Methods for producing and using perovskite materials and devices therefrom

Zhu, Kai; Luther, Joseph M.; Zhao, Yixin

Title: Methods for producing and using perovskite materials and devices therefrom

Patent · Tue Mar 01 00:00:00 EST 2022

OSTI ID:1892669

Zhu, Kai; Luther, Joseph M.; Zhao, Yixin

The present disclosure describes solution methods for manufacturing perovskite halide films for use in solar cells. The methods include the use of additives that facilitate the formation of transitory, intermediate films that are later transformed into the final target perovskite halide films, such that the final films provide improved physical characteristics and operational performance.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC36-08GO28308

Assignee:: Alliance for Sustainable Energy, LLC (Golden, CO)

Patent Number(s):: 11,264,179

Application Number:: 16/704,207

OSTI ID:: 1892669

Resource Relation:: Patent File Date: 12/05/2019

Country of Publication:: United States

Language:: English

References (108)

Liquid Exfoliation of Layered Materials Nicolosi, V.; Chhowalla, M.; Kanatzidis, M. G. Science, Vol. 340, Issue 6139, p. 1226419 https://doi.org/10.1126/science.1226419	journal	June 2013
Enhanced Crystallinity in Organic–Inorganic Lead Halide Perovskites on Mesoporous TiO₂ via Disorder–Order Phase Transition Park, Byung-wook; Philippe, Bertrand; Gustafsson, Torbjörn Chemistry of Materials, Vol. 26, Issue 15, p. 4466-4471 https://doi.org/10.1021/cm501541p	journal	July 2014
Solid-State Mesostructured Perovskite CH ₃ NH ₃ PbI ₃ Solar Cells: Charge Transport, Recombination, and Diffusion Length Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai The Journal of Physical Chemistry Letters, Vol. 5, Issue 3 https://doi.org/10.1021/jz500003v	journal	January 2014
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Mesoscopic CH₃NH₃PbI₃/TiO₂ Heterojunction Solar Cells Etgar, Lioz; Gao, Peng; Xue, Zhaosheng Journal of the American Chemical Society, Vol. 134, Issue 42, p. 17396-17399 https://doi.org/10.1021/ja307789s	journal	October 2012
Charge Transport and Recombination in Perovskite (CH ₃ NH ₃ )PbI ₃ Sensitized TiO ₂ Solar Cells Zhao, Yixin; Zhu, Kai The Journal of Physical Chemistry Letters, Vol. 4, Issue 17 https://doi.org/10.1021/jz401527q	journal	August 2013
An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide Christians, Jeffrey A.; Fung, Raymond C. M.; Kamat, Prashant V. Journal of the American Chemical Society, Vol. 136, Issue 2, p. 758-764 https://doi.org/10.1021/ja411014k	journal	December 2013
High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization Saidaminov, Makhsud I.; Abdelhady, Ahmed L.; Murali, Banavoth Nature Communications, Vol. 6, Article No. 7586 https://doi.org/10.1038/ncomms8586	journal	July 2015
Tandem photovoltaic cell Pschirer, Neil Gregory; Eickemeyer, Felix; Schoeneboom, Jan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8563855 US Patent Document 8,563,855	patent	October 2013
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
Solution Deposition-Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells Docampo, Pablo; Hanusch, Fabian C.; Stranks, Samuel D. Advanced Energy Materials, Vol. 4, Issue 14, Article No. 1400355 https://doi.org/10.1002/aenm.201400355	journal	May 2014
Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen Advanced Materials, Vol. 26, Issue 22, p. 3748-3754 https://doi.org/10.1002/adma.201400231	journal	March 2014
A highly efficient mesoscopic solar cell based on CH ₃ NH ₃ PbI _3−x Cl _x fabricated via sequential solution deposition Ma, Yingzhuang; Zheng, Lingling; Chung, Yao-Hsien Chem. Commun., Vol. 50, Issue 83 https://doi.org/10.1039/C4CC01962H	journal	January 2014
Dynamic Response of Dye-Sensitized Nanocrystalline Solar Cells: Characterization by Intensity-Modulated Photocurrent Spectroscopy Dloczik, L.; Ileperuma, O.; Lauermann, I. The Journal of Physical Chemistry B, Vol. 101, Issue 49, p. 10281-10289 https://doi.org/10.1021/jp972466i	journal	December 1997
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
