Dehydration of fatty alcohols on zirconia supported tungstate catalysts

Milaković, Lara; Liu, Yue; Baráth, Eszter; Lercher, Johannes A.

doi:10.1039/D2CY00785A

Dehydration of fatty alcohols on zirconia supported tungstate catalysts

Journal Article · Mon Oct 17 00:00:00 EDT 2022 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/D2CY00785A· OSTI ID:1886064

Milaković, Lara ^[1]; ^[1]; ^[1]; Lercher, Johannes A. ^[2]

Technische Universität München, Department of Chemistry and Catalysis Research Center, Lichtenbergstraβe 4, 85748 Garching, Germany
Technische Universität München, Department of Chemistry and Catalysis Research Center, Lichtenbergstraβe 4, 85748 Garching, Germany, Institute for Integrated Catalysis, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99352, USA

Zirconia supported tungstates catalyze octadecanol dehydration, an important step in the carbon preserving conversion of triglycerides to fuels.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1886064

Alternate ID(s):: OSTI ID: 1975253

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 20 Vol. 12; ISSN CSTAGD; ISSN 2044-4753

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (37)

Towards Quantitative Conversion of Microalgae Oil to Diesel-Range Alkanes with Bifunctional Catalysts Peng, Baoxiang; Yao, Yuan; Zhao, Chen Angewandte Chemie International Edition, Vol. 51, Issue 9 https://doi.org/10.1002/anie.201106243	journal	November 2011
Controlling Hydrodeoxygenation of Stearic Acid to n -Heptadecane and n -Octadecane by Adjusting the Chemical Properties of Ni/SiO ₂ -ZrO ₂ Catalyst Foraita, Sebastian; Liu, Yue; Haller, Gary L. ChemCatChem, Vol. 9, Issue 1 https://doi.org/10.1002/cctc.201601162	journal	November 2016
Impact of the Oxygen Defects and the Hydrogen Concentration on the Surface of Tetragonal and Monoclinic ZrO ₂ on the Reduction Rates of Stearic Acid on Ni/ZrO ₂ Foraita, Sebastian; Fulton, John L.; Chase, Zizwe A. Chemistry - A European Journal, Vol. 21, Issue 6 https://doi.org/10.1002/chem.201405312	journal	December 2014
Simplifying biodiesel production: The direct or in situ transesterification of algal biomass Haas, Michael J.; Wagner, Karen European Journal of Lipid Science and Technology, Vol. 113, Issue 10 https://doi.org/10.1002/ejlt.201100106	journal	October 2011
Influence of the Preparative Method on the Activity of Highly Acidic WOx/ZrO2and the Relative Acid Activity Compared with Zeolites Santiesteban, J. G.; Vartuli, J. C.; Han, S. Journal of Catalysis, Vol. 168, Issue 2 https://doi.org/10.1006/jcat.1997.1658	journal	June 1997
Characterization of WOx/ZrO2by Vibrational Spectroscopy andn-Pentane Isomerization Catalysis Scheithauer, M.; Cheung, T. -K.; Jentoft, R. E. Journal of Catalysis, Vol. 180, Issue 1 https://doi.org/10.1006/jcat.1998.2237	journal	November 1998
Structural and Catalytic Characterization of Solid Acids Based on Zirconia Modified by Tungsten Oxide Barton, David G.; Soled, Stuart L.; Meitzner, George D. Journal of Catalysis, Vol. 181, Issue 1 https://doi.org/10.1006/jcat.1998.2269	journal	January 1999
Genesis of Brønsted Acid Sites during Dehydration of 2-Butanol on Tungsten Oxide Catalysts Baertsch, Chelsey D.; Komala, Kenny T.; Chua, Yong-Hwee Journal of Catalysis, Vol. 205, Issue 1 https://doi.org/10.1006/jcat.2001.3426	journal	January 2002
Algal Lipids and Their Metabolism Guschina, Irina A.; Harwood, John L. Algae for Biofuels and Energy https://doi.org/10.1007/978-94-007-5479-9_2	book	November 2012
