Not all types of secondary organic aerosol mix: two phases observed when mixing different secondary organic aerosol types

Mahrt, Fabian; Peng, Long; Zaks, Julia; Huang, Yuanzhou; Ohno, Paul E.; Smith, Natalie R.; Gregson, Florence K. A.; Qin, Yiming; Faiola, Celia L.; Martin, Scot T.; Nizkorodov, Sergey A.; Ammann, Markus; Bertram, Allan K.

doi:10.5194/acp-22-13783-2022

Title: Not all types of secondary organic aerosol mix: two phases observed when mixing different secondary organic aerosol types

Journal Article · Tue Nov 01 00:00:00 EDT 2022 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-22-13783-2022· OSTI ID:1896540

; Peng, Long; Zaks, Julia; Huang, Yuanzhou; Ohno, Paul E.;

; Gregson, Florence K. A.; Qin, Yiming; Faiola, Celia L.; Martin, Scot T.;

;

Abstract. Secondary organic aerosol (SOA) constitutes a large fraction of atmospheric aerosol. To assess its impacts on climate and air pollution, knowledge of the number of phases in internal mixtures of different SOA types is required. Atmospheric models often assume that different SOA types form a single phase when mixed. Here, we present visual observations of the number of phases formed after mixing different anthropogenic and biogenic SOA types. Mixing SOA types generated in environmental chambers with oxygen-to-carbon (O/C) ratios between 0.34 and 1.05, we found 6 out of 15 mixtures of two SOA types to result in two phase particles. We demonstrate that the number of phases depends on the difference in the average O/C ratio between the two SOA types (Δ(O/C)). Using a threshold Δ(O/C) of 0.47, we can predict the phase behavior of over 90 % of our mixtures, with one- and two-phase particles predicted for Δ(O/C)<0.47 and Δ(O/C)≥0.47, respectively. This threshold ΔO/C value provides a simple parameter to predict whether mixtures of fresh and aged SOA form one- or two-phase particles in the atmosphere. In addition, we show that phase-separated SOA particles form when mixtures of volatile organic compounds emitted from real trees are oxidized.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: ECS-2003368; AGS-1853639

OSTI ID:: 1896540

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Vol. 22 Journal Issue: 20; ISSN 1680-7324

Publisher:: Copernicus GmbHCopyright Statement

Country of Publication:: Germany

Language:: English

References (78)

