Lignin as a bioactive polymer and heavy metal absorber- an overview

Sadeghifar, Hasan; Ragauskas, Arthur

doi:10.1016/j.chemosphere.2022.136564

Lignin as a bioactive polymer and heavy metal absorber- an overview

Journal Article · Thu Sep 22 00:00:00 EDT 2022 · Chemosphere

DOI:https://doi.org/10.1016/j.chemosphere.2022.136564· OSTI ID:1896978

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Hollingsworth & Vose, Groton, MA (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

As a pulping and bio-refinery by-product with phenolic chemical structure, lignin indicated high potential as natural antioxidant activity, UV blocker, antibacterial and toxic material absorbent properties. Presence of phenolic hydroxyl groups in lignin structure plays the main role of its antioxidant activity. However, lignin antioxidant power can change depending on its other structural features and functional groups like ortho-methoxy groups, –OCH₃ groups, the α-CH₂ groups, the aliphatic carbonyl groups, and the size of π-conjugated systems. Lignin in mixture with synthetic polymers, improved their thermal stability. Lignin has high UV light absorbing potential in broad-spectrum (UVA, UVB). Adding 1–5% of lignin into hand cream indicated excellent range of sun protection factor (SPF) with more than 95% UV light absorption. Lignin also indicated strong UV light protection when applied in different transparent film and protect paint, oil, and varnish from UV degradation. Further, lignosulfonate and other modified lignin including chemically modification, nano-particles and lignin hydrogel indicated high potential as heavy metal absorber.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1896978

Journal Information:: Chemosphere, Journal Name: Chemosphere Journal Issue: 1 Vol. 309; ISSN 0045-6535

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Antiviral and Immunostimulating Effects of Lignin-Carbohydrate-Protein Complexes from Pimpinella anisum Lee, Jung-Bum; Yamagishi, Chihiro; Hayashi, Kyoko Bioscience, Biotechnology, and Biochemistry, Vol. 75, Issue 3 https://doi.org/10.1271/bbb.100645	journal	March 2011
Towards better UV-blocking and antioxidant performance of varnish via additives based on lignin and its colloids Tan, Shanyuan; Liu, Di; Qian, Yong Holzforschung, Vol. 73, Issue 5 https://doi.org/10.1515/hf-2018-0134	journal	May 2019
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Analytical Methods Used in Determining Antioxidant Activity: A Review Munteanu, Irina Georgiana; Apetrei, Constantin International Journal of Molecular Sciences, Vol. 22, Issue 7 https://doi.org/10.3390/ijms22073380	journal	March 2021
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Antioxidant Activity of the Lignins Derived from Fluidized-Bed Fast Pyrolysis Qazi, Sohail; Li, Dongbing; Briens, Cedric Molecules, Vol. 22, Issue 3 https://doi.org/10.3390/molecules22030372	journal	March 2017
Lignocellulosic Biomass as Source for Lignin-Based Environmentally Benign Antioxidants Alzagameem, Abla; Khaldi-Hansen, Basma; Büchner, Dominik Molecules, Vol. 23, Issue 10 https://doi.org/10.3390/molecules23102664	journal	October 2018
Antioxidant PLA Composites Containing Lignin for 3D Printing Applications: A Potential Material for Healthcare Applications Domínguez-Robles, Juan; Martin, Niamh; Fong, Mun Pharmaceutics, Vol. 11, Issue 4 https://doi.org/10.3390/pharmaceutics11040165	journal	April 2019
Polypropylene Blend with Polyphenols through Dynamic Vulcanization: Mechanical, Rheological, Crystalline, Thermal, and UV Protective Property Liao, Jingjing; Brosse, Nicolas; Pizzi, Antonio Polymers, Vol. 11, Issue 7 https://doi.org/10.3390/polym11071108	journal	July 2019
The Effect of Degradation of Soda Lignin Using Pd/SO42−/ZrO2 as a Catalyst: Improved Reactivity and Antioxidant Activity Zhang, Shengming; Fang, Guizhen; Chen, Haitao Polymers, Vol. 11, Issue 7 https://doi.org/10.3390/polym11071218	journal	July 2019
Preparation and Application of Light-Colored Lignin Nanoparticles for Broad-Spectrum Sunscreens Lee, Sang Cheon; Yoo, Eunjin; Lee, Sang Hyun Polymers, Vol. 12, Issue 3 https://doi.org/10.3390/polym12030699	journal	March 2020

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