Progress Towards Extended Cycle Life Si-based Anodes: Investigation of Fluorinated Local High Concentration Electrolytes

Lutz, Diana M.; McCarthy, Alison H.; King, Steven T.; Singh, Gurpreet; Stackhouse, Chavis A.; Wang, Lei; Quilty, Calvin D.; Bernardez, Edelmy Marin; Tallman, Killian R.; Tong, Xiao; Bai, Jianming; Zhong, Hui; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Marschilok, Amy C.; Bock, David C.

doi:10.1149/1945-7111/ac8a1e

Progress Towards Extended Cycle Life Si-based Anodes: Investigation of Fluorinated Local High Concentration Electrolytes

Journal Article · Fri Sep 02 00:00:00 EDT 2022 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1945-7111/ac8a1e· OSTI ID:1885490

Lutz, Diana M.; ; King, Steven T.; Singh, Gurpreet; Stackhouse, Chavis A.; ; Quilty, Calvin D.; Bernardez, Edelmy Marin; Tallman, Killian R.; Tong, Xiao; Bai, Jianming; Zhong, Hui; ; ; ; Bock, David C.

Silicon (Si) anodes are promising candidates for Li-ion batteries due to their high specific capacity and low operating potential. Implementation has been challenged by the significant Si volume changes during (de)lithiation and associated growth/regrowth of the solid electrolyte interphase (SEI). In this report, fluorinated local high concentration electrolytes (FLHCEs) were designed such that each component of the electrolyte (solvent, salt, diluent) is fluorinated to modify the chemistry and stabilize the SEI of high (30%) silicon content anodes. FLHCEs were formulated to probe the electrolyte salt concentration and ratio of the fluorinated carbonate solvents to a hydrofluoroether diluent. Higher salt concentrations led to higher viscosities, conductivities, and contact angles on polyethylene separators. Electrochemical cycling of Si-graphite/NMC622 pouch cells using the FLHCEs delivered up to 67% capacity retention after 100 cycles at a C/3 rate. Post-cycling X-ray photoelectron spectroscopy (XPS) analyses of the Si-graphite anodes indicated the FLHCEs formed a LiF rich solid electrolyte interphase (SEI). The findings show that the fluorinated local high concentration electrolytes contribute to stabilizing the Si-graphite electrode over extended cycling.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); New York State Department of Economic Development (DED); New York State Energy Research and Development Authority (NYSERDA); USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: EE0009184; SC0012704

OSTI ID:: 1885490

Alternate ID(s):: OSTI ID: 1881560
OSTI ID: 1889182

Report Number(s):: BNL-223445-2022-JAAM

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 9 Vol. 169; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (113)

Trifluoropropylene Carbonate‐Driven Interface Regulation Enabling Greatly Enhanced Lithium Storage Durability of Silicon‐Based Anodes Hu, Zhongli; Zhao, Liubin; Jiang, Tao Advanced Functional Materials, Vol. 29, Issue 45 https://doi.org/10.1002/adfm.201906548	journal	September 2019
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Direct Visualization of the Solid Electrolyte Interphase and Its Effects on Silicon Electrochemical Performance Sina, Mahsa; Alvarado, Judith; Shobukawa, Hitoshi Advanced Materials Interfaces, Vol. 3, Issue 20 https://doi.org/10.1002/admi.201600438	journal	August 2016
Elucidating the Mechanism Involved in the Performance Improvement of Lithium‐Ion Transition Metal Oxide Battery by Conducting Polymer Kim, Taehoon; Ono, Luis K.; Qi, Yabing Advanced Materials Interfaces, Vol. 6, Issue 7 https://doi.org/10.1002/admi.201801785	journal	February 2019
Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications Zheng, Jianming; Lochala, Joshua A.; Kwok, Alexander Advanced Science, Vol. 4, Issue 8 https://doi.org/10.1002/advs.201700032	journal	March 2017
