Relaxor ferroelectric polymer exhibits ultrahigh electromechanical coupling at low electric field

Chen, Xin; Qin, Hancheng; Qian, Xiaoshi; Zhu, Wenyi; Li, Bo; Zhang, Bing; Lu, Wenchang; Li, Ruipeng; Zhang, Shihai; Zhu, Lei; Domingues Dos Santos, Fabrice; Bernholc, J.; Zhang, Q. M.

doi:10.1126/science.abn0936

Relaxor ferroelectric polymer exhibits ultrahigh electromechanical coupling at low electric field

Journal Article · Thu Mar 24 00:00:00 EDT 2022 · Science

DOI:https://doi.org/10.1126/science.abn0936· OSTI ID:1889150

^[1]; ^[2]; ^[3]; ^[1]; ^[4]; ^[2]; ^[2]; Li, Ruipeng ^[5]; Zhang, Shihai ^[4]; ^[6]; ^[7]; ^[2]; ^[1]

Pennsylvania State Univ., University Park, PA (United States)
North Carolina State Univ., Raleigh, NC (United States)
Shanghai Jiao Tong University (China)
PolyK Technologies, LLC, State College, PA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
Case Western Reserve Univ., Cleveland, OH (United States)
Arkema-Piezotech (France)

Electromechanical (EM) coupling—the conversion of energy between electric and mechanical forms—in ferroelectrics has been used for a broad range of applications. Ferroelectric polymers have weak EM coupling that severely limits their usefulness for applications. Here, we introduced a small amount of fluorinated alkyne (FA) monomers (<2 mol %) in relaxor ferroelectric poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (PVDF-TrFE-CFE) terpolymer that markedly enhances the polarization change with strong EM coupling while suppressing other polarization changes that do not contribute to it. Under a low–dc bias field of 40 megavolts per meter, the relaxor tetrapolymer has an EM coupling factor (k₃₃) of 88% and a piezoelectric coefficient (d₃₃) >1000 picometers per volt. These values make this solution-processed polymer competitive with ceramic oxide piezoelectrics, with the potential for use in distinct applications.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: SC0012704; AC05-00OR22725

OSTI ID:: 1889150

Report Number(s):: BNL-223446-2022-JAAM

Journal Information:: Science, Journal Name: Science Journal Issue: 6587 Vol. 375; ISSN 0036-8075

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

References (34)