Characterization of submicron aerosols at a rural site in Pearl River Delta of China using an Aerodyne High-Resolution Aerosol Mass Spectrometer Huang, X. -F.; He, L. -Y.; Hu, M. Atmospheric Chemistry and Physics, Vol. 11, Issue 5 https://doi.org/10.5194/acp-11-1865-2011	journal	January 2011
Aerosol Optical Tweezers Constrain the Morphology Evolution of Liquid-Liquid Phase-Separated Atmospheric Particles Gorkowski, Kyle; Donahue, Neil M.; Sullivan, Ryan C. Chem, Vol. 6, Issue 1 https://doi.org/10.1016/j.chempr.2019.10.018	journal	January 2020
Liquid-liquid phase separation in aerosol particles: Dependence on O:C, organic functionalities, and compositional complexity: PHASE SEPARATION Song, M.; Marcolli, C.; Krieger, U. K. Geophysical Research Letters, Vol. 39, Issue 19 https://doi.org/10.1029/2012GL052807	journal	October 2012
Known and Unexplored Organic Constituents in the Earth's Atmosphere Goldstein, Allen H.; Galbally, Ian E. Environmental Science & Technology, Vol. 41, Issue 5 https://doi.org/10.1021/es072476p	journal	March 2007
Liquid–liquid phase separation and morphologies in organic particles consisting of <i>α</i>-pinene and <i>β</i>-caryophyllene ozonolysis products and mixtures with commercially available organic compounds Song, Young-Chul; Bé, Ariana G.; Martin, Scot T. Atmospheric Chemistry and Physics, Vol. 20, Issue 19 https://doi.org/10.5194/acp-20-11263-2020	journal	October 2020
Relative humidity-dependent viscosity of secondary organic material from toluene photo-oxidation and possible implications for organic particulate matter over megacities Song, Mijung; Liu, Pengfei F.; Hanna, Sarah J. Atmospheric Chemistry and Physics, Vol. 16, Issue 14 https://doi.org/10.5194/acp-16-8817-2016	journal	January 2016
Gas/Particle Partitioning and Secondary Organic Aerosol Yields Odum, Jay R.; Hoffmann, Thorsten; Bowman, Frank Environmental Science & Technology, Vol. 30, Issue 8 https://doi.org/10.1021/es950943+	journal	July 1996
The viscosity of atmospherically relevant organic particles Reid, Jonathan P.; Bertram, Allan K.; Topping, David O. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03027-z	journal	March 2018
Liquid–liquid phase separation in particles containing organics mixed with ammonium sulfate, ammonium bisulfate, ammonium nitrate or sodium chloride You, Y.; Renbaum-Wolff, L.; Bertram, A. K. Atmospheric Chemistry and Physics, Vol. 13, Issue 23 https://doi.org/10.5194/acp-13-11723-2013	journal	January 2013
Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies Ervens, B.; Turpin, B. J.; Weber, R. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-11069-2011	journal	January 2011
Elemental Analysis of Organic Species with Electron Ionization High-Resolution Mass Spectrometry Aiken, Allison C.; DeCarlo, Peter F.; Jimenez, Jose L. Analytical Chemistry, Vol. 79, Issue 21 https://doi.org/10.1021/ac071150w	journal	November 2007
Development of an Aerosol Mass Spectrometer for Size and Composition Analysis of Submicron Particles Jayne, John T.; Leard, Danna C.; Zhang, Xuefeng Aerosol Science and Technology, Vol. 33, Issue 1-2 https://doi.org/10.1080/027868200410840	journal	July 2000
Nile Red Dye in Aqueous Surfactant and Micellar Solution Kurniasih, Indah Nurita; Liang, Hua; Mohr, Parveen Choudhary Langmuir, Vol. 31, Issue 9 https://doi.org/10.1021/la504378m	journal	February 2015
Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA Smith, Natalie R.; Crescenzo, Giuseppe V.; Huang, Yuanzhou Environmental Science: Atmospheres, Vol. 1, Issue 3 https://doi.org/10.1039/D0EA00020E	journal	January 2021
Characterization of the sources and processes of organic and inorganic aerosols in New York city with a high-resolution time-of-flight aerosol mass apectrometer Sun, Y. -L.; Zhang, Q.; Schwab, J. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 4 https://doi.org/10.5194/acp-11-1581-2011	journal	January 2011