High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes Jia, Haiping; Zou, Lianfeng; Gao, Peiyuan Advanced Energy Materials, Vol. 9, Issue 31 https://doi.org/10.1002/aenm.201900784	journal	July 2019
Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode Chen, Hao; Pei, Allen; Lin, Dingchang Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900858	journal	April 2019
Countersolvent Electrolytes for Lithium‐Metal Batteries Piao, Nan; Ji, Xiao; Xu, Hong Advanced Energy Materials, Vol. 10, Issue 10 https://doi.org/10.1002/aenm.201903568	journal	March 2020
Intrinsically Nonflammable Ionic Liquid‐Based Localized Highly Concentrated Electrolytes Enable High‐Performance Li‐Metal Batteries Wang, Zhicheng; Zhang, Fengrui; Sun, Yiyang Advanced Energy Materials, Vol. 11, Issue 17 https://doi.org/10.1002/aenm.202003752	journal	March 2021
A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase Tan, Jian; Matz, John; Dong, Pei Advanced Energy Materials, Vol. 11, Issue 16 https://doi.org/10.1002/aenm.202100046	journal	March 2021
A Selection Rule for Hydrofluoroether Electrolyte Cosolvent: Establishing a Linear Free‐Energy Relationship in Lithium–Sulfur Batteries Su, Chi‐Cheung; He, Meinan; Amine, Rachid Angewandte Chemie, Vol. 131, Issue 31 https://doi.org/10.1002/ange.201904240	journal	June 2019
Inhibiting Solvent Co‐Intercalation in a Graphite Anode by a Localized High‐Concentration Electrolyte in Fast‐Charging Batteries Jiang, Li‐Li; Yan, Chong; Yao, Yu‐Xing Angewandte Chemie International Edition, Vol. 60, Issue 7 https://doi.org/10.1002/anie.202009738	journal	December 2020
Model Studies on the Solid Electrolyte Interphase Formation on Graphite Electrodes in Ethylene Carbonate and Dimethyl Carbonate: Highly Oriented Pyrolytic Graphite Weber, Isabella; Schnaidt, Johannes; Wang, Bin ChemElectroChem, Vol. 6, Issue 19 https://doi.org/10.1002/celc.201900909	journal	August 2019
Reaction Mechanisms of the Degradation of Fluoroethylene Carbonate, an Additive of Lithium‐Ion Batteries, Unraveled by Radiation Chemistry Puget, Marin; Shcherbakov, Viacheslav; Denisov, Sergey Chemistry – A European Journal, Vol. 27, Issue 31 https://doi.org/10.1002/chem.202100562	journal	May 2021
The Electrochemical Performance of Silicon Nanoparticles in Concentrated Electrolyte Chang, Zeng-hua; Wang, Jian-tao; Wu, Zhao-hui ChemSusChem, Vol. 11, Issue 11 https://doi.org/10.1002/cssc.201800480	journal	May 2018
Confronting the Challenges of Next‐Generation Silicon Anode‐Based Lithium‐Ion Batteries: Role of Designer Electrolyte Additives and Polymeric Binders Eshetu, Gebrekidan Gebresilassie; Figgemeier, Egbert ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900209	journal	May 2019
Surface film formation on a graphite electrode in Li-ion batteries: AFM and XPS study Leroy, S.; Blanchard, F.; Dedryvère, R. Surface and Interface Analysis, Vol. 37, Issue 10 https://doi.org/10.1002/sia.2072	journal	January 2005
Nanostructured Silicon Anodes for Lithium Ion Rechargeable Batteries Teki, Ranganath; Datta, Moni K.; Krishnan, Rahul Small, Vol. 5, Issue 20 https://doi.org/10.1002/smll.200900382	journal	October 2009
Promoting Si-graphite composite anodes with SWCNT additives for half and NCM811 full lithium ion batteries and assessment criteria from an industrial perspective Shan, Jingning; Yang, Xiaofang; Yan, Chao Frontiers in Energy, Vol. 13, Issue 4 https://doi.org/10.1007/s11708-019-0650-y	journal	December 2019
On electrochemical impedance measurements of LixCo0.2Ni0.8O2 and LixNiO2 intercalation electrodes Levi, M. D.; Gamolsky, K.; Aurbach, D. Electrochimica Acta, Vol. 45, Issue 11 https://doi.org/10.1016/S0013-4686(99)00402-8	journal	February 2000
