Influence of oxidizing and reducing pretreatment on the catalytic performance of CeO2 for CO oxidation

Lee, Kyung-Min; Brito, Melanie; DeCoster, Jamie; Linskens, Kelvin; Mehdi, Kareem; Lee, Won-Il; Kim, Emily; Kim, Hajoon; Kwon, Gihan; Nam, Chang-Yong; Kim, Taejin

doi:10.1016/j.mcat.2022.112465

Influence of oxidizing and reducing pretreatment on the catalytic performance of CeO₂ for CO oxidation

Journal Article · Sun Jun 26 00:00:00 EDT 2022 · Molecular Catalysis (Online)

DOI:https://doi.org/10.1016/j.mcat.2022.112465· OSTI ID:1890197

Lee, Kyung-Min ^[1]; Brito, Melanie ^[1]; DeCoster, Jamie ^[1]; Linskens, Kelvin ^[1]; Mehdi, Kareem ^[1]; ^[1]; Kim, Emily ^[2]; Kim, Hajoon ^[3]; Kwon, Gihan ^[4]; Nam, Chang-Yong ^[5]; ^[1]

Stony Brook Univ., NY (United States)
Hankuk Academy of Foreign Studies, Yongin (Korea, Republic of)
Radnor Senior High School, PA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Cerium oxide (CeO₂) and ceria-based materials have been extensively investigated as catalyst and support materials for various catalytic reactions, due to higher oxygen storage capacity and excellent redox properties. In the current work, we investigated the impact of pretreatment conditions (e.g., oxidation and reduction) on the physical properties of bulk CeO₂ and catalytic activity for CO oxidation as a model reaction. To understand the physical properties of pretreated CeO₂ catalysts, a suite of complementary characterization techniques, including X-ray diffraction (XRD), surface area analysis (BET), X-ray photoemission spectroscopy (XPS), and Raman spectroscopy, were applied. The results showed that a higher pretreatment temperature led to a decreased specific surface area (SSA), a decrease in oxygen vacancy/defect sites, and increased crystallite size, while surface Ce³⁺/Ce⁴⁺ ratio did not show a specific relationship to the treatment conditions. The 700 °C treated CeO₂ samples under oxidizing and reducing conditions showed higher specific oxidation rate (μmolCO/s/m²) compared to other samples at 280 and 300 °C (or < 15% CO conversion). The CO conversion per total mass of catalysts, however, decreased with increasing temperatures, especially at 700 °C under reducing condition, indicating that the catalytic performance was affected by the physical properties (SSA, oxygen vacancy/defect sites, and crystallite size).

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Fund (NSF)

Grant/Contract Number:: SC0012704

OSTI ID:: 1890197

Report Number(s):: BNL-223505-2022-JAAM

Journal Information:: Molecular Catalysis (Online), Journal Name: Molecular Catalysis (Online) Vol. 528; ISSN 2468-8231

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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