Mixing of the Organic Aerosol Fractions: Liquids as the Thermodynamically Stable Phases Marcolli, Claudia; Luo, Beiping; Peter, Thomas The Journal of Physical Chemistry A, Vol. 108, Issue 12 https://doi.org/10.1021/jp036080l	journal	March 2004
Laboratory studies of the chemical composition and cloud condensation nuclei (CCN) activity of secondary organic aerosol (SOA) and oxidized primary organic aerosol (OPOA) Lambe, A. T.; Onasch, T. B.; Massoli, P. Atmospheric Chemistry and Physics, Vol. 11, Issue 17 https://doi.org/10.5194/acp-11-8913-2011	journal	January 2011
Nile red: a selective fluorescent stain for intracellular lipid droplets Greenspan, P. The Journal of Cell Biology, Vol. 100, Issue 3 https://doi.org/10.1083/jcb.100.3.965	journal	March 1985
Phase Behavior of Internal Mixtures of Hydrocarbon-like Primary Organic Aerosol and Secondary Aerosol Based on Their Differences in Oxygen-to-Carbon Ratios Mahrt, Fabian; Huang, Yuanzhou; Zaks, Julia Environmental Science & Technology, Vol. 56, Issue 7 https://doi.org/10.1021/acs.est.1c07691	journal	March 2022
Investigation of the sources and processing of organic aerosol over the Central Mexican Plateau from aircraft measurements during MILAGRO DeCarlo, P. F.; Ulbrich, I. M.; Crounse, J. Atmospheric Chemistry and Physics, Vol. 10, Issue 12 https://doi.org/10.5194/acp-10-5257-2010	journal	January 2010
Size dependent partitioning of organic material: evidence for the formation of organic coatings on aqueous aerosols Anttila, T.; Kiendler-Scharr, A.; Mentel, Th. F. Journal of Atmospheric Chemistry, Vol. 57, Issue 3 https://doi.org/10.1007/s10874-007-9067-9	journal	May 2007
Emulsified and Liquid–Liquid Phase-Separated States of α-Pinene Secondary Organic Aerosol Determined Using Aerosol Optical Tweezers Gorkowski, Kyle; Donahue, Neil M.; Sullivan, Ryan C. Environmental Science & Technology, Vol. 51, Issue 21 https://doi.org/10.1021/acs.est.7b03250	journal	October 2017
Predicting Secondary Organic Aerosol Enhancement in the Presence of Atmospherically Relevant Organic Particles Ye, Jianhuai; Van Rooy, Paul; Adam, Cullen H. ACS Earth and Space Chemistry, Vol. 2, Issue 10 https://doi.org/10.1021/acsearthspacechem.8b00093	journal	August 2018
Evaluation of secondary organic aerosol formation in winter Strader, R. Atmospheric Environment, Vol. 33, Issue 29 https://doi.org/10.1016/S1352-2310(99)00310-6	journal	December 1999
Mixing of secondary organic aerosols versus relative humidity Ye, Qing; Robinson, Ellis Shipley; Ding, Xiang Proceedings of the National Academy of Sciences, Vol. 113, Issue 45 https://doi.org/10.1073/pnas.1604536113	journal	October 2016
Particle mass yield from β -caryophyllene ozonolysis Chen, Q.; Li, Y. L.; McKinney, K. A. Atmospheric Chemistry and Physics, Vol. 12, Issue 7 https://doi.org/10.5194/acp-12-3165-2012	journal	January 2012
Organic Aerosol Mixing Observed by Single-Particle Mass Spectrometry Robinson, Ellis Shipley; Saleh, Rawad; Donahue, Neil M. The Journal of Physical Chemistry A, Vol. 117, Issue 51 https://doi.org/10.1021/jp405789t	journal	November 2013
Size-Dependent Liquid–Liquid Phase Separation in Atmospherically Relevant Complex Systems Kucinski, Theresa M.; Dawson, Joseph Nelson; Freedman, Miriam Arak The Journal of Physical Chemistry Letters, Vol. 10, Issue 21 https://doi.org/10.1021/acs.jpclett.9b02532	journal	October 2019
Phase Behavior of Hydrocarbon-like Primary Organic Aerosol and Secondary Organic Aerosol Proxies Based on Their Elemental Oxygen-to-Carbon Ratio Mahrt, Fabian; Newman, Elli; Huang, Yuanzhou Environmental Science & Technology, Vol. 55, Issue 18 https://doi.org/10.1021/acs.est.1c02697	journal	September 2021
Surface tension prevails over solute effect in organic-influenced cloud droplet activation Ovadnevaite, Jurgita; Zuend, Andreas; Laaksonen, Ari Nature, Vol. 546, Issue 7660 https://doi.org/10.1038/nature22806	journal	June 2017