Binding state information from XPS depth profiling: capabilities and limits Oswald, S.; Reiche, R. Applied Surface Science, Vol. 179, Issue 1-4 https://doi.org/10.1016/S0169-4332(01)00299-9	journal	July 2001
Towards reliable X-ray photoelectron spectroscopy: Sputter-damage effects in transition metal borides, carbides, nitrides, and oxides Greczynski, G.; Hultman, L. Applied Surface Science, Vol. 542 https://doi.org/10.1016/j.apsusc.2020.148599	journal	March 2021
Study of the corrosion behavior of LiFSI based electrolyte for Li-ion cells Wu, Xianyang; Du, Zhijia Electrochemistry Communications, Vol. 129 https://doi.org/10.1016/j.elecom.2021.107088	journal	August 2021
Comparing anode and cathode electrode/electrolyte interface composition and morphology using soft and hard X-ray photoelectron spectroscopy Malmgren, S.; Ciosek, K.; Hahlin, M. Electrochimica Acta, Vol. 97 https://doi.org/10.1016/j.electacta.2013.03.010	journal	May 2013
Unraveling the role of LiFSI electrolyte in the superior performance of graphite anodes for Li-ion batteries Kang, Sung-Jin; Park, Kisung; Park, Seong-Hyo Electrochimica Acta, Vol. 259 https://doi.org/10.1016/j.electacta.2017.11.018	journal	January 2018
Surface tension and density of dielectric heat transfer fluids of HFE type-experimental data at 0.1 MPa and modeling with PC-SAFT equation of state and density gradient theory Vinš, Václav; Aminian, Ali; Celný, David International Journal of Refrigeration, Vol. 131 https://doi.org/10.1016/j.ijrefrig.2021.06.029	journal	November 2021
A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries Edström, Kristina; Herstedt, Marie; Abraham, Daniel P. Journal of Power Sources, Vol. 153, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.05.062	journal	February 2006
Minimization of the cation mixing in Li1+x(NMC)1−xO2 as cathode material Zhang, Xiaoyu; Jiang, W. J.; Mauger, A. Journal of Power Sources, Vol. 195, Issue 5 https://doi.org/10.1016/j.jpowsour.2009.09.029	journal	March 2010
Characterization of high-power lithium-ion batteries by electrochemical impedance spectroscopy. I. Experimental investigation Andre, D.; Meiler, M.; Steiner, K. Journal of Power Sources, Vol. 196, Issue 12 https://doi.org/10.1016/j.jpowsour.2010.12.102	journal	June 2011
Surface study of electrodes after long-term cycling in Li1.2Ni0.15Mn0.55Co0.1O2–graphite lithium-ion cells Li, Xiaobo; Xu, Mengqing; Chen, Yanjing Journal of Power Sources, Vol. 248 https://doi.org/10.1016/j.jpowsour.2013.10.044	journal	February 2014
Comparative study of imide-based Li salts as electrolyte additives for Li-ion batteries Sharova, Varvara; Moretti, Arianna; Diemant, Thomas Journal of Power Sources, Vol. 375 https://doi.org/10.1016/j.jpowsour.2017.11.045	journal	January 2018
Post-mortem analysis of calendar aged large-format lithium-ion cells: Investigation of the solid electrolyte interphase Storch, Mathias; Hahn, Severin Lukas; Stadler, Jochen Journal of Power Sources, Vol. 443 https://doi.org/10.1016/j.jpowsour.2019.227243	journal	December 2019
Ethylene carbonate-free electrolytes for Li-ion battery: Study of the solid electrolyte interphases formed on graphite anodes Ehteshami, Niloofar; Ibing, Lukas; Stolz, Lukas Journal of Power Sources, Vol. 451 https://doi.org/10.1016/j.jpowsour.2020.227804	journal	March 2020
Silicon based lithium-ion battery anodes: A chronicle perspective review Zuo, Xiuxia; Zhu, Jin; Müller-Buschbaum, Peter Nano Energy, Vol. 31 https://doi.org/10.1016/j.nanoen.2016.11.013	journal	January 2017
Unravelling high-temperature stability of lithium-ion battery with lithium-rich oxide cathode in localized high-concentration electrolyte Zhang, Xianhui; Jia, Hao; Xu, Yaobin Journal of Power Sources Advances, Vol. 5 https://doi.org/10.1016/j.powera.2020.100024	journal	October 2020