Raman and IR studies of surface metal oxide species on oxide supports: Supported metal oxide catalysts Wachs, Israel E. Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00203-0	journal	February 1996
Surface structures of supported tungsten oxide catalysts under dehydrated conditions Kim, Du Soung; Ostromecki, Marlene; Wachs, Israel E. Journal of Molecular Catalysis A: Chemical, Vol. 106, Issue 1-2 https://doi.org/10.1016/1381-1169(95)00186-7	journal	March 1996
In situ FT-IR spectroscopic investigation of gold supported on tungstated zirconia as catalyst for CO-SCR of NOx Kantcheva, M.; Milanova, M.; Mametsheripov, S. Catalysis Today, Vol. 191, Issue 1 https://doi.org/10.1016/j.cattod.2012.03.058	journal	September 2012
Activation and isomerization of hydrocarbons over WO3/ZrO2 catalystsI. Preparation, characterization, and X-ray photoelectron spectroscopy studies Digregorio, F. Journal of Catalysis, Vol. 225, Issue 1 https://doi.org/10.1016/j.jcat.2004.03.023	journal	July 2004
Support effects on Brønsted acid site densities and alcohol dehydration turnover rates on tungsten oxide domains Macht, Josef; Baertsch, Chelsey D.; May-Lozano, Marcos Journal of Catalysis, Vol. 227, Issue 2 https://doi.org/10.1016/j.jcat.2004.08.014	journal	October 2004
Molecular/electronic structure–surface acidity relationships of model-supported tungsten oxide catalysts Kim, T.; Burrows, A.; Kiely, C. Journal of Catalysis, Vol. 246, Issue 2 https://doi.org/10.1016/j.jcat.2006.12.018	journal	March 2007
New insights into the nature of the acidic catalytic active sites present in ZrO2-supported tungsten oxide catalysts Rossmedgaarden, E.; Knowles, W.; Kim, T. Journal of Catalysis, Vol. 256, Issue 1 https://doi.org/10.1016/j.jcat.2008.03.003	journal	May 2008
Functional assessment of the strength of solid acid catalysts Macht, Josef; Carr, Robert T.; Iglesia, Enrique Journal of Catalysis, Vol. 264, Issue 1 https://doi.org/10.1016/j.jcat.2009.03.005	journal	May 2009
Higher Brønsted acidity of WO /ZrO2 catalysts prepared using a high-surface-area zirconium oxyhydroxide Lee, Jae-Hong; Shin, Chae-Ho; Suh, Young-Woong Molecular Catalysis, Vol. 438 https://doi.org/10.1016/j.mcat.2017.06.012	journal	September 2017
Facile synthesis of WOx/ZrO2 catalysts using WO3·H2O precipitate as synthetic precursor of active tungsten species Piva, D. H.; Piva, R. H.; Pereira, C. A. Materials Today Chemistry, Vol. 18 https://doi.org/10.1016/j.mtchem.2020.100367	journal	December 2020
Nature of Catalytically Active Sites in the Supported WO ₃ /ZrO ₂ Solid Acid System: A Current Perspective Zhou, Wu; Soultanidis, Nikolaos; Xu, Hui ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03697	journal	February 2017
Relating n -Pentane Isomerization Activity to the Tungsten Surface Density of WO _x /ZrO ₂ Soultanidis, Nikolaos; Zhou, Wu; Psarras, Antonis C. Journal of the American Chemical Society, Vol. 132, Issue 38 https://doi.org/10.1021/ja105519y	journal	September 2010
Stabilizing Catalytic Pathways via Redundancy: Selective Reduction of Microalgae Oil to Alkanes Peng, Baoxiang; Yuan, Xiaoguo; Zhao, Chen Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja302436q	journal	May 2012
Impact of the Local Concentration of Hydronium Ions at Tungstate Surfaces for Acid-Catalyzed Alcohol Dehydration Pfriem, Niklas; Liu, Yue; Zahn, Florian Journal of the American Chemical Society, Vol. 143, Issue 48 https://doi.org/10.1021/jacs.1c07203	journal	November 2021