Model Representation of Secondary Organic Aerosol in CMAQv4.7 Carlton, Annmarie G.; Bhave, Prakash V.; Napelenok, Sergey L. Environmental Science & Technology, Vol. 44, Issue 22 https://doi.org/10.1021/es100636q	journal	November 2010
Internal mixing of the organic aerosol by gas phase diffusion of semivolatile organic compounds Marcolli, C.; Luo, B. P.; Peter, Th. Atmospheric Chemistry and Physics, Vol. 4, Issue 11/12 https://doi.org/10.5194/acp-4-2593-2004	journal	January 2004
Submicron aerosol analysis and organic source apportionment in an urban atmosphere in Pearl River Delta of China using high-resolution aerosol mass spectrometry He, Ling-Yan; Huang, Xiao-Feng; Xue, Lian Journal of Geophysical Research, Vol. 116, Issue D12 https://doi.org/10.1029/2010JD014566	journal	January 2011
Fluorescence Aerosol Flow Tube Spectroscopy to Detect Liquid–Liquid Phase Separation Ohno, Paul E.; Qin, Yiming; Ye, Jianhuai ACS Earth and Space Chemistry, Vol. 5, Issue 5 https://doi.org/10.1021/acsearthspacechem.1c00061	journal	May 2021
Influence of an organic coating on the reactivity of aqueous aerosols probed by the heterogeneous hydrolysis of N ₂ O ₅ : ORGANIC COATINGS AND AEROSOL REACTIVITY Folkers, M.; Mentel, Th. F.; Wahner, A. Geophysical Research Letters, Vol. 30, Issue 12 https://doi.org/10.1029/2003GL017168	journal	June 2003
Images reveal that atmospheric particles can undergo liquid-liquid phase separations You, Y.; Renbaum-Wolff, L.; Carreras-Sospedra, M. Proceedings of the National Academy of Sciences, Vol. 109, Issue 33 https://doi.org/10.1073/pnas.1206414109	journal	July 2012
Yields of β-Hydroxynitrates and Dihydroxynitrates in Aerosol Formed from OH Radical-Initiated Reactions of Linear Alkenes in the Presence of NO _x Matsunaga, Aiko; Ziemann, Paul J. The Journal of Physical Chemistry A, Vol. 113, Issue 3 https://doi.org/10.1021/jp807764d	journal	December 2008
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges Nozière, Barbara; Kalberer, Markus; Claeys, Magda Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr5003485	journal	February 2015
O/C and OM/OC Ratios of Primary, Secondary, and Ambient Organic Aerosols with High-Resolution Time-of-Flight Aerosol Mass Spectrometry Aiken, Allison C.; DeCarlo, Peter F.; Kroll, Jesse H. Environmental Science & Technology, Vol. 42, Issue 12 https://doi.org/10.1021/es703009q	journal	June 2008
An absorption model of gas/particle partitioning of organic compounds in the atmosphere Pankow, James F. Atmospheric Environment, Vol. 28, Issue 2 https://doi.org/10.1016/1352-2310(94)90093-0	journal	January 1994
Relative-humidity-dependent organic aerosol thermodynamics via an efficient reduced-complexity model Gorkowski, Kyle; Preston, Thomas C.; Zuend, Andreas Atmospheric Chemistry and Physics, Vol. 19, Issue 21 https://doi.org/10.5194/acp-19-13383-2019	journal	January 2019
Multiphase Chemistry at the Atmosphere–Biosphere Interface Influencing Climate and Public Health in the Anthropocene Pöschl, Ulrich; Shiraiwa, Manabu Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr500487s	journal	February 2015
Global distribution and climate forcing of carbonaceous aerosols Chung, Serena H. Journal of Geophysical Research, Vol. 107, Issue D19 https://doi.org/10.1029/2001JD001397	journal	January 2002
The 2005 Study of Organic Aerosols at Riverside (SOAR-1): instrumental intercomparisons and fine particle composition Docherty, K. S.; Aiken, A. C.; Huffman, J. A. Atmospheric Chemistry and Physics, Vol. 11, Issue 23 https://doi.org/10.5194/acp-11-12387-2011	journal	January 2011
Organic aerosol and global climate modelling: a review Kanakidou, M.; Seinfeld, J. H.; Pandis, S. N. Atmospheric Chemistry and Physics, Vol. 5, Issue 4 https://doi.org/10.5194/acp-5-1053-2005	journal	January 2005
Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors Song, Mijung; Maclean, Adrian M.; Huang, Yuanzhou Atmospheric Chemistry and Physics, Vol. 19, Issue 19 https://doi.org/10.5194/acp-19-12515-2019	journal	January 2019