Evolution of the Si electrode/electrolyte interface in lithium batteries characterized by XPS and AFM techniques: The influence of vinylene carbonate additive Martin, L.; Martinez, H.; Ulldemolins, M. Solid State Ionics, Vol. 215 https://doi.org/10.1016/j.ssi.2012.03.042	journal	May 2012
Interplay between solid-electrolyte interphase and (in)active LixSi in silicon anode Zhang, Xiao; Weng, Suting; Yang, Gaojing Cell Reports Physical Science, Vol. 2, Issue 12 https://doi.org/10.1016/j.xcrp.2021.100668	journal	December 2021
Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers Briggs, David.; Beamson, Graham. Analytical Chemistry, Vol. 64, Issue 15 https://doi.org/10.1021/ac00039a018	journal	August 1992
Li ₂ O Solid Electrolyte Interphase: Probing Transport Properties at the Chemical Potential of Lithium Guo, Rui; Gallant, Betar M. Chemistry of Materials, Vol. 32, Issue 13 https://doi.org/10.1021/acs.chemmater.0c00333	journal	May 2020
Controlling Ion Coordination Structure and Diffusion Kinetics for Optimized Electrode-Electrolyte Interphases and High-Performance Si Anodes Jia, Haiping; Gao, Peiyuan; Zou, Lianfeng Chemistry of Materials, Vol. 32, Issue 20 https://doi.org/10.1021/acs.chemmater.0c02954	journal	September 2020
Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive Xu, Chao; Lindgren, Fredrik; Philippe, Bertrand Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/acs.chemmater.5b00339	journal	March 2015
Estimating Cost and Energy Demand in Producing Lithium Hexafluorophosphate for Li-Ion Battery Electrolyte Susarla, Naresh; Ahmed, Shabbir Industrial & Engineering Chemistry Research, Vol. 58, Issue 9 https://doi.org/10.1021/acs.iecr.8b03752	journal	January 2019
Density, Surface Tension, and Kinematic Viscosity of Hydrofluoroethers HFE-7000, HFE-7100, HFE-7200, HFE-7300, and HFE-7500 Rausch, Michael H.; Kretschmer, Lorenz; Will, Stefan Journal of Chemical & Engineering Data, Vol. 60, Issue 12 https://doi.org/10.1021/acs.jced.5b00691	journal	July 2015
Investigation of Solid Electrolyte Interphase Layer Formation and Electrochemical Reversibility of Magnetite, Fe ₃ O ₄ , Electrodes: A Combined X-ray Absorption Spectroscopy and X-ray Photoelectron Spectroscopy Study Bock, David C.; Waller, Gordon H.; Mansour, Azzam N. The Journal of Physical Chemistry C, Vol. 122, Issue 26 https://doi.org/10.1021/acs.jpcc.8b01970	journal	May 2018
In Situ Observation of Lithiation and Delithiation Reactions of a Silicon Thin Film Electrode for All-Solid-State Lithium-Ion Batteries by X-ray Photoelectron Spectroscopy Endo, Raimu; Ohnishi, Tsuyoshi; Takada, Kazunori The Journal of Physical Chemistry Letters, Vol. 11, Issue 16 https://doi.org/10.1021/acs.jpclett.0c01906	journal	July 2020
Systematic Investigation of Electrochemical Performances for Lithium-Ion Batteries with Si/Graphite Anodes: Effect of Electrolytes Based on Fluoroethylene Carbonate and Linear Carbonates Zhao, Enyou; Gu, Yixuan; Fang, Shaohua ACS Applied Energy Materials, Vol. 4, Issue 3 https://doi.org/10.1021/acsaem.0c02946	journal	February 2021
XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction Wood, Kevin N.; Teeter, Glenn ACS Applied Energy Materials, Vol. 1, Issue 9 https://doi.org/10.1021/acsaem.8b00406	journal	August 2018
Highly Concentrated LiTFSI–EC Electrolytes for Lithium Metal Batteries Nilsson, Viktor; Kotronia, Antonia; Lacey, Matthew ACS Applied Energy Materials, Vol. 3, Issue 1 https://doi.org/10.1021/acsaem.9b01203	journal	December 2019
