Methane oligomerization in the gas phase by third-row transition-metal ions. (Reannouncement with new availability information). Technical report
Technical Report
·
OSTI ID:189787
Methane is spontaneously dehydrogenated in the gas phase by many metal ions of the 5d transition series. In most cases, the product MCH2+ undergoes further reactions, leading eventually to products such as WC8H16+, which must contain at least six carbon-carbon bonds. Reactivity patterns of the third-row transition metals are rationalized in terms of their electronic structure, including the interesting unreactive ions La+, Hf+, and Re+.
- Research Organization:
- California Inst. of Tech., Pasadena, CA (United States). Div. of Chemistry and Chemical Engineering
- OSTI ID:
- 189787
- Report Number(s):
- AD-A--258894/5/XAB; CONTRIB--8351; CNN: Contract N00014-89-J-3198, Grant NSF-CHE87-11567
- Country of Publication:
- United States
- Language:
- English
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