Voltage-Enhancement Mechanisms of an Organic Dye in High Open-Circuit Voltage Solid-State Dye-Sensitized Solar Cells Jang, Song-Rim; Zhu, Kai; Ko, Min Jae ACS Nano, Vol. 5, Issue 10 https://doi.org/10.1021/nn2029567	journal	September 2011
Perovskites by Design: A Toolbox of Solid-State Reactions Schaak, Raymond E.; Mallouk, Thomas E. Chemistry of Materials, Vol. 14, Issue 4, p. 1455-1471 https://doi.org/10.1021/cm010689m	journal	April 2002
Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong Nature Photonics, Vol. 7, Issue 6, p. 486-491 https://doi.org/10.1038/nphoton.2013.80	journal	May 2013
Controllable Sequential Deposition of Planar CH ₃ NH ₃ PbI ₃ Perovskite Films via Adjustable Volume Expansion Zhang, Taiyang; Yang, Mengjin; Zhao, Yixin Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/acs.nanolett.5b00843	journal	May 2015
All-solid-state dye-sensitized solar cells with high efficiency Chung, In; Lee, Byunghong; He, Jiaqing Nature, Vol. 485, Issue 7399, p. 486-489 https://doi.org/10.1038/nature11067	journal	May 2012
Films and crystalline powder of PbI2 intercalated with ammonia and pyridine Preda, N.; Mihut, L.; Baibarac, M. Journal of Materials Science: Materials in Electronics, Vol. 20, Issue S1 https://doi.org/10.1007/s10854-008-9681-6	journal	March 2008
Process for forming epitaxial perovskite thin film layers using halide precursors Clem, Paul G.; Rodriguez, Mark A.; Voigt, James A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6231666 US Patent Document 6,231,666	patent	May 2001
Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell Park, Nam-Gyu The Journal of Physical Chemistry Letters, Vol. 4, Issue 15, p. 2423-2429 https://doi.org/10.1021/jz400892a	journal	July 2013
Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process Chen, Qi; Zhou, Huanping; Hong, Ziruo Journal of the American Chemical Society, Vol. 136, Issue 2, p. 622-625 https://doi.org/10.1021/ja411509g	journal	December 2013
n-Type Transition Metal Oxide as a Hole Extraction Layer in PbS Quantum Dot Solar Cells Gao, Jianbo; Perkins, Craig L.; Luther, Joseph M. Nano Letters, Vol. 11, Issue 8, p. 3263-3266 https://doi.org/10.1021/nl2015729	journal	August 2011
Unusual defect physics in CH ₃ NH ₃ PbI ₃ perovskite solar cell absorber Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa Applied Physics Letters, Vol. 104, Issue 6 https://doi.org/10.1063/1.4864778	journal	February 2014
High performance hybrid solar cells sensitized by organolead halide perovskites Cai, Bing; Xing, Yedi; Yang, Zhou Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee40343b	journal	January 2013
Structure of Methylammonium Lead Iodide Within Mesoporous Titanium Dioxide: Active Material in High-Performance Perovskite Solar Cells Choi, Joshua J.; Yang, Xiaohao; Norman, Zachariah M. Nano Letters, Vol. 14, Issue 1, p. 127-133 https://doi.org/10.1021/nl403514x	journal	December 2013
Effective hole extraction using MoO _x -Al contact in perovskite CH ₃ NH ₃ PbI ₃ solar cells Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai Applied Physics Letters, Vol. 104, Issue 21 https://doi.org/10.1063/1.4880899	journal	May 2014
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Trap-limited recombination in dye-sensitized nanocrystalline metal oxide electrodes Nelson, Jenny; Haque, Saif A.; Klug, David R. Physical Review B, Vol. 63, Issue 20 https://doi.org/10.1103/PhysRevB.63.205321	journal	May 2001
Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques Liu, Dianyi; Kelly, Timothy L. Nature Photonics, Vol. 8, Issue 2, p. 133-138 https://doi.org/10.1038/nphoton.2013.342	journal	December 2013
Retarding the crystallization of PbI ₂ for highly reproducible planar-structured perovskite solar cells via sequential deposition Wu, Yongzhen; Islam, Ashraful; Yang, Xudong Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01624F	journal	January 2014
Thermally Induced Structural Evolution and Performance of Mesoporous Block Copolymer-Directed Alumina Perovskite Solar Cells Tan, Kwan Wee; Moore, David T.; Saliba, Michael ACS Nano, Vol. 8, Issue 5 https://doi.org/10.1021/nn500526t	journal	April 2014