Nature of the Cathode–Electrolyte Interface in Highly Concentrated Electrolytes Used in Graphite Dual-Ion Batteries Kotronia, Antonia; Asfaw, Habtom D.; Tai, Cheuk-Wai ACS Applied Materials & Interfaces, Vol. 13, Issue 3 https://doi.org/10.1021/acsami.0c18586	journal	January 2021
Chemical Interplay of Silicon and Graphite in a Composite Electrode in SEI Formation Yang, Zhenzhen; Kim, Minkyu; Yu, Lei ACS Applied Materials & Interfaces, Vol. 13, Issue 47 https://doi.org/10.1021/acsami.1c15727	journal	November 2021
Nonflammable Fluorinated Carbonate Electrolyte with High Salt-to-Solvent Ratios Enables Stable Silicon-Based Anode for Next-Generation Lithium-Ion Batteries Zeng, Guifang; An, Yongling; Xiong, Shenglin ACS Applied Materials & Interfaces, Vol. 11, Issue 26 https://doi.org/10.1021/acsami.9b05570	journal	June 2019
Understanding the Electrode/Electrolyte Interface Layer on the Li-Rich Nickel Manganese Cobalt Layered Oxide Cathode by XPS Hekmatfar, Maral; Kazzazi, Arefeh; Eshetu, Gebrekidan Gebresilassie ACS Applied Materials & Interfaces, Vol. 11, Issue 46 https://doi.org/10.1021/acsami.9b14389	journal	October 2019
Rational Design of Electrolytes for Long-Term Cycling of Si Anodes over a Wide Temperature Range Chae, Sujong; Kwak, Won-Jin; Han, Kee Sung ACS Energy Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsenergylett.0c02214	journal	January 2021
Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes Zheng, Jianming; Chen, Shuru; Zhao, Wengao ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01213	journal	January 2018
Lithium Metal Battery Using LiFe_0.5Mn_0.5PO₄ Olivine Cathode and Pyrrolidinium-Based Ionic Liquid Electrolyte Di Lecce, Daniele; Hassoun, Jusef ACS Omega, Vol. 3, Issue 8 https://doi.org/10.1021/acsomega.8b01328	journal	August 2018
Role of Surface Oxides in the Formation of Solid–Electrolyte Interphases at Silicon Electrodes for Lithium-Ion Batteries Schroder, Kjell W.; Dylla, Anthony G.; Harris, Stephen J. ACS Applied Materials & Interfaces, Vol. 6, Issue 23 https://doi.org/10.1021/am506517j	journal	November 2014
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
Nanosilicon Electrodes for Lithium-Ion Batteries: Interfacial Mechanisms Studied by Hard and Soft X-ray Photoelectron Spectroscopy Philippe, Bertrand; Dedryvère, Rémi; Allouche, Joachim Chemistry of Materials, Vol. 24, Issue 6 https://doi.org/10.1021/cm2034195	journal	February 2012
Salt Effects and Ion Pairs in Solvolysis and Related Reactions. III. ¹ Common Ion Rate Depression and Exchange of Anions during Acetolysis ^2,3 Winstein, S.; Clippinger, E.; Fainberg, A. H. Journal of the American Chemical Society, Vol. 78, Issue 2 https://doi.org/10.1021/ja01583a022	journal	January 1956
Improved Performances of Nanosilicon Electrodes Using the Salt LiFSI: A Photoelectron Spectroscopy Study Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela Journal of the American Chemical Society, Vol. 135, Issue 26 https://doi.org/10.1021/ja403082s	journal	June 2013
Side-Chain Conducting and Phase-Separated Polymeric Binders for High-Performance Silicon Anodes in Lithium-Ion Batteries Park, Sang-Jae; Zhao, Hui; Ai, Guo Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja511181p	journal	February 2015
Stable Dendrite-Free Sodium–Sulfur Batteries Enabled by a Localized High-Concentration Electrolyte He, Jiarui; Bhargav, Amruth; Shin, Woochul Journal of the American Chemical Society, Vol. 143, Issue 48 https://doi.org/10.1021/jacs.1c08851	journal	November 2021
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability Zhao, Jie; Liao, Lei; Shi, Feifei Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05251	journal	August 2017