Isotopic and Chemical Titration of Acid Sites in Tungsten Oxide Domains Supported on Zirconia Baertsch, Chelsey D.; Soled, Stuart L.; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 105, Issue 7 https://doi.org/10.1021/jp003073d	journal	February 2001
A Comparative Study of the Surface Structure, Acidity, and Catalytic Performance of Tungstated Zirconia Prepared from Crystalline Zirconia or Amorphous Zirconium Oxyhydroxide Lebarbier, Vanessa; Clet, Guillaume; Houalla, Marwan The Journal of Physical Chemistry B, Vol. 110, Issue 28 https://doi.org/10.1021/jp0571224	journal	July 2006
Structural Determination of Bulk and Surface Tungsten Oxides with UV−vis Diffuse Reflectance Spectroscopy and Raman Spectroscopy Ross-Medgaarden, Elizabeth I.; Wachs, Israel E. The Journal of Physical Chemistry C, Vol. 111, Issue 41 https://doi.org/10.1021/jp074219c	journal	September 2007
Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures Barton, David G.; Shtein, Max; Wilson, Ryan D. The Journal of Physical Chemistry B, Vol. 103, Issue 4 https://doi.org/10.1021/jp983555d	journal	January 1999
Genesis and Structure of WO _x /ZrO ₂ Solid Acid Catalysts ^† Scheithauer, Markus; Grasselli, Robert K.; Knözinger, Helmut Langmuir, Vol. 14, Issue 11 https://doi.org/10.1021/la971399g	journal	May 1998
Solid acid catalysts based on supported tungsten oxides Barton, David G.; Soled, Stuart L.; Iglesia, Enrique Topics In Catalysis, Vol. 6, Issue 1/4, p. 87-99 https://doi.org/10.1023/A:1019126708945	journal	January 1998
Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts Zhou, Wu; Ross-Medgaarden, Elizabeth I.; Knowles, William V. Nature Chemistry, Vol. 1, Issue 9 https://doi.org/10.1038/nchem.433	journal	November 2009
One step microwave-assisted synthesis of nanocrystalline WO_x–ZrO₂ acid catalysts Gonell, Francisco; Portehault, David; Julián-López, Beatriz Catalysis Science & Technology, Vol. 6, Issue 23 https://doi.org/10.1039/C6CY01082B	journal	January 2016
Rate enhancement by Cu in Ni _x Cu _1−x /ZrO ₂ bimetallic catalysts for hydrodeoxygenation of stearic acid Denk, Christoph; Foraita, Sebastian; Kovarik, Libor Catalysis Science & Technology, Vol. 9, Issue 10 https://doi.org/10.1039/C9CY00181F	journal	January 2019
Adsorption sites on polymorphic zirconia Jacob, Karl-Heinz; Knözinger, Erich; Benier, Sigrid J. Mater. Chem., Vol. 3, Issue 6 https://doi.org/10.1039/JM9930300651	journal	January 1993
Synthesis of solid superacid of tungsten oxide supported on zirconia and its catalytic action for reactions of butane and pentane Hino, Makoto; Arata, Kazushi Journal of the Chemical Society, Chemical Communications, Issue 18 https://doi.org/10.1039/c39880001259	journal	January 1988
Catalytic deoxygenation of microalgae oil to green hydrocarbons Zhao, Chen; Brück, Thomas; Lercher, Johannes A. Green Chemistry, Vol. 15, Issue 7 https://doi.org/10.1039/c3gc40558c	journal	January 2013
Microbial alkane production for jet fuel industry: motivation, state of the art and perspectives Jiménez-Díaz, Lorena; Caballero, Antonio; Pérez-Hernández, Natalia Microbial Biotechnology, Vol. 10, Issue 1 https://doi.org/10.1111/1751-7915.12423	journal	October 2016
Raman Scattering Study of the Crystallization and Phase Transformations of ZrO2 Keramidas, Vassilis G.; White, William B. Journal of the American Ceramic Society, Vol. 57, Issue 1 https://doi.org/10.1111/j.1151-2916.1974.tb11355.x	journal	January 1974

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