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Following Particle-Particle Mixing in Atmospheric Secondary Organic Aerosols by Using Isotopically Labeled Terpenes Ye, Qing; Upshur, Mary Alice; Robinson, Ellis S. Chem, Vol. 4, Issue 2 https://doi.org/10.1016/j.chempr.2017.12.008	journal	February 2018
Secondary organic aerosols from anthropogenic volatile organic compounds contribute substantially to air pollution mortality Nault, Benjamin A.; Jo, Duseong S.; McDonald, Brian C. Atmospheric Chemistry and Physics, Vol. 21, Issue 14 https://doi.org/10.5194/acp-21-11201-2021	journal	July 2021
Hygroscopic growth of ammonium sulfate/dicarboxylic acids Wise, Matthew E. Journal of Geophysical Research, Vol. 108, Issue D20 https://doi.org/10.1029/2003JD003775	journal	January 2003
A biogenic secondary organic aerosol source of cirrus ice nucleating particles Wolf, Martin J.; Zhang, Yue; Zawadowicz, Maria A. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18424-6	journal	October 2020
Particle-Phase Chemistry of Secondary Organic Material: Modeled Compared to Measured O:C and H:C Elemental Ratios Provide Constraints Chen, Qi; Liu, Yingjun; Donahue, Neil M. Environmental Science & Technology, Vol. 45, Issue 11 https://doi.org/10.1021/es104398s	journal	June 2011
Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer DeCarlo, Peter F.; Kimmel, Joel R.; Trimborn, Achim Analytical Chemistry, Vol. 78, Issue 24 https://doi.org/10.1021/ac061249n	journal	December 2006
Aggregation of Nile Red in Water: Prevention through Encapsulation in β-Cyclodextrin Ray, Anusree; Das, Sinjan; Chattopadhyay, Nitin ACS Omega, Vol. 4, Issue 1 https://doi.org/10.1021/acsomega.8b02503	journal	January 2019
Effect of Hydrophilic Organic Seed Aerosols on Secondary Organic Aerosol Formation from Ozonolysis of α-Pinene Song, Chen; Zaveri, Rahul A.; Shilling, John E. Environmental Science & Technology, Vol. 45, Issue 17 https://doi.org/10.1021/es201225c	journal	September 2011
Nile Red fluorescence spectroscopy reports early physicochemical changes in myelin with high sensitivity Teo, Wulin; Caprariello, Andrew V.; Morgan, Megan L. Proceedings of the National Academy of Sciences, Vol. 118, Issue 8 https://doi.org/10.1073/pnas.2016897118	journal	February 2021
Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol Shrivastava, Manish; Cappa, Christopher D.; Fan, Jiwen Reviews of Geophysics, Vol. 55, Issue 2 https://doi.org/10.1002/2016RG000540	journal	June 2017
Combined Determination of the Chemical Composition and of Health Effects of Secondary Organic Aerosols: The POLYSOA Project Baltensperger, Urs; Dommen, Josef; Alfarra, M. Rami Journal of Aerosol Medicine and Pulmonary Drug Delivery, Vol. 21, Issue 1 https://doi.org/10.1089/jamp.2007.0655	journal	March 2008
Effect of oxidant concentration, exposure time, and seed particles on secondary organic aerosol chemical composition and yield Lambe, A. T.; Chhabra, P. S.; Onasch, T. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 6 https://doi.org/10.5194/acp-15-3063-2015	journal	January 2015
Formation and aging of secondary organic aerosol from toluene: changes in chemical composition, volatility, and hygroscopicity Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K. M. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-8301-2015	journal	January 2015
Deliquescence, efflorescence, and supercooling of ammonium sulfate aerosols at low temperature: Implications for cirrus cloud formation and aerosol phase in the atmosphere Cziczo, D. J.; Abbatt, J. P. D. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D11 https://doi.org/10.1029/1999JD900112	journal	June 1999
Loading-dependent elemental composition of α-pinene SOA particles Shilling, J. E.; Chen, Q.; King, S. M. Atmospheric Chemistry and Physics, Vol. 9, Issue 3 https://doi.org/10.5194/acp-9-771-2009	journal	January 2009
