Zhao, Liang; Chen, Bo; Wang, Mengru; Zhou, Ying; Yang, Guang; Dai, Xuezeng; Sellinger, Alan; Huang, Jinsong

doi:10.1021/acsenergylett.2c01578

Carbazole-Based Hole Transport Polymer for Methylammonium-Free Tin-Lead Perovskite Solar Cells with Enhanced Efficiency and Stability

Journal Article · Mon Sep 12 00:00:00 EDT 2022 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.2c01578· OSTI ID:1898023

Wang, Jiantao; Yu, Zhenhua; Astridge, Daniel D.; Ni, Zhenyi; Zhao, Liang; Chen, Bo; Wang, Mengru; Zhou, Ying; Yang, Guang; Dai, Xuezeng; Sellinger, Alan; Huang, Jinsong

As the most commonly used hole transport material (HTM) in tin-lead (Sn-Pb) perovskite solar cells (PSCs), poly(3,4-ethylenedioxythiophene) polystyrenesulfonate (PEDOT:PSS) limits the power conversion efficiency (PCE) and stability of the PSCs due to its acidic characteristics. Herein, an easily synthesized polymer HTM poly[(phenyl)imino[9-(2-ethylhexyl)carbazole]-2,7-diyl] (CzAn) with a shallow highest occupied molecular orbital (HOMO) level of -4.95 eV is used in a p-i-n structure, methylammonium-free, Sn-Pb PSC to replace PEDOT:PSS. Upon optimization using doping and surface engineering, high quality Sn-Pb PSCs could be successfully fabricated, boosting the PCE to 22.6% (stabilized PCE of 21.3%) compared with 21.2% for PEDOT:PSS. The perovskite films prepared on the modified CzAn HTM possess improved crystallinity, reduced trap-state density, and larger carrier mobility resulting in PSCs with greatly improved stability.

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1898023

Report Number(s):: NREL/JA-5900-84532; MainId:85305; UUID:7c5a54ab-3493-4874-82ef-17f562e74747; MainAdminID:67980

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 10 Vol. 7

Country of Publication:: United States

Language:: English

References (47)

