Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg2(m-dobdc)

Chen, Elena Y.; Mandel, Ruth M.; Milner, Phillip J.

doi:10.1039/d2ce00739h

Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg₂(m-dobdc)

Journal Article · Thu Jun 30 00:00:00 EDT 2022 · CrystEngComm

DOI:https://doi.org/10.1039/d2ce00739h· OSTI ID:1891062

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Cornell Univ., Ithaca, NY (United States); Cornell University
Cornell Univ., Ithaca, NY (United States)

Metal–organic frameworks bearing coordinatively unsaturated Mg(II) sites are promising materials for gas storage, chemical separations, and drug delivery due to their low molecular weights and lack of toxicity. Furthermore, there remains a limited number of such MOFs reported in the literature. Herein, we investigate the gas sorption properties of the understudied framework Mg₂(m-dobdc) (dobdc^4– = 4,6-dioxido-1,3-benzenedicarboxylate) synthesized under both solvothermal and mechanochemical conditions. Both materials are found to be permanently porous, as confirmed by 77 K N₂ adsorption measurements. In particular, Mg₂(m-dobdc) synthesized under mechanochemical conditions using exogenous organic base displays one of the highest capacities reported to date (6.14 mmol g^–1) for CO₂ capture in a porous solid under simulated coal flue gas conditions (150 mbar, 40 °C). As such, mechanochemically synthesized Mg₂(m-dobdc) represents a promising new framework for applications requiring high gas adsorption capacities in a porous solid.

View Accepted Manuscript (DOE)

Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0021000

OSTI ID:: 1891062

Alternate ID(s):: OSTI ID: 1875012
OSTI ID: 1974510

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 41 Vol. 24; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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