Computation of liquid-liquid equilibria and phase stabilities: implications for RH-dependent gas/particle partitioning of organic-inorganic aerosols Zuend, A.; Marcolli, C.; Peter, T. Atmospheric Chemistry and Physics, Vol. 10, Issue 16 https://doi.org/10.5194/acp-10-7795-2010	journal	January 2010
Evidence for High Molecular Weight Nitrogen-Containing Organic Salts in Urban Aerosols Wang, Xiaofei; Gao, Song; Yang, Xin Environmental Science & Technology, Vol. 44, Issue 12 https://doi.org/10.1021/es1001117	journal	June 2010
Quantitative sampling using an Aerodyne aerosol mass spectrometer 1. Techniques of data interpretation and error analysis: QUANTITATIVE AEROSOL MASS SPECTROMETER ANALYSIS, 1 Allan, James D.; Jimenez, Jose L.; Williams, Paul I. Journal of Geophysical Research: Atmospheres, Vol. 108, Issue D3 https://doi.org/10.1029/2002JD002358	journal	February 2003
Mathematical model for gas-particle partitioning of secondary organic aerosols Bowman, Frank M.; Odum, Jay R.; Seinfeld, John H. Atmospheric Environment, Vol. 31, Issue 23 https://doi.org/10.1016/S1352-2310(97)00245-8	journal	December 1997
Identification and quantification of organic aerosol from cooking and other sources in Barcelona using aerosol mass spectrometer data Mohr, C.; DeCarlo, P. F.; Heringa, M. F. Atmospheric Chemistry and Physics, Vol. 12, Issue 4 https://doi.org/10.5194/acp-12-1649-2012	journal	January 2012
Characterization of submicron aerosols in the urban outflow of the central Pearl River Delta region of China Gong, Zhaoheng; Lan, Zijuan; Xue, Lian Frontiers of Environmental Science & Engineering, Vol. 6, Issue 5 https://doi.org/10.1007/s11783-012-0441-8	journal	September 2012
Coexistence of three liquid phases in individual atmospheric aerosol particles Huang, Yuanzhou; Mahrt, Fabian; Xu, Shaun Proceedings of the National Academy of Sciences, Vol. 118, Issue 16 https://doi.org/10.1073/pnas.2102512118	journal	April 2021
Aerosol Mixing State: Measurements, Modeling, and Impacts Riemer, N.; Ault, A. P.; West, M. Reviews of Geophysics, Vol. 57, Issue 2 https://doi.org/10.1029/2018RG000615	journal	May 2019
Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H. Atmospheric Chemistry and Physics, Vol. 15, Issue 1 https://doi.org/10.5194/acp-15-253-2015	journal	January 2015
Enhancement in Secondary Organic Aerosol Formation in the Presence of Preexisting Organic Particle Ye, Jianhuai; Gordon, Catherine A.; Chan, Arthur W. H. Environmental Science & Technology, Vol. 50, Issue 7 https://doi.org/10.1021/acs.est.5b05512	journal	March 2016
Secondary organic aerosol yields from cloud-processing of isoprene oxidation products Ervens, Barbara; Carlton, Annmarie G.; Turpin, Barbara J. Geophysical Research Letters, Vol. 35, Issue 2 https://doi.org/10.1029/2007GL031828	journal	January 2008
Secondary Organic Aerosol Formation Enhanced by Organic Seeds of Similar Polarity at Atmospherically Relative Humidity Gordon, Catherine A.; Ye, Jianhuai; Chan, Arthur W. H. STEM Fellowship Journal, Vol. 1, Issue 2 https://doi.org/10.17975/sfj-2015-009	journal	December 2015
Highly time-resolved chemical characterization of atmospheric fine particles during 2010 Shanghai World Expo Huang, X. -F.; He, L. -Y.; Xue, L. Atmospheric Chemistry and Physics, Vol. 12, Issue 11 https://doi.org/10.5194/acp-12-4897-2012	journal	January 2012
Molecular formula composition of β-caryophyllene ozonolysis SOA formed in humid and dry conditions Kundu, Shuvashish; Fisseha, Rebeka; Putman, Annie L. Atmospheric Environment, Vol. 154 https://doi.org/10.1016/j.atmosenv.2016.12.031	journal	April 2017
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics Donahue, N. M.; Robinson, A. L.; Stanier, C. O. Environmental Science & Technology, Vol. 40, Issue 8 https://doi.org/10.1021/es052297c	journal	April 2006

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