Low-bandgap mixed tin–lead iodide perovskites with reduced methylammonium for simultaneous enhancement of solar cell efficiency and stability Li, Chongwen; Song, Zhaoning; Chen, Cong Nature Energy, Vol. 5, Issue 10 https://doi.org/10.1038/s41560-020-00692-7	journal	October 2020
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
Sulfonate-Assisted Surface Iodide Management for High-Performance Perovskite Solar Cells and Modules Chen, Ruihao; Wang, Yongke; Nie, Siqing Journal of the American Chemical Society, Vol. 143, Issue 28 https://doi.org/10.1021/jacs.1c03419	journal	July 2021
Physical Passivation of Grain Boundaries and Defects in Perovskite Solar Cells by an Isolating Thin Polymer Ochoa-Martinez, Efrain; Ochoa, Mario; Ortuso, Roberto D. ACS Energy Letters, Vol. 6, Issue 7 https://doi.org/10.1021/acsenergylett.1c01187	journal	June 2021
Understanding Performance Limiting Interfacial Recombination in pin Perovskite Solar Cells Warby, Jonathan; Zu, Fengshuo; Zeiske, Stefan Advanced Energy Materials, Vol. 12, Issue 12 https://doi.org/10.1002/aenm.202103567	journal	February 2022
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Flexible all-perovskite tandem solar cells approaching 25% efficiency with molecule-bridged hole-selective contact Li, Ludong; Wang, Yurui; Wang, Xiaoyu Nature Energy, Vol. 7, Issue 8 https://doi.org/10.1038/s41560-022-01045-2	journal	June 2022
Design of low bandgap tin–lead halide perovskite solar cells to achieve thermal, atmospheric and operational stability Prasanna, Rohit; Leijtens, Tomas; Dunfield, Sean P. Nature Energy, Vol. 4, Issue 11 https://doi.org/10.1038/s41560-019-0471-6	journal	October 2019
Suppressing PEDOT:PSS Doping-Induced Interfacial Recombination Loss in Perovskite Solar Cells Chin, Yi-Chun; Daboczi, Matyas; Henderson, Charlie ACS Energy Letters, Vol. 7, Issue 2 https://doi.org/10.1021/acsenergylett.1c02577	journal	January 2022
Front-Contact Passivation of PIN MAPbI₃ Solar Cells with Superior Device Performances Wang, Jiantao; Xu, Jing; Li, Zhixin ACS Applied Energy Materials, Vol. 3, Issue 7 https://doi.org/10.1021/acsaem.0c00561	journal	June 2020
A bilayer conducting polymer structure for planar perovskite solar cells with over 1,400 hours operational stability at elevated temperatures Zhao, Yicheng; Heumueller, Thomas; Zhang, Jiyun Nature Energy, Vol. 7, Issue 2 https://doi.org/10.1038/s41560-021-00953-z	journal	December 2021
Thermally Stable All‐Perovskite Tandem Solar Cells Fully Using Metal Oxide Charge Transport Layers and Tunnel Junction Gao, Han; Lu, Qianwen; Xiao, Ke Solar RRL, Vol. 5, Issue 12 https://doi.org/10.1002/solr.202100814	journal	October 2021
Reducing Saturation-Current Density to Realize High-Efficiency Low-Bandgap Mixed Tin-Lead Halide Perovskite Solar Cells Li, Chongwen; Song, Zhaoning; Zhao, Dewei Advanced Energy Materials, Vol. 9, Issue 3 https://doi.org/10.1002/aenm.201803135	journal	November 2018
Carrier control in Sn–Pb perovskites via 2D cation engineering for all-perovskite tandem solar cells with improved efficiency and stability Tong, Jinhui; Jiang, Qi; Ferguson, Andrew J. Nature Energy, Vol. 7, Issue 7 https://doi.org/10.1038/s41560-022-01046-1	journal	June 2022
Conformal quantum dot–SnO ₂ layers as electron transporters for efficient perovskite solar cells Kim, Minjin; Jeong, Jaeki; Lu, Haizhou Science, Vol. 375, Issue 6578 https://doi.org/10.1126/science.abh1885	journal	January 2022
Strain engineering in perovskite solar cells and its impacts on carrier dynamics Zhu, Cheng; Niu, Xiuxiu; Fu, Yuhao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08507-4	journal	February 2019
Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process Wang, Qi; Shao, Yuchuan; Dong, Qingfeng Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00233D	journal	January 2014
Highly Efficient Perovskite-Perovskite Tandem Solar Cells Reaching 80% of the Theoretical Limit in Photovoltage Rajagopal, Adharsh; Yang, Zhibin; Jo, Sae Byeok Advanced Materials, Vol. 29, Issue 34 https://doi.org/10.1002/adma.201702140	journal	July 2017
Perovskite-perovskite tandem photovoltaics with optimized band gaps Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A. Science, Vol. 354, Issue 6314 https://doi.org/10.1126/science.aaf9717	journal	October 2016
Nanoscale localized contacts for high fill factors in polymer-passivated perovskite solar cells Peng, Jun; Walter, Daniel; Ren, Yuhao Science, Vol. 371, Issue 6527 https://doi.org/10.1126/science.abb8687	journal	January 2021
Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes Min, Hanul; Lee, Do Yoon; Kim, Junu Nature, Vol. 598, Issue 7881 https://doi.org/10.1038/s41586-021-03964-8	journal	October 2021
Tin–Lead Perovskite Solar Cells Fabricated on Hole Selective Monolayers Kapil, Gaurav; Bessho, Takeru; Sanehira, Yoshitaka ACS Energy Letters, Vol. 7, Issue 3 https://doi.org/10.1021/acsenergylett.1c02718	journal	February 2022
A piperidinium salt stabilizes efficient metal-halide perovskite solar cells Lin, Yen-Hung; Sakai, Nobuya; Da, Peimei Science, Vol. 369, Issue 6499 https://doi.org/10.1126/science.aba1628	journal	July 2020
Doped hole transport layer for efficiency enhancement in planar heterojunction organolead trihalide perovskite solar cells Wang, Qi; Bi, Cheng; Huang, Jinsong Nano Energy, Vol. 15 https://doi.org/10.1016/j.nanoen.2015.04.029	journal	July 2015