High Electromechanical Responses in a Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) Terpolymer Xia, F.; Cheng, Z. -Y.; Xu, H. S. Advanced Materials, Vol. 14, Issue 21 https://doi.org/10.1002/1521-4095(20021104)14:21<1574::AID-ADMA1574>3.0.CO;2-#	journal	November 2002
Novel polymer ferroelectric behavior via crystal isomorphism and the nanoconfinement effect Yang, Lianyun; Li, Xinyu; Allahyarov, Elshad Polymer, Vol. 54, Issue 7 https://doi.org/10.1016/j.polymer.2013.01.035	journal	March 2013
Origins of Electrostriction in Poly(vinylidene fluoride)-Based Ferroelectric Polymers Wongwirat, Thumawadee; Zhu, Zhiwen; Rui, Guanchun Macromolecules, Vol. 53, Issue 24 https://doi.org/10.1021/acs.macromol.0c02083	journal	December 2020
Crystalline forms in a copolymer of vinylidene fluoride and trifluoroethylene (52/48 mol %) Lovinger, Andrew J.; Davis, G. T.; Furukawa, T. Macromolecules, Vol. 15, Issue 2 https://doi.org/10.1021/ma00230a024	journal	March 1982
The negative piezoelectric effect of the ferroelectric polymer poly(vinylidene fluoride) Katsouras, Ilias; Asadi, Kamal; Li, Mengyuan Nature Materials, Vol. 15, Issue 1 https://doi.org/10.1038/nmat4423	journal	October 2015
Precision and efficiency in solid-state pseudopotential calculations Prandini, Gianluca; Marrazzo, Antimo; Castelli, Ivano E. npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0127-2	journal	December 2018
Chirality-induced relaxor properties in ferroelectric polymers Liu, Yang; Zhang, Bing; Xu, Wenhan Nature Materials, Vol. 19, Issue 11 https://doi.org/10.1038/s41563-020-0724-6	journal	June 2020
Ferroelectric polymers exhibiting behaviour reminiscent of a morphotropic phase boundary Liu, Yang; Aziguli, Haibibu; Zhang, Bing Nature, Vol. 562, Issue 7725 https://doi.org/10.1038/s41586-018-0550-z	journal	October 2018
Superior electrostrictive strain achieved under low electric fields in relaxor ferroelectric polymers Zhang, Zhicheng; Wang, Xiao; Tan, Shaobo Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/C8TA11938D	journal	January 2019
A bimorph based dilatometer for field induced strain measurement in soft and thin free standing polymer films Su, J.; Moses, P.; Zhang, Q. M. Review of Scientific Instruments, Vol. 69, Issue 6 https://doi.org/10.1063/1.1148947	journal	June 1998
Influence of composition on relaxor ferroelectric and electromechanical properties of poly(vinylidene fluoride-trifluoroethylene- chlorofluoroethylene) Klein, Rob J.; Xia, Feng; Zhang, Q. M. Journal of Applied Physics, Vol. 97, Issue 9 https://doi.org/10.1063/1.1882769	journal	May 2005
Piezoelectric, dielectric, and elastic properties of poly(vinylidene fluoride/trifluoroethylene) Wang, H.; Zhang, Q. M.; Cross, L. E. Journal of Applied Physics, Vol. 74, Issue 5 https://doi.org/10.1063/1.354566	journal	September 1993
Temperature dependence of elastic, dielectric, and piezoelectric properties of “single crystalline’’ films of vinylidene fluoride trifluoroethylene copolymer Omote, Kenji; Ohigashi, Hiroji; Koga, Keiko Journal of Applied Physics, Vol. 81, Issue 6 https://doi.org/10.1063/1.364300	journal	March 1997
Electrostrictive effect in ferroelectrics: An alternative approach to improve piezoelectricity Li, Fei; Jin, Li; Xu, Zhuo Applied Physics Reviews, Vol. 1, Issue 1 https://doi.org/10.1063/1.4861260	journal	March 2014
Towards electrocaloric heat pump—A relaxor ferroelectric polymer exhibiting large electrocaloric response at low electric field Chen, Xin; Xu, Wenhan; Lu, Biao Applied Physics Letters, Vol. 113, Issue 11 https://doi.org/10.1063/1.5048599	journal	September 2018
Observation of a change in the form of polarization reversal in a vinylidene fluoride/trifluoroethylene copolymer Guy, I. L.; Unsworth, J. Applied Physics Letters, Vol. 52, Issue 7 https://doi.org/10.1063/1.99407	journal	February 1988
Relaxor ferroelectrics Cross, L. Eric Ferroelectrics, Vol. 76, Issue 1 https://doi.org/10.1080/00150198708016945	journal	December 1987
Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics Damjanovic, Dragan Reports on Progress in Physics, Vol. 61, Issue 9 https://doi.org/10.1088/0034-4885/61/9/002	journal	September 1998
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Dipole correction for surface supercell calculations Bengtsson, Lennart Physical Review B, Vol. 59, Issue 19 https://doi.org/10.1103/PhysRevB.59.12301	journal	May 1999
Van der Waals density functional: Self-consistent potential and the nature of the van der Waals bond Thonhauser, T.; Cooper, Valentino R.; Li, Shen Physical Review B, Vol. 76, Issue 12 https://doi.org/10.1103/PhysRevB.76.125112	journal	September 2007
Electric Field Induced Phase Transitions in Polymers: A Novel Mechanism for High Speed Energy Storage Ranjan, V.; Nardelli, Marco Buongiorno; Bernholc, J. Physical Review Letters, Vol. 108, Issue 8 https://doi.org/10.1103/PhysRevLett.108.087802	journal	February 2012
Electric Field Dependence of Crystallinity in Poly(Vinylidene Fluoride) Kepler, R. G.; Anderson, R. A.; Lagasse, R. R. Physical Review Letters, Vol. 48, Issue 18 https://doi.org/10.1103/PhysRevLett.48.1274	journal	May 1982
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Ferroelectric Polymers Lovinger, A. J. Science, Vol. 220, Issue 4602 https://doi.org/10.1126/science.220.4602.1115	journal	June 1983
Giant Electrostriction and Relaxor Ferroelectric Behavior in Electron-Irradiated Poly(vinylidene fluoride-trifluoroethylene) Copolymer Zhang, Q. M. Science, Vol. 280, Issue 5372 https://doi.org/10.1126/science.280.5372.2101	journal	June 1998
High-Speed Electrically Actuated Elastomers with Strain Greater Than 100% Pelrine, Ron; Kornbluh, Roy; Pei, Qibing Science, Vol. 287, Issue 5454, p. 836-839 https://doi.org/10.1126/science.287.5454.836	journal	February 2000
Highly efficient electrocaloric cooling with electrostatic actuation Ma, Rujun; Zhang, Ziyang; Tong, Kwing Science, Vol. 357, Issue 6356 https://doi.org/10.1126/science.aan5980	journal	September 2017
Insect-scale fast moving and ultrarobust soft robot Wu, Yichuan; Yim, Justin K.; Liang, Jiaming Science Robotics, Vol. 4, Issue 32 https://doi.org/10.1126/scirobotics.aax1594	journal	July 2019
Electrostriction as the Origin of Piezoelectricity in Ferroelectric Polymers Furukawa, Takeo; Seo, Naoya Japanese Journal of Applied Physics, Vol. 29, Issue Part 1, No. 4 https://doi.org/10.1143/JJAP.29.675	journal	April 1990
Electrostrictive and Piezoelectric Materials for Actuator Applications Damjanovic, D.; Newnham, R. E. Journal of Intelligent Material Systems and Structures, Vol. 3, Issue 2 https://doi.org/10.1177/1045389X9200300201	journal	April 1992
Ferroelectric Polymers Nalwa, Hari Singh https://doi.org/10.1201/9781482295450	book	January 1995
Ferroelectric Devices Uchino, Kenji CRC Press https://doi.org/10.1201/b15852	book	September 2018
Relaxor freezing and electric-field–induced ferroelectric transition in a lanthanum lead zirconate titanate ceramics Bobnar, V.; Kutnjak, Z.; Pirc, R. Europhysics Letters (EPL), Vol. 48, Issue 3 https://doi.org/10.1209/epl/i1999-00549-4	journal	November 1999

Similar Records

A high-k ferroelectric relaxor terpolymer as a gate dielectric for orgnaic thin film transistors

Journal Article · Mon Dec 31 23:00:00 EST 2012 · Applied Physics Letters · OSTI ID:1095670

Enhanced piezoelectric response in the artificial ferroelectric polymer multilayers

Journal Article · Sun Nov 30 23:00:00 EST 2014 · Applied Physics Letters · OSTI ID:22402423

Related Subjects

36 MATERIALS SCIENCE

Relaxor ferroelectric polymer exhibits ultrahigh electromechanical coupling at low electric field

Citation Formats

References (34)

Similar Records

Related Subjects