Customized metallodielectric colloids and their behavior in dielectrophoretic fields

Dong, Fangyuan; Munkaila, Samira; Grebe, Veronica; Weck, Marcus; Ward, Michael D.

doi:10.1039/d2sm01099b

Customized metallodielectric colloids and their behavior in dielectrophoretic fields

Journal Article · Tue Oct 11 00:00:00 EDT 2022 · Soft Matter

DOI:https://doi.org/10.1039/d2sm01099b· OSTI ID:1894024

Dong, Fangyuan ^[1]; ^[2]; ^[2]; ^[2]; ^[2]

New York Univ. (NYU), NY (United States); NYU
New York Univ. (NYU), NY (United States)

A synthetic strategy for fabricating colloidal particles with spatially segregated amine-functionalized lobes enables regioselective coating with gold to afford metallodielectric particles with a variety of shapes and lobe sizes. This approach can produce either dissymmetric dumbbell-shaped two-lobed Au-TPM particles (Au-T) or dissymmetric or symmetric three-lobed particles with gold coating on one (Au-T-T and T-Au-T) or two lobes (Au-T-Au). Dielectrophoretic (DEP) forces exerted by an AC field confined between two opposing electrodes generate aggregates ranging from 1D chains to 2D close-packed lattices, depending on the particle shape and lobe arrangement. Furthermore, the aggregate structures reflect the lowest energy configurations resulting from the induced dipole moments created in particle lobes within the confined electric field.

View Accepted Manuscript (DOE)

Research Organization:: New York Univ. (NYU), NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE

Grant/Contract Number:: SC0007991

OSTI ID:: 1894024

Alternate ID(s):: OSTI ID: 1891691

Journal Information:: Soft Matter, Journal Name: Soft Matter Journal Issue: 41 Vol. 18; ISSN 1744-683X

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Customized metallodielectric colloids and their behavior in dielectrophoretic fields

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