Iodine reduction for reproducible and high-performance perovskite solar cells and modules Chen, Shangshang; Xiao, Xun; Gu, Hangyu Science Advances, Vol. 7, Issue 10 https://doi.org/10.1126/sciadv.abe8130	journal	March 2021
Polymer Hole Transport Materials for Perovskite Solar Cells via Buchwald–Hartwig Amination Astridge, Daniel D.; Hoffman, Jacob B.; Zhang, Fei ACS Applied Polymer Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsapm.1c00891	journal	November 2021
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange Yang, W. S.; Noh, J. H.; Jeon, N. J. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa9272	journal	May 2015
Systematic investigation of the impact of operation conditions on the degradation behaviour of perovskite solar cells Domanski, Konrad; Alharbi, Essa A.; Hagfeldt, Anders Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0060-5	journal	January 2018
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Characterizations and Understanding of Additives Induced Passivation Effects in Narrow-Bandgap Sn–Pb Alloyed Perovskite Solar Cells Yang, Yang Michael; Chen, Xinya; Liu, Shaocong The Journal of Physical Chemistry C, Vol. 125, Issue 23 https://doi.org/10.1021/acs.jpcc.1c03213	journal	June 2021
High-performance methylammonium-free ideal-band-gap perovskite solar cells Tong, Jinhui; Gong, Jue; Hu, Mingyu Matter, Vol. 4, Issue 4 https://doi.org/10.1016/j.matt.2021.01.003	journal	April 2021
Unveiling Roles of Tin Fluoride Additives in High‐Efficiency Low‐Bandgap Mixed Tin‐Lead Perovskite Solar Cells Chen, Qiyu; Luo, Jincheng; He, Rui Advanced Energy Materials, Vol. 11, Issue 29 https://doi.org/10.1002/aenm.202101045	journal	June 2021
A Universal Double-Side Passivation for High Open-Circuit Voltage in Perovskite Solar Cells: Role of Carbonyl Groups in Poly(methyl methacrylate) Peng, Jun; Khan, Jafar I.; Liu, Wenzhu Advanced Energy Materials, Vol. 8, Issue 30 https://doi.org/10.1002/aenm.201801208	journal	September 2018
Simplified interconnection structure based on C60/SnO2-x for all-perovskite tandem solar cells Yu, Zhenhua; Yang, Zhibin; Ni, Zhenyi Nature Energy, Vol. 5, Issue 9 https://doi.org/10.1038/s41560-020-0657-y	journal	July 2020
Thermally Stable Perovskite Solar Cells by Systematic Molecular Design of the Hole-Transport Layer Schloemer, Tracy H.; Gehan, Timothy S.; Christians, Jeffrey A. ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.8b02431	journal	January 2019
Stabilizing perovskite-substrate interfaces for high-performance perovskite modules Chen, Shangshang; Dai, Xuezeng; Xu, Shuang Science, Vol. 373, Issue 6557 https://doi.org/10.1126/science.abi6323	journal	August 2021
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Improving Low-Bandgap Tin–Lead Perovskite Solar Cells via Contact Engineering and Gas Quench Processing Werner, Jérémie; Moot, Taylor; Gossett, Tyler A. ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00255	journal	March 2020
Gradient Doping in Sn–Pb Perovskites by Barium Ions for Efficient Single‐Junction and Tandem Solar Cells Yu, Zhenhua; Chen, Xihan; Harvey, Steven P. Advanced Materials, Vol. 34, Issue 16 https://doi.org/10.1002/adma.202110351	journal	March 2022
Fluoride Chemistry in Tin Halide Perovskites Pascual, Jorge; Flatken, Marion; Félix, Roberto Angewandte Chemie International Edition, Vol. 60, Issue 39 https://doi.org/10.1002/anie.202107599	journal	July 2021
Centimetre-scale perovskite solar cells with fill factors of more than 86 per cent Peng, Jun; Kremer, Felipe; Walter, Daniel Nature, Vol. 601, Issue 7894 https://doi.org/10.1038/s41586-021-04216-5	journal	January 2022
All-perovskite tandem solar cells with improved grain surface passivation Lin, Renxing; Xu, Jian; Wei, Mingyang Nature, Vol. 603, Issue 7899 https://doi.org/10.1038/s41586-021-04372-8	journal	January 2022
NiO _x ‐Seeded Self‐Assembled Monolayers as Highly Hole‐Selective Passivating Contacts for Efficient Inverted Perovskite Solar Cells Sun, Juanjuan; Shou, Chunhui; Sun, Jingsong Solar RRL, Vol. 5, Issue 11 https://doi.org/10.1002/solr.202100663	journal	October 2021
Low-temperature processed inorganic hole transport layer for efficient and stable mixed Pb-Sn low-bandgap perovskite solar cells Han, Qiaolei; Wei, Ying; Lin, Renxing Science Bulletin, Vol. 64, Issue 19 https://doi.org/10.1016/j.scib.2019.08.002	journal	October 2019
High‐Performance Tin–Lead Mixed‐Perovskite Solar Cells with Vertical Compositional Gradient Cao, Jiupeng; Loi, Hok‐Leung; Xu, Yang Advanced Materials, Vol. 34, Issue 6 https://doi.org/10.1002/adma.202107729	journal	December 2021
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6784	journal	December 2014
Tailored Phase Conversion under Conjugated Polymer Enables Thermally Stable Perovskite Solar Cells with Efficiency Exceeding 21% Meng, Lei; Sun, Chenkai; Wang, Rui Journal of the American Chemical Society, Vol. 140, Issue 49 https://doi.org/10.1021/jacs.8b10520	journal	November 2018

Similar Records

Carbazole-Based Hole Transport Polymer for Methylammonium-Free Tin–Lead Perovskite Solar Cells with Enhanced Efficiency and Stability

Journal Article · Mon Sep 12 00:00:00 EDT 2022 · ACS Energy Letters · OSTI ID:1891007

Related Subjects

MATERIALS SCIENCE
SOLAR ENERGY
carrier mobility
crystallinity
hole transport material
perovskite solar cells
power conversion efficiency
stability
trap-state density

Carbazole-Based Hole Transport Polymer for Methylammonium-Free Tin-Lead Perovskite Solar Cells with Enhanced Efficiency and Stability

Citation Formats

References (47)

Similar Records

Related Subjects