High Open-Circuit Voltage Solar Cells Based on Organic–Inorganic Lead Bromide Perovskite Edri, Eran; Kirmayer, Saar; Cahen, David The Journal of Physical Chemistry Letters, Vol. 4, Issue 6, p. 897-902 https://doi.org/10.1021/jz400348q	journal	March 2013
Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher Energy & Environmental Science, Vol. 7, Issue 3 https://doi.org/10.1039/c3ee43822h	journal	January 2014
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Methods for producing single crystal mixed halide perovskites Zhu, Kai; Zhao, Yixin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9701696 US Patent Document 9,701,696	patent	July 2017
High performance organic light emitting diodes using substoichiometric tungsten oxide as efficient hole injection layer Vasilopoulou, Maria; Papadimitropoulos, George; Palilis, Leonidas C. Organic Electronics, Vol. 13, Issue 5 https://doi.org/10.1016/j.orgel.2012.01.008	journal	May 2012
High Efficiency Solid-State Sensitized Solar Cell-Based on Submicrometer Rutile TiO₂ Nanorod and CH₃NH₃PbI₃ Perovskite Sensitizer Kim, Hui-Seon; Lee, Jin-Wook; Yantara, Natalia Nano Letters, Vol. 13, Issue 6, p. 2412-2417 https://doi.org/10.1021/nl400286w	journal	May 2013
Photoexcitation and photoluminescence study of coordination complexes of lead diiodide with pyridine Yu-Hallada, L. C.; Francis, Anthony H. The Journal of Physical Chemistry, Vol. 94, Issue 19 https://doi.org/10.1021/j100382a039	journal	September 1990
Hybrid Organic Solar Cell With Perovskite Structure As Absorption Material And Manufacturing Method Thereof Guo, Tzung-Fang; Jeng, Jyun-Yuan; Chiang, Yi-Fang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140332078 US Patent Application 13/947070; 20140332078	patent-application	November 2014
Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells Dualeh, Amalie; Moehl, Thomas; Tétreault, Nicolas ACS Nano, Vol. 8, Issue 1, p. 362-373 https://doi.org/10.1021/nn404323g	journal	December 2013
Superconductivity in a layered perovskite without copper Maeno, Y.; Hashimoto, H.; Yoshida, K. Nature, Vol. 372, Issue 6506 https://doi.org/10.1038/372532a0	journal	December 1994
Light Absorbing Oxide Materials for Photovoltaic and Photocatalytic Applications and Devices Martin, Lane W.; Lee, Sungki; Apgar, Brent A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140060643 US Patent Application 14/018350; 20140060643	patent-application	March 2014
Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting Pellet, Norman; Gao, Peng; Gregori, Giuliano Angewandte Chemie International Edition, Vol. 53, Issue 12, p. 3151-3157 https://doi.org/10.1002/anie.201309361	journal	February 2014
Low-Temperature Processed Electron Collection Layers of Graphene/TiO₂ Nanocomposites in Thin Film Perovskite Solar Cells Wang, Jacob Tse-Wei; Ball, James M.; Barea, Eva M. Nano Letters, Vol. 14, Issue 2, p. 724-730 https://doi.org/10.1021/nl403997a	journal	December 2013
High voltage and efficient bilayer heterojunction solar cells based on an organic–inorganic hybrid perovskite absorber with a low-cost flexible substrate Chiang, Yi-Fang; Jeng, Jun-Yuan; Lee, Mu-Huan Phys. Chem. Chem. Phys., Vol. 16, Issue 13 https://doi.org/10.1039/C4CP00298A	journal	January 2014
Interpretation of the Time Constants Measured by Kinetic Techniques in Nanostructured Semiconductor Electrodes and Dye-Sensitized Solar Cells Bisquert, Juan; Vikhrenko, Vyacheslav S. The Journal of Physical Chemistry B, Vol. 108, Issue 7, p. 2313-2322 https://doi.org/10.1021/jp035395y	journal	February 2004
Electron Transport in the Nanostructured TiO ₂ −Electrolyte System Studied with Time-Resolved Photocurrents Solbrand, Anita; Lindström, Henrik; Rensmo, Håkan The Journal of Physical Chemistry B, Vol. 101, Issue 14 https://doi.org/10.1021/jp962819y	journal	April 1997
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck Nano Letters, Vol. 13, Issue 4, p. 1764-1769 https://doi.org/10.1021/nl400349b	journal	March 2013
Organic Semiconductor Device Oku, Yoshiaki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100301311 US Patent Application 12/681028; 20100301311	patent-application	December 2010
