Solution-processable copper(I) iodide-based inorganic-organic hybrid semiconductors composed of both coordinate and ionic bonds

Hei, Xiuze; Zhu, Kun; Carignan, Gia; Teat, Simon J.; Li, Mingxing; Zhang, Guoyu; Bonite, Megan; Li, Jing

doi:10.1016/j.jssc.2022.123427

Solution-processable copper(I) iodide-based inorganic-organic hybrid semiconductors composed of both coordinate and ionic bonds

Journal Article · Fri Jul 22 00:00:00 EDT 2022 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2022.123427· OSTI ID:1896873

Hei, Xiuze ^[1]; Zhu, Kun ^[1]; Carignan, Gia ^[1]; Teat, Simon J. ^[2]; Li, Mingxing ^[3]; Zhang, Guoyu ^[1]; Bonite, Megan ^[1]; Li, Jing ^[1]

Rutgers Univ., Piscataway, NJ (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Three new one-dimensional (1D) All-In-One (AIO) type CuI-based hybrid semiconductors with both dative and ionic bonds between the inorganic and organic components have been successfully designed and synthesized by using the ligands containing both cationic center and coordination available sites. Structural analysis confirms that all compounds share the same formula of Cu₄I₆(L)₂ (L = ligand) and are composed of 1D-Cu₄I₆^2- anionic chains that coordinate to cationic ligands. Additionally, these materials demonstrate high stability towards heat and moisture and excellent solution processability due to their unique bonding nature. They emit low energy light ranging from green to orange color (530-590 nm). The origin and mechanism of their emissions were studied by both experimental and theoretical methods. More importantly, all compounds can be easily fabricated into films by solution process, a desired but rare feature for most of CuI-based hybrids built of extended networks.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; SC0012704; SC0019902

OSTI ID:: 1896873

Alternate ID(s):: OSTI ID: 1879580
OSTI ID: 1963462

Report Number(s):: BNL-223658-2022-JAAM

Journal Information:: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Vol. 314; ISSN 0022-4596

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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