A New Class of Ionically Conducting Fluorinated Ether Electrolytes with High Electrochemical Stability Amanchukwu, Chibueze V.; Yu, Zhiao; Kong, Xian Journal of the American Chemical Society, Vol. 142, Issue 16 https://doi.org/10.1021/jacs.9b11056	journal	April 2020
Effect of Sulfate Electrolyte Additives on LiNi _1/3 Mn _1/3 Co _1/3 O ₂ /Graphite Pouch Cell Lifetime: Correlation between XPS Surface Studies and Electrochemical Test Results Madec, Lénaïc; Xia, Jian; Petibon, Rémi The Journal of Physical Chemistry C, Vol. 118, Issue 51 https://doi.org/10.1021/jp509731y	journal	December 2014
Solvent Activity in Electrolyte Solutions Controls Electrochemical Reactions in Li-Ion and Li-Sulfur Batteries Moon, Heejoon; Mandai, Toshihiko; Tatara, Ryoichi The Journal of Physical Chemistry C, Vol. 119, Issue 8 https://doi.org/10.1021/jp5128578	journal	February 2015
Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes Etacheri, Vinodkumar; Haik, Ortal; Goffer, Yossi Langmuir, Vol. 28, Issue 1 https://doi.org/10.1021/la203712s	journal	December 2011
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Hierarchical porous silicon structures with extraordinary mechanical strength as high-performance lithium-ion battery anodes Jia, Haiping; Li, Xiaolin; Song, Junhua Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15217-9	journal	March 2020
Advances and issues in developing salt-concentrated battery electrolytes Yamada, Yuki; Wang, Jianhui; Ko, Seongjae Nature Energy https://doi.org/10.1038/s41560-019-0336-z	journal	March 2019
All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents Fan, Xiulin; Ji, Xiao; Chen, Long Nature Energy, Vol. 4, Issue 10 https://doi.org/10.1038/s41560-019-0474-3	journal	October 2019
Surface-wetting characterization using contact-angle measurements Huhtamäki, Tommi; Tian, Xuelin; Korhonen, Juuso T. Nature Protocols, Vol. 13, Issue 7 https://doi.org/10.1038/s41596-018-0003-z	journal	July 2018
Determination of the Solid Electrolyte Interphase Structure Grown on a Silicon Electrode Using a Fluoroethylene Carbonate Additive Veith, Gabriel M.; Doucet, Mathieu; Sacci, Robert L. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-06555-8	journal	July 2017
Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms McOwen, Dennis W.; Seo, Daniel M.; Borodin, Oleg Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42351D	journal	January 2014
An XPS/AES comparative study of the surface behaviour of nano-silicon anodes for Li-ion batteries Radvanyi, Etienne; De Vito, Eric; Porcher, Willy J. Anal. At. Spectrom., Vol. 29, Issue 6 https://doi.org/10.1039/C3JA50362C	journal	January 2014
SEI-component formation on sub 5 nm sized silicon nanoparticles in Li-ion batteries: the role of electrode preparation, FEC addition and binders Jaumann, Tony; Balach, Juan; Klose, Markus Physical Chemistry Chemical Physics, Vol. 17, Issue 38 https://doi.org/10.1039/C5CP03672K	journal	January 2015
Enhancing metallic lithium battery performance by tuning the electrolyte solution structure Huang, Feifei; Ma, Guoqiang; Wen, Zhaoyin Journal of Materials Chemistry A, Vol. 6, Issue 4 https://doi.org/10.1039/C7TA08274F	journal	January 2018
Ionic association analysis of LiTDI, LiFSI and LiPF ₆ in EC/DMC for better Li-ion battery performances Berhaut, Christopher L.; Lemordant, Daniel; Porion, Patrice RSC Advances, Vol. 9, Issue 8 https://doi.org/10.1039/C8RA08430K	journal	January 2019
FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries Xue, Weijiang; Shi, Zhe; Huang, Mingjun Energy & Environmental Science, Vol. 13, Issue 1 https://doi.org/10.1039/C9EE02538C	journal	January 2020
Anion effects on the solvation structure and properties of imide lithium salt-based electrolytes Wang, Li; Luo, Zhen; Xu, Hong RSC Advances, Vol. 9, Issue 71 https://doi.org/10.1039/C9RA07824J	journal	January 2019
Electrolytes for advanced lithium ion batteries using silicon-based anodes Xu, Zhixin; Yang, Jun; Li, Hongping Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/C9TA01876J	journal	January 2019
A localized high concentration electrolyte for 4 V-class potassium metal batteries Xu, Wenxin; Wang, Huwei; Gao, Yueteng Energy Advances, Vol. 1, Issue 4 https://doi.org/10.1039/D2YA00015F	journal	January 2022
Chemically stable artificial SEI for Li-ion battery electrodes Zhang, Qinglin; Han, Lei; Pan, Jie Applied Physics Letters, Vol. 110, Issue 13 https://doi.org/10.1063/1.4979108	journal	March 2017
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries Suo, Liumin; Xue, Weijiang; Gobet, Mallory Proceedings of the National Academy of Sciences, Vol. 115, Issue 6 https://doi.org/10.1073/pnas.1712895115	journal	January 2018
Rheological Characterization of Ethanolamine Gel Propellants Jyoti, Botchu V. S.; Baek, Seung Wook Journal of Energetic Materials, Vol. 34, Issue 3 https://doi.org/10.1080/07370652.2015.1061617	journal	January 2016
Compression of lithium fluoride to 92 GPa Dong, Haini; Dorfman, Susannah M.; Holl, Christopher M. High Pressure Research, Vol. 34, Issue 1 https://doi.org/10.1080/08957959.2013.878932	journal	January 2014
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Poly(acrylic acid) (PAA) XPS Reference Core Level and Energy Loss Spectra Louette, Pierre; Bodino, Frederic; Pireaux, Jean-Jacques Surface Science Spectra, Vol. 12, Issue 1 https://doi.org/10.1116/11.20050905	journal	December 2005
Practical guide for curve fitting in x-ray photoelectron spectroscopy Major, George H.; Fairley, Neal; Sherwood, Peter M. A. Journal of Vacuum Science & Technology A, Vol. 38, Issue 6 https://doi.org/10.1116/6.0000377	journal	December 2020
Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries Choi, Sunghun; Kwon, Tae-woo; Coskun, Ali Science, Vol. 357, Issue 6348 https://doi.org/10.1126/science.aal4373	journal	July 2017
Impedance spectroscopy of lithium-carbon electrodes Ivanishchev, A. V.; Churikov, A. V.; Ivanishcheva, I. A. Russian Journal of Electrochemistry, Vol. 44, Issue 5 https://doi.org/10.1134/S1023193508050030	journal	May 2008
Common Electroanalytical Behavior of Li Intercalation Processes into Graphite and Transition Metal Oxides Aurbach, Doron Journal of The Electrochemical Society, Vol. 145, Issue 9 https://doi.org/10.1149/1.1838758	journal	January 1998
In Situ Analysis of NMC∣graphite Li-Ion Batteries by Means of Complementary Electrochemical Methods Landa-Medrano, Imanol; Eguia-Barrio, Aitor; Sananes-Israel, Susan Journal of The Electrochemical Society, Vol. 167, Issue 9 https://doi.org/10.1149/1945-7111/ab8b99	journal	January 2020
Studies of the SEI layers in Li(Ni _0.5 Mn _0.3 Co _0.2 )O ₂ /Artificial Graphite Cells after Formation and after Cycling Keefe, A. S.; Weber, Rochelle; Hill, I. G. Journal of The Electrochemical Society, Vol. 167, Issue 12 https://doi.org/10.1149/1945-7111/abaa1b	journal	January 2020
Improved Capacity Retention of Lithium Ion Batteries under Fast Charge via Metal-Coated Graphite Electrodes Tallman, Killian R.; Yan, Shan; Quilty, Calvin D. Journal of The Electrochemical Society, Vol. 167, Issue 16 https://doi.org/10.1149/1945-7111/abcaba	journal	November 2020
Review—Localized High-Concentration Electrolytes for Lithium Batteries Cao, Xia; Jia, Hao; Xu, Wu Journal of The Electrochemical Society, Vol. 168, Issue 1 https://doi.org/10.1149/1945-7111/abd60e	journal	January 2021
Reduction Mechanism of Solid Electrolyte Interphase Formation on Lithium Metal Anode: Fluorine-Rich Electrolyte Wu, Yu; Sun, Qintao; Liu, Yue Journal of The Electrochemical Society, Vol. 169, Issue 1 https://doi.org/10.1149/1945-7111/ac44bc	journal	January 2022
Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows Klett, Matilda; Gilbert, James A.; Pupek, Krzysztof Z. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0131701jes	journal	October 2016
Corrosion/Passivation Behavior of Concentrated Ionic Liquid Electrolytes and Its Impact on the Li-Ion Battery Performance Liu, Qian; Dzwiniel, Trevor L.; Pupek, Krzysztof Z. Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.0161916jes	journal	January 2019
Fluorinated Electrolytes for 5-V Li-Ion Chemistry: Probing Voltage Stability of Electrolytes with Electrochemical Floating Test He, Meinan; Hu, Libo; Xue, Zheng Journal of The Electrochemical Society, Vol. 162, Issue 9 https://doi.org/10.1149/2.0231509jes	journal	January 2015
A Study of the Physical Properties of Li-Ion Battery Electrolytes Containing Esters Logan, E. R.; Tonita, Erin M.; Gering, K. L. Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0271802jes	journal	January 2018
Perspective—Fluorinating Interphases Wang, Chunsheng; Meng, Ying Shirley; Xu, Kang Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0281903jes	journal	December 2018
Battery Electrolytes Based on Unsaturated Ring Ionic Liquids: Conductivity and Electrochemical Stability DiLeo, Roberta A.; Marschilok, Amy C.; Takeuchi, Kenneth J. Journal of The Electrochemical Society, Vol. 160, Issue 9 https://doi.org/10.1149/2.045309jes	journal	January 2013
Dilution of Highly Concentrated LiBF ₄ /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi _0.5 Mn _1.5 O ₄ Positive Electrodes Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0611701jes	journal	January 2017
Solid Electrolyte Interphase Film on Lithium Metal Anode in Mixed-Salt System Eijima, Sho; Sonoki, Hidetoshi; Matsumoto, Mitsuhiro Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0611903jes	journal	January 2019
Development of Electrolytes for Si-Graphite Composite Electrodes Nguyen, Cao Cuong; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.0621810jes	journal	January 2018
Solvate Ionic Liquid Electrolyte for Li–S Batteries Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.111308jes	journal	January 2013
Temperature Dependence of Oxygen Release from LiNi _0.6 Mn _0.2 Co _0.2 O ₂ (NMC622) Cathode Materials for Li-Ion Batteries Jung, Roland; Strobl, Philipp; Maglia, Filippo Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.1261811jes	journal	January 2018
Safety Appraisal of Lithium Bis(fluorosulfonyl) Imide (LiFSI) As Electrolyte Salt for Li-Ion Batteries Grugeon, Sylvie; Eshetu, Gebrekidan Gebresilassie; Bertrand, Jean-Pierre ECS Meeting Abstracts, Vol. MA2016-01, Issue 5 https://doi.org/10.1149/MA2016-01/5/457	journal	April 2016
Progress of Binder Structures in Silicon-Based Anodes for Advanced Lithium-Ion Batteries: A Mini Review Zhu, Wenqiang; Zhou, Junjian; Xiang, Shuang Frontiers in Chemistry, Vol. 9 https://doi.org/10.3389/fchem.2021.712225	journal	October 2021
Atomic Layer Deposition of Lithium Fluoride Optical Coatings for the Ultraviolet Hennessy, John; Nikzad, Shouleh Inorganics, Vol. 6, Issue 2 https://doi.org/10.3390/inorganics6020046	journal	May 2018
Synthesis and Properties of Acyclic Ammonium-based Ionic Liquids with Allyl Substituents as Electrolytes Yim, Taeeun; Choi, Chang Young; Mun, Junyoung Molecules, Vol. 14, Issue 5 https://doi.org/10.3390/molecules14051840	journal	May 2009
Modeling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium-ion Batteries Choi, Woosung; Shin, Heon-Cheol; Kim, Ji Man Journal of Electrochemical Science and Technology, Vol. 11, Issue 1 https://doi.org/10.33961/jecst.2019.00528	journal	February 2020

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