Optoelectronic Device Snaith, Henry James; Crossland, Edward James William; Hey, Andrew https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150249170 US Patent Application 14/427930; 20150249170	patent-application	September 2015
Size and shape control of nanocrystallites in mesoporous TiO₂ films Neale, Nathan R.; Frank, Arthur J. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3216-3221 https://doi.org/10.1039/b700885f	journal	January 2007
Hybrid Lead Halide Iodide and Lead Halide Bromide in Efficient Hole Conductor Free Perovskite Solar Cell Aharon, Sigalit; Cohen, Bat El; Etgar, Lioz The Journal of Physical Chemistry C, Vol. 118, Issue 30 https://doi.org/10.1021/jp5023407	journal	May 2014
Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells Juarez-Perez, Emilio J.; Wuβler, Michael; Fabregat-Santiago, Francisco The Journal of Physical Chemistry Letters, Vol. 5, Issue 4, p. 680-685 https://doi.org/10.1021/jz500059v	journal	January 2014
Efficient Planar Perovskite Solar Cells Based on 1.8 eV Band Gap CH ₃ NH ₃ PbI ₂ Br Nanosheets via Thermal Decomposition Zhao, Yixin; Zhu, Kai Journal of the American Chemical Society, Vol. 136, Issue 35 https://doi.org/10.1021/ja5071398	journal	August 2014
Hole-conductor-free perovskite organic lead iodide heterojunction thin-film solar cells: High efficiency and junction property Shi, Jiangjian; Dong, Juan; Lv, Songtao Applied Physics Letters, Vol. 104, Issue 6 https://doi.org/10.1063/1.4864638	journal	February 2014
Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells Eperon, Giles E.; Burlakov, Victor M.; Docampo, Pablo Advanced Functional Materials, Vol. 24, Issue 1, p. 151-157 https://doi.org/10.1002/adfm.201302090	journal	September 2013
Low-temperature processed meso-superstructured to thin-film perovskite solar cells Ball, James M.; Lee, Michael M.; Hey, Andrew Energy & Environmental Science, Vol. 6, Issue 6 https://doi.org/10.1039/c3ee40810h	journal	January 2013
Optoelectronic Device Comprising Perovskites Snaith, Henry; Lee, Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150129034 US Patent Application 14/401452; 2015012903	patent-application	May 2015
Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates Docampo, Pablo; Ball, James M.; Darwich, Mariam Nature Communications, Vol. 4, Article No. 2761 https://doi.org/10.1038/ncomms3761	journal	November 2013
Two-step dipping technique for the preparation of organic-inorganic perovskite thin films Liang, Kangning; Mitzi, David B.; Prikas, Michael T. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5871579 US Patent Document 5,871,579	patent	February 1999
Mechanism of carrier accumulation in perovskite thin-absorber solar cells Kim, Hui-Seon; Mora-Sero, Ivan; Gonzalez-Pedro, Victoria Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3242	journal	July 2013
6.5% efficient perovskite quantum-dot-sensitized solar cell Im, Jeong-Hyeok; Lee, Chang-Ryul; Lee, Jin-Wook Nanoscale, Vol. 3, Issue 10, p. 4088-4093 https://doi.org/10.1039/c1nr10867k	journal	January 2011
Efficient Inorganic–Organic Hybrid Perovskite Solar Cells Based on Pyrene Arylamine Derivatives as Hole-Transporting Materials Jeon, Nam Joong; Lee, Jaemin; Noh, Jun Hong Journal of the American Chemical Society, Vol. 135, Issue 51, p. 19087-19090 https://doi.org/10.1021/ja410659k	journal	December 2013
Active Materials For Electro-Optic Devices And Electro-Optic Devices Yang, Yang; Dou, Letian; You, Jing-Bi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140020739 US Patent Application 14/009033; 20140020739	patent-application	January 2014
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells Snaith, Henry J. The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630 https://doi.org/10.1021/jz4020162	journal	October 2013
Redox Material For Thermochemical Water Splitting, And Method For Producing Hydrogen Takeshima, Shinichi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110300064 US Patent Application 12/785938; 20110300064	patent-application	December 2011
Systems and Methods for Scalable Perovskite Device Fabrication Huang, Jinsong; Dong, Qingfeng; Sao, Yuchuan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160218307 US Patent Application 15/009,718; 2016/0218307 Al	patent-application	July 2016
CH ₃ NH ₃ Cl-Assisted One-Step Solution Growth of CH ₃ NH ₃ PbI ₃ : Structure, Charge-Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells Zhao, Yixin; Zhu, Kai The Journal of Physical Chemistry C, Vol. 118, Issue 18 https://doi.org/10.1021/jp502696w	journal	April 2014
Methods for producing single crystal mixed halide perovskites Zhu, Kai; Zhao, Yixin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160251383 US Patent Application 15/055712; 20160251383	patent-application	September 2016
Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach Conings, Bert; Baeten, Linny; De Dobbelaere, Christopher Advanced Materials, Vol. 26, Issue 13, p. 2041-2046 https://doi.org/10.1002/adma.201304803	journal	December 2013
Efficient planar heterojunction perovskite solar cells by vapour deposition Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J. Nature, Vol. 501, Issue 7467, p. 395-398 https://doi.org/10.1038/nature12509	journal	September 2013
Self-powered GHZ solution-processed hybrid perovskite photodetectors Huang, Jinsong https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10199579 US Patent Document 10,199,579	patent	February 2019
Method for producing high quality, ultra-thin organic-inorganic hybrid perovskite Bag, Santanu; Durstock, Michael F. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9793056 US Patent Document 9,793,056	patent	October 2017
Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells Dualeh, Amalie; Tétreault, Nicolas; Moehl, Thomas Advanced Functional Materials, Vol. 24, Issue 21, p. 3250-3258 https://doi.org/10.1002/adfm.201304022	journal	February 2014
Development of MoOx thin films as back contact buffer for CdTe solar cells in substrate configuration Gretener, C.; Perrenoud, J.; Kranz, L. Thin Solid Films, Vol. 535 https://doi.org/10.1016/j.tsf.2012.11.110	journal	May 2013
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
A facile solvothermal growth of single crystal mixed halide perovskite CH₃NH₃Pb(Br_1−xCl_x)₃ Zhang, Taiyang; Yang, Mengjin; Benson, Eric E. Chemical Communications, Vol. 51, Issue 37, p. 7820-7823 https://doi.org/10.1039/C5CC01835H	journal	January 2015
Perovskite Solar Cells Keep On Surging Service, R. F. Science, Vol. 344, Issue 6183, Article No. 458 https://doi.org/10.1126/science.344.6183.458	journal	May 2014
Process of Forming a Photoactive Layer of a Perovskite Photoactive Device Vak, Doojin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170084399 US Patent Application 15/119835; 20170084399 A1	patent-application	March 2017
Metal Halide Perovskites, Light-Emitting Diodes, and Methods Ma, Biwu; Tian, Yu https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190256535 US Patent Application 16/279088; 20190256535	patent-application	August 2019
Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells Edri, Eran; Kirmayer, Saar; Kulbak, Michael The Journal of Physical Chemistry Letters, Vol. 5, Issue 3, p. 429-433 https://doi.org/10.1021/jz402706q	journal	January 2014
Mesoporous perovskite solar cells: material composition, charge-carrier dynamics, and device characteristics Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai Faraday Discuss., Vol. 176 https://doi.org/10.1039/C4FD00128A	journal	January 2014
Optical bleaching of perovskite (CH3NH3)PbI3 through room-temperature phase transformation induced by ammonia Zhao, Yixin; Zhu, Kai Chemical Communications, Vol. 50, Issue 13 https://doi.org/10.1039/c3cc48522f	journal	January 2014
Heterojunction Device Snaith, Henry J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120216865 US Patent Application 13/395405; 20120216865	patent-application	August 2012
Effect of Different Hole Transport Materials on Recombination in CH₃NH₃PbI₃ Perovskite-Sensitized Mesoscopic Solar Cells Bi, Dongqin; Yang, Lei; Boschloo, Gerrit The Journal of Physical Chemistry Letters, Vol. 4, Issue 9, p. 1532-1536 https://doi.org/10.1021/jz400638x	journal	April 2013
Enhanced Extraction Rates through Gap States of Molybdenum Oxide Anode Buffer Dasgupta, Binayak; Goh, Wei Peng; Ooi, Zi En The Journal of Physical Chemistry C, Vol. 117, Issue 18, p. 9206-9211 https://doi.org/10.1021/jp3114013	journal	April 2013
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Three-step sequential solution deposition of PbI ₂ -free CH ₃ NH ₃ PbI ₃ perovskite Zhao, Yixin; Zhu, Kai Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05384B	journal	January 2015
All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer and one-dimensional TiO2 nanowire arrays Qiu, Jianhang; Qiu, Yongcai; Yan, Keyou Nanoscale, Vol. 5, Issue 8 https://doi.org/10.1039/c3nr00218g	journal	January 2013
Depleted hole conductor-free lead halide iodide heterojunction solar cells Laban, Waleed Abu; Etgar, Lioz Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee42282h	journal	January 2013
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Perovskite complex oxide and method of producing the same Yano, Takuya; Suda, Hisashi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040191150 US Patent Application 10/803963; 20040191150	patent-application	September 2004
Silicon heterojunction solar cell with passivated hole selective MoO _x contact Battaglia, Corsin; de Nicolás, Silvia Martín; De Wolf, Stefaan Applied Physics Letters, Vol. 104, Issue 11 https://doi.org/10.1063/1.4868880	journal	March 2014
Performance improvement of inverted polymer solar cells with different top electrodes by introducing a MoO3 buffer layer Tao, Chen; Ruan, Shengping; Zhang, Xindong Applied Physics Letters, Vol. 93, Issue 19 https://doi.org/10.1063/1.3026741	journal	November 2008
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Layered organic-inorganic perovskites having metal-deficient inorganic frameworks Mitzi, David B. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6429318 US Patent Document 6,429,318	patent	August 2002
Thousandfold Change in Resistivity in Magnetoresistive La-Ca-Mn-O Films Jin, S.; Tiefel, T. H.; McCormack, M. Science, Vol. 264, Issue 5157 https://doi.org/10.1126/science.264.5157.413	journal	April 1994
Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency Qin, Peng; Tanaka, Soichiro; Ito, Seigo Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4834	journal	May 2014
Optoelectronic Devices With Organometal Perovskites With Mixed Anions Snaith, Henry; Lee, Michael; Murakami, Takuro https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150136232 US Patent Application 14/401423; 20150136232	patent-application	May 2015
Organolead Halide Perovskite: New Horizons in Solar Cell Research Kim, Hui-Seon; Im, Sang Hyuk; Park, Nam-Gyu The Journal of Physical Chemistry C, Vol. 118, Issue 11, p. 5615-5625 https://doi.org/10.1021/jp409025w	journal	February 2014
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Science, Vol. 286, Issue 5441, p. 945-947 https://doi.org/10.1126/science.286.5441.945	journal	October 1999
Synthesis and Characterization of Organic−Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique Liang, Kangning; Mitzi, David B.; Prikas, Michael T. Chemistry of Materials, Vol. 10, Issue 1, p. 403-411 https://doi.org/10.1021/cm970568f	journal	January 1998
Systems and methods for scalable perovskite device fabrication Huang, Jinsong; Dong, Qingfeng; Sao, Yuchuan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9583724 US Patent Document 9,583,724	patent	February 2017
MAPbI_3-xCl_x Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties Colella, Silvia; Mosconi, Edoardo; Fedeli, Paolo Chemistry of Materials, Vol. 25, Issue 22, p. 4613-4618 https://doi.org/10.1021/cm402919x	journal	November 2013
Nanocrystalline Rutile Electron Extraction Layer Enables Low-Temperature Solution Processed Perovskite Photovoltaics with 13.7% Efficiency Yella, Aswani; Heiniger, Leo-Philipp; Gao, Peng Nano Letters, Vol. 14, Issue 5, p. 2591-2596 https://doi.org/10.1021/nl500399m	